Process for controlling concentration of a solution of a solvent and polymer

• US 5,573,952 A
• Filed: 08/12/1994
• Issued: 11/12/1996
• Est. Priority Date: 08/12/1994
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Moessner, Richard C.
• Primary Examiner(s): Snay, Jeffrey R.
• Assistant Examiner(s): Le, Long V.
• Application Number:
  US08/289,558
• Time in Patent Office: 823 Days
• Field of Search: 436/8, 436/50, 436/52, 436/55, 436/60, 436/139, 436/140, 436/164, 436/171, 436/179, 422/62, 422/67, 422/82.05, 422/105, 422/108, 208/DIG. 1, 364/497, 364/498, 364/500, 250/301, 250/339.6, 250/339.12
• US Class Current: 436/8
• CPC Class Codes: G01J 3/28 Investigating the spectrum using colour filters G01J3/51
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: Y10T 436/10 Composition for standardization, calibration, simulation, stabilization, preparation or preservation; processes of use in preparation for chemical testing
• CPC Class Codes: Y10T 436/115831 Condition or time responsive
• CPC Class Codes: Y10T 436/117497 with a continuously flowing sample or carrier stream
• CPC Class Codes: Y10T 436/12 Condition responsive control
• CPC Class Codes: Y10T 436/21 Hydrocarbon
• CPC Class Codes: Y10T 436/212 Aromatic

Abstract

A process for measuring and controlling the concentration of a solution at an aim point of an amide solvent and aramid polymers having aromatic and aliphatic carbon-hydrogen bonds that overlap using a near-infrared analyzer.

Claims

1. A process for measuring and controlling the concentration of a solution at an aim point of an amide solvent and aramid polymers having aromatic and aliphatic carbon-hydrogen bonds that overlap using a near-infrared analyzer, said process comprising the steps of:

a) obtaining averaged absorbance spectra of the solution for the wavelengths where the contributions to the spectrum by aromatic and aliphatic carbon-hydrogen bonds overlap;

b) making a baseline correction to the spectra;

c) determining area-based contributions, A1, to the spectra from aromatic carbon-hydrogen bonds;

d) determining area-based contributions, A2, to the spectra from aliphatic carbon-hydrogen bonds;

e) computing a ratio (A1-C2)/(A2-C3) by utilizing a ratio-based algorithm with the area-based contributions of the aromatic and aliphatic carbon-hydrogen bonds as inputs wherein C2 and C3 are constants;

f) scaling the ratio, (A1-C2)/(A2-C3) from step e) using known polymer concentrations and multiple linear regression to provide a corrected slope and intercept so that the percent of aromatic polymer solids dissolved in the solvent is determined; and

g) adjusting the amount of solvent by removing excess solvent from the solution in accordance with percent aromatic polymer solids dissolved in the solution as determined in step f).

2. The process of claim 1 wherein the aromatic polyamide polymer is an aramid polymer.

3. The process of claim 1 wherein the aromatic polyamide polymer is poly(meta-phenylene isophthalamide).

4. The process of claim 1 wherein the amide solvent is dimetyl acetamide.