Direct methanol oxidation polymer electrolyte membrane power system

• US 5,573,866 A
• Filed: 05/08/1995
• Issued: 11/12/1996
• Est. Priority Date: 05/08/1995
• Status: Expired due to Fees

• Current Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Original Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Inventors: Van Dine, Leslie L., Maricle, Donald L.
• Primary Examiner(s): Tung, T.
• Assistant Examiner(s): Noguerda, Alex
• Application Number:
  US08/437,267
• Time in Patent Office: 554 Days
• Field of Search: 429/40, 429/188, 429/13, 429/14, 429/41, 429/46, 429/30, 429/33, 429/192
• US Class Current: 429/414
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04119 with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A polymer electrolyte membrane fuel cell includes an anode chamber and a cathode chamber which are separated by the electrolyte membrane. The fuel cell directly oxidizes a liquid methanol fuel which is fed into the anode chamber from a liquid methanol storage container. The liquid methanol is mixed with water in the anode chamber, and the mixture passes into and through the electrolyte membrane. Some of the methanol and water pass through the membrane into the cathode chamber and into a process air stream which moves through the cathode chamber. The methanol and water are removed from the cathode chamber by evaporation into the process air stream, which then is directed into a condenser/radiator. The methanol and water vapors are condensed in the condenser/radiator, from whence the condensed water and methanol are returned to the anode chamber of the cell. The evaporating cathode process air stream provides oxygen for the fuel cell reaction, and also cools the cell.

Claims

1. A fuel cell power plant assembly which is adapted for utilizing liquid methanol as a fuel source, said assembly comprising:

a) a solid polymer electrolyte membrane;

b) an anode reactant chamber disposed on one side of said electrolyte membrane;

c) a cathode reactant chamber disposed on a side of said electrolyte membrane opposite to said anode reactant chamber;

d) a water-methanol solution disposed in said anode chamber;

e) a cathode catalyst disposed in said cathode reactant chamber, said cathode catalyst being formed from a catalytic composition which does not significantly oxidize methanol that enters said cathode reactant chamber from said anode reactant chamber by diffusion through said electrolyte membrane;

f) a source of oxygen disposed in said cathode chamber, wherein said source of oxygen is a stream of air which flows through said cathods reactant chamber and sweeps product water and diffused water and methanol out of said cathode reactant chamber to cool the latter; and

g) a condenser for receiving an effluent stream of humidified air from said cathode reactant chamber, said condenser being operable to condense liquid water and liquid methanol from said effluent cathode reactant chamber air stream.

2. The fuel cell power plant assembly of claim 1 further comprising a return line from said condenser to said anode chamber, said return line being operable to transfer condensed water and methanol from said condenser to said anode reactant chamber for recycling said condensed water and methanol through the power plant.

3. The fuel cell power plant assembly of claim 2 further comprising a supply of liquid methanol, and methanol delivery means for selectively delivering liquid methanol from said supply thereof to said anode reactant chamber.

4. The fuel cell power plant assembly of claim 3 wherein said supply of liquid methanol comprises a tank containing the liquid methanol, and means for pressurizing the liquid methanol in said tank.

5. The fuel cell power plant assembly of claim 4 further comprising a metering pump in said methanol delivery means for assisting movement of the liquid methanol from said tank to said anode reactant chamber.

8. A method of operating a solid polymer fuel cell power plant with a liquid methanol fuel source, said method comprising the steps of:

a) providing a solid polymer electrolyte membrane in said power plant;

b) providing a supply of a water-methanol solution in an anode reactant chamber disposed on one side of said electrolyte membrane;

c) providing a cathode catalyst in a cathode reactant chamber disposed on a side of said electrolyte membrane opposite said anode reactant chamber, said cathode catalyst being formed from a catalytic composition which does not significantly oxidize liquid methanol which diffuses from said anode reactant chamber to said cathode reactant chamber through said electrolyte membrane;

d) allowing liquid methanol to diffuse through said electrolyte membrane during operation of the power plant;

e) directing a stream of air through said cathode reactant chamber to provide oxygen to produce electricity in the power plant, and to provide a gaseous stream which will sweep product water and diffused water and methanol out of said cathode reactant chamber to cool the latter; and

f) providing a condenser for receiving an effluent stream of humidified air from said cathode reactant chamber, said condenser being operable to condense liquid water and liquid methanol from said effluent cathode reactant chamber air stream.

6. The fuel cell power plant assembly of claim 7 further comprising means for sensing the level of the water-methanol solution in said anode reactant chamber.

7. The fuel cell power plant assembly of claim 8 further comprising means for selectively enhancing cooling in said condenser, and operatively connected to said means for sensing, so as to increase the amount of water and methanol condensed out of said effluent stream of humidified air when a target level of the water-methanol solution is sensed in said anode reactant chamber.

9. The method of claim 8 further comprising the step of providing a return line from said condenser to said anode chamber, said return line being operable to transfer condensed water and methanol from said condenser to said anode reactant chamber for recycling said condensed water and methanol through the power plant.

10. The method of claim 9 further comprising the step of selectively delivering liquid methanol from said supply thereof to said anode reactant chamber.

11. The method of claim 10 further comprising the step of containing the liquid methanol in a tank.

12. The method of claim 11 further comprising the step of assisting movement of the liquid methanol from said tank to said anode reactant chamber.

13. The method of claim 12 further comprising the step of sensing the level of the water-methanol solution in said anode reactant chamber.

14. The method of claim 13 further comprising the step of selectively cooling said condenser to increase the amount of water condensed out of said effluent stream of humidified air upon sensing a target level of water-methanol in said anode reactant chamber.

15. A fuel cell power plant assembly which is adapted for utilizing liquid methanol as a fuel source, said assembly comprising:

a) a solid polymer electrolyte membrane;

b) an anode reactant chamber disposed on one side of said electrolyte membrane;

c) a cathode reactant chamber disposed on a side of said electrolyte membrane opposite to said anode reactant chamber;

d) a water-methanol solution disposed in said anode chamber;

e) a cathode catalyst disposed in said cathode reactant chamber, said cathode catalyst being formed from a catalytic composition which does not significantly oxidize methanol that enters said cathode reactant chamber from said anode reactant chamber by diffusion through said electrolyte membrane;

f) means for producing a stream of air which flows through said cathode reactant chamber and sweeps product water and diffused water and methanol out of said cathode reactant chamber to cool the latter;

g) a condenser for receiving an effluent stream of humidified air from said cathode reactant chamber, said condenser being operable to condense liquid water and liquid methanol from said effluent stream; and

h) a return line from said condenser to said anode chamber, said return line being operable to transfer condensed water and methanol from said condenser to said anode reactant chamber for recycling said condensed water and methanol through the power plant.