Abrasion resistant quasi monofilament and sheathing composition

• US 5,573,850 A
• Filed: 03/24/1995
• Issued: 11/12/1996
• Est. Priority Date: 03/24/1995
• Status: Expired due to Term

• Current Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Original Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Inventors: Kavesh, Sheldon, Cunningham, David V., Griffin, Christopher P.
• Primary Examiner(s): EDWARDS, NEWTON O
• Application Number:
  US08/410,248
• Time in Patent Office: 599 Days
• Field of Search: 428/370, 428/373, 428/374, 264/184, 525/240, 57/232, 57/231, 57/250, 57/258
• US Class Current: 428/373
• CPC Class Codes: A61C 15/041 Dental floss chemical aspects A61Q11/00
• CPC Class Codes: D01D 11/06 Coating with spinning solutions or melts
• CPC Class Codes: D01F 8/06 with at least one polyolefin as constituent
• CPC Class Codes: Y10T 428/2924 Composite
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
• CPC Class Codes: Y10T 428/2931 Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]

Abstract

A quasi monofilament having a high strength polyethylene fiber core with an adherent, abrasion resistant polymer sheath is prepared by feeding the core yarn through a crosshead die, while simultaneously supplying a polymer melt at a temperature greater than the melting point of the core yarn to the die, for sheathing the core yarn within the die with the melt under a sufficient pressure to cause the melt to adhere to the core yam. The abrasion resistant polymer sheath includes an effective amount of a first polymer having ethylene crystallinity, a density of at least about 0.94 g/cm³, and a melt index of less than about 0.1 g/10 min. The composition used to sheathe the core yarn is characterized by a weight average tensile strength at yield of greater than about 13.8 MPa. The quasi monofilament has utility in applications subjected to high abrasion, such as sports fishing lines, kite lines, dental floss, "weedeater" lines and tennis racket strings.

Claims

1. A quasi monofilament comprising:

a. a core of polyethylene multi-filament yarn having a tenacity of at least 15 g/d and a tensile modulus of at least 500 g/d; and

adhered thereto

b. an abrasion resistant sheath, comprising a first polymer having ethylene crystallinity, a density of at least 0.94 g/cm³, and a melt index of less than 0.1 g/10 min.

2. The quasi monofilament of claim 1 wherein the first polymer is polyethylene.

3. The quasi monofilament of claim 1 wherein the sheath is formed from a blend comprising:

a. about 15 to about 95 weight percent, on the weight of the blend, of the first polymer;

in combination with

b. about 5 to about 85 weight percent, on the weight of the blend, of a compatible processing aid.

4. The quasi monofilament of claim 3 wherein the processing aid comprises a second polymer having ethylene crystallinity, a density of at least 0.94 g/cm³, and a melt index of at least 1.0 g/10 min.

5. The quasi monofilament of claim 4 wherein the melt index of the second polymer is from about 1.0 to about 100 g/10 min.

6. The quasi monofilament of claim 5 wherein both the first and second polymers are polyethylene.

7. The quasi monofilament of claim 4 wherein said processing aid further comprises a wax.

8. The quasi monofilament of claim 7 wherein said wax has a density of at least 0.92 g/cm³ and a viscosity at 140°

C. of at least 50 cps.

9. The quasi monofilament of claim 8 wherein the sheath forms about 15 to about 60 weight percent of the monofilament.

10. The quasi monofilament of claim 9 wherein the sheath forms about 20 to about 45 weight percent of the monofilament.

11. The quasi monofilament of claim 1 wherein the core yarn is comprised of about 5 to about 9600 filaments having a dpf of about 0.5 to about 20.

12. The quasi monofilament of claim 11 wherein the core yarn is comprised of about 30 to about 400 filaments having a dpf of about 1 to about 10.

13. The quasi monofilament of claim 1 wherein the core yarn has about 0.1 to about 20 tpi.

14. The quasi monofilament of claim 13 wherein the core yarn has about 0.5 to about 15 tpi.

15. The quasi monofilament of claim 6 wherein said processing aid further comprises a wax having a density of at least 0.92 g/cm³ and a viscosity at 140°

C. of at least 50 cps, the sheath forms about 15 to about 60 weight percent of the monofilament, and the core yarn is comprised of about 30 to about 400 filaments having a dpf of about 1 to about 10.