Tin oxide based conductive powders and coatings

• US 5,571,456 A
• Filed: 04/24/1995
• Issued: 11/05/1996
• Est. Priority Date: 08/18/1994
• Status: Expired due to Term

• Current Assignee: Milliken & Company
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Hormadaly, Jacob, Feist, Thomas P., Jacobson, Howard W., Bergmann, Oswald R.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): DELCOTTO, GREGORY R
• Application Number:
  US08/427,315
• Time in Patent Office: 561 Days
• Field of Search: 252/518, 106/443, 423/593
• US Class Current: 252/519.33
• CPC Class Codes: C01G 19/02 Oxides
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: H01B 1/08 oxides
• CPC Class Codes: H01B 1/20 Conductive material dispersed in non-conductive organic material organic macromolecular compounds or compositions C08

Abstract

A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.

Claims

1. A transparent conductive coating on a substrate, said conductive coating containing an electroconductive powder consisting essentially of from about 0.1 to 10% by weight silica, and tin oxide doped with at least one of tantalum and niobium, and optionally phosphorus;

wherein said powder is substantially free of antimony and pyrochlore.

2. The transparent conductive coating composition of claim 1 characterized by surface resistivity of less than about 10¹² ohm/sq, a haze value of less than about 60%.

3. The transparent, conductive coating composition of claim 1 wherein the distance from whiteness is less than about 20%.

5. The transparent conductive coating composition of claim 1 wherein the thickness of said coating ranges from about 0.0001 to 0.009 inches thick.

6. The transparent conductive coating composition of claim 1 or 4 wherein said dopant ranges from about 0.25 to 15 wt % based upon the tin oxide.

7. The transparent conductive coating composition of claim 1 or 4 wherein the electroconductive powder comprises crystallites that range is size from about 40-500 Angstroms.

8. The transparent conductive coating composition of claim 1 or 4 wherein the electroconductive powder has a dry powder resistivity of about 0.1 to 1,000 Ohms.

9. The transparent conductive coating composition of claim 1 wherein the tin oxide is doped with tantalum.

10. The transparent conductive coating composition of claim 1 wherein the tin oxide is doped with niobium.

11. The transparent conductive coating composition of claim 1 wherein tin oxide is doped with phosphorus and at least one member selected from the group of tantalum and niobium.

12. The transparent conductive coating composition of claim 1 wherein said coating further comprises a binder selected from the group consisting of acrylic resins, polyester resins and gelatin.

13. The transparent conductive coating composition of claim 1 wherein the coating has a haze value of less than about 50%.

4. A transparent conductive coating composition comprising an aqueous acrylic binder resin having a pigment to binder ratio of about 1:

2 to 1;

5 by weight, a surface resistivity of less than about 10¹² ohms/sq, a haze value of less than 20%, a distance from whiteness of less than about 20%, wherein the pigment comprises an electroconductive powder consisting essentially of from about 0.1 to 10% by weight silica and tin oxide doped with at least one of tantalum and niobium, and optionally phosphorus;

wherein said powder is substantially free of antimony and pyrochlore.