Silicone rubber compositions

• US 5,576,054 A
• Filed: 01/17/1995
• Issued: 11/19/1996
• Est. Priority Date: 01/21/1986
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Brown, Peter
• Primary Examiner(s): BELL, JANYCE A
• Application Number:
  US08/373,483
• Time in Patent Office: 672 Days
• Field of Search: 427/160, 427/387, 427/389.7, 427/165
• US Class Current: 427/160
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 17/32 with synthetic or natural resins C03C17/30 takes precedence
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09D 183/04 Polysiloxanes

Abstract

The invention described is a silicone rubber composition useful as an opacifying coating comprising a organopolysiloxane and an opacifier. The opacifying coating is particularly useful as an opacifying layer on translucent material such as glass.

Claims

1. A method of opacifying a spandrel glass surface, which is intended to be on the interior of a building, to stop light transmission by the glass which method comprises applying to the surface, which is intended to be on the interior of the building, a coating composition comprising an ultraviolet light resistant organopolysiloxane and an opacifier, wherein the opacifier is a mixture of carbon black and titanium dioxide present in the amount of 1 to 25% by weight and in a ratio of between 1:

10 and 1;

100 by weight carbon black;

titanium dioxide, in an amount sufficient to provide to the surface sufficient opacity to light transmission, and curing the coating composition on the surface whereby the bond at the interface between the coating composition and the surface maintains its bond strength without peeling, fading or degradation after exposure to daylight for at least 20 months.

2. The method of claim 1 wherein the ultraviolet light resistant organopolysiloxane is a curable silicone rubber.

3. The method of claim 2 wherein the curable silicone rubber is self-bonding.

4. A method of opacifying a spandrel glass surface, which is intended to be on the interior of a building, to stop light transmission by the glass which method comprises applying to the surface, which is intended to be on the interior of the building a coating composition, comprising an ultraviolet light resistant organopolysiloxane and an opacifier selected from the group consisting of titanium, carbon black and calcium carbonate, in an amount to provide to the surface consistent opacity to light transmission, and curing the coating composition on the surface whereby the bond at the interface between the coating composition and the surface maintains its bond strength without peeling, fading or degrading after exposure to daylight for at least 20 months.

5. A method as claimed in claim 4 wherein the opacifier is carbon black present in an amount of 0.1 to 3% by weight of the organopolysiloxane.

6. A method as claimed in claim 4 wherein the opacifier is titanium dioxide present in an amount of 1 to 25% by weight of the organopolysiloxane.

7. The method of claim 4 wherein the ultraviolet light resistant organopolysiloxane is a curable silicone rubber.

8. The method of claim 7 wherein the curable silicone rubber is self-bonding.