Imaging element having an electrically-conductive layer

• US 5,576,162 A
• Filed: 01/18/1996
• Issued: 11/19/1996
• Est. Priority Date: 01/18/1996
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Papadopoulos, Kimon
• Primary Examiner(s): VISCONTI, GERALDINA
• Application Number:
  US08/588,180
• Time in Patent Office: 306 Days
• Field of Search: 430/502, 430/495, 430/523, 430/527, 430/631, 430/538, 430/31, 430/56, 430/202, 430/270.1, 430/616
• US Class Current: 430/527
• CPC Class Codes: G03C 1/7614 Cover layers; Backing layers; Base or auxiliary layers characterised by means for lubricating, for rendering anti-abrasive or for preventing adhesion characterised by the inert particulate additive G03C1/95
• CPC Class Codes: G03C 1/7954 Polyesters
• CPC Class Codes: G03C 1/81 characterised by anticoiling means
• CPC Class Codes: G03C 1/853 Inorganic compounds, e.g. metals
• CPC Class Codes: G03C 2200/10 Advanced photographic system
• CPC Class Codes: Y10S 977/742 Carbon nanotubes, CNTs
• CPC Class Codes: Y10S 977/753 with polymeric or organic binder
• CPC Class Codes: Y10S 977/843 Gas phase catalytic growth, i.e. chemical vapor deposition
• CPC Class Codes: Y10S 977/932 for electronic or optoelectronic application

Abstract

Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder. Use of carbon nanofibers provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.

Claims

1. An imaging element for use in an image-forming process;

said imaging element comprising a support, an image-forming layer, and an electrically-conductive layer;

said electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.

2. An imaging element as claimed in claim 1, wherein the weight ratio of carbon nanofibers to film-forming binder is in the range of 0.01 to 1 to 100 to 1.

3. An imaging element as claimed in claim 1, wherein the weight ratio of carbon nanofibers to film-forming binder is in the range of 0.1 to 1 to 10 to 1.

4. An imaging element as claimed in claim 1, wherein the weight ratio of carbon nanofibers to film-forming binder is in the range of 0.5 to 2 to 2 to 1.

5. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a diameter of less than 500 nanometers.

6. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a diameter of less than 200 nanometers.

7. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a diameter of less than 50 nanometers.

8. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a length to diameter ratio of at least 20.

9. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a length to diameter ratio of at least 50.

10. An imaging element as claimed in claim 1, wherein said carbon nanofibers have a powder resistivity of less than one ohm-cm.

11. An imaging element as claimed in claim 1, wherein the coverage of said carbon nanofibers, based on weight of carbon, is from 1 to 300 mg/m².

12. An imaging element as claimed in claim 1, wherein the coverage of said carbon nanofibers, based on weight of carbon, is from 2 to 50 mg/m².

13. An imaging element as claimed in claim 1, wherein said binder is a water-soluble polymer.

14. An imaging element as claimed in claim 1, wherein said binder is gelatin.

15. An imaging element as claimed in claim 1, wherein said binder is a polyalkoxysilane.

16. An imaging element as claimed in claim 1, wherein said binder is a polyesterionomer.

17. An imaging element as claimed in claim 1, wherein said binder is a polyurethane resin.

18. An imaging element as claimed in claim 1, wherein said support is a poly(ethylene terephthalate) film or a poly(ethylene naphthalate) film.

19. An imaging element as claimed in claim 1, wherein said support is a transparent polymeric film, said image-forming layer is comprised of silver halide grains dispersed in gelatin, and said film-forming binder in said electrically-conductive layer is gelatin.

20. An imaging element as claimed in claim 1, wherein said element is a photographic film.

21. An imaging element as claimed in claim 1, wherein said element is a photographic paper.

22. An imaging element as claimed in claim 1, wherein said element is an electrostatographic element.

23. An imaging element as claimed in claim 1, wherein said element is a photothermographic element.

24. An imaging element as claimed in claim 1, wherein said element is an element adapted for use in a laser toner fusion process.

25. An imaging element as claimed in claim 1, wherein said element is a thermal-dye-transfer receiver element.

26. An imaging element for use in an image-forming process;

said imaging element comprising a support, an image-forming layer, a transparent magnetic layer comprising magnetic particles dispersed in a film-forming binder, and an electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.

27. A photographic film comprising:

(1) a support;

(2) an electrically-conductive layer which serves as an antistatic layer overlying said support; and

(3) a silver halide emulsion layer overlying said electrically-conductive layer;

said electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.

28. A photographic film comprising:

(1) a support;

(2) a silver halide emulsion layer on one side of said support;

(3) an electrically-conductive layer which serves as an antistatic layer on the opposite side of said support; and

(4) a curl control layer overlying said electrically-conductive layer;

said electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.

29. A photographic film comprising:

(1) a support;

(2) a silver halide emulsion layer on one side of said support; and

(3) an electrically-conductive layer which serves as an antistatic backing layer on the opposite side of said support;

said electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.

30. A photographic film comprising:

(1) a support;

(2) a silver halide emulsion layer on one side of said support;

(3) an electrically-conductive layer which serves as an antistatic layer on the opposite side of said support; and

(4) an abrasion-resistant backing layer overlying said electrically-conductive layer;

said electrically-conductive layer comprising a dispersion of carbon nanofibers in a film-forming binder.