Color-safe bleach boosters, compositions and laundry methods employing same

• US 5,576,282 A
• Filed: 09/11/1995
• Issued: 11/19/1996
• Est. Priority Date: 09/11/1995
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Miracle, Gregory S., Kellett, Patti J., Burckett-St. Laurent, James C. T. R., Burns, Michael E.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Douyon, Lorna M.
• Application Number:
  US08/526,623
• Time in Patent Office: 435 Days
• Field of Search: 252/95, 252/102, 252/544, 252/547, 252/174.12, 252/186.38, 252/186.39, 252/186.42, 252/186.43, 252/99, 252/104, 252/174, 252/528, 546/145, 546/150, 8/111, 8/137
• US Class Current: 510/276
• CPC Class Codes: C07D 217/10 Quaternary compounds
• CPC Class Codes: C11D 3/349 additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
• CPC Class Codes: C11D 3/392 Heterocyclic compounds, e.g. cyclic imides or lactames
• CPC Class Codes: D06L 4/12 combined with specific additives

Abstract

Bleach boosters comprising zwitterionic imines and anionic imine polyions having a net negative charge are disclosed. The bleach boosters increase bleaching effectiveness in lower temperature solutions and demonstrate superior color safety profiles. The bleach boosters are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a laundry additive product including zwitterionic imines and anionic imine polyions with a net negative charge as bleach boosters. A method for laundering a fabric employing the bleach boosters of the present invention is also disclosed.

Claims

1. A bleaching composition comprising:

from about 0.01% to about 60% by weight of a peroxygen source and

from about 0.01% to about 10% by weight of a bleach booster selected from the group consisting of zwitterionic imines, anionic imine polyions having a net negative charge of from about -1 to about -3, and mixtures thereof, said bleach booster has the formula;

##STR29## wherein R¹ -R³ are moieties having a total charge of from about 0 to about -1;

R¹ and R² form part of a common ring;

T is selected from the group consisting of;

--(CH₂)_b -- wherein b is from about 1 to about 8, --(CH(R⁵))-- wherein R⁵ is C₁ -C₈ alkyl, --CH₂ (C₆ H₄)--, ##STR30## and --(CH₂)_d (E)(CH₂)_f -- wherein d is from 2 to 8, f is from 1 to 3 and E is --C(O)O--, --C(O)NR⁶ -- or;

##STR31## wherein R⁶ is H or C₁ -C₄ alkyl;

Z is covalently bonded to T; and

Z is selected from the group consisting of --CO₂^-, --SO₃^- and --OSO₃^- ; and

a is either 1 or 2.

2. The bleaching composition as claimed in claim 1 wherein said peroxygen source comprises a preformed peracid compound selected from the group consisting of percarboxylic acids and salts, percarbonic acids and salts, perimidic acids and salts, peroxymonosulfuric acids and salts, and mixtures thereof.

3. The bleaching composition as claimed in claim 1 wherein said peroxygen source comprises a hydrogen peroxide source and a bleach activator.

4. The bleaching composition as claimed in claim 3 wherein said hydrogen peroxide source is selected from the group consisting of perborate compounds, percarbonate compounds, perphosphate compounds and mixtures thereof.

5. The bleaching composition as claimed in claim 3 wherein said bleach activator is selected from the group consisting of tetraacetylethylenediamine, sodium decanoyloxybenzene sulfonate, sodium nonanoyloxybenzene sulfonate, sodium octanoyloxybenzene sulfonate, (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamido-caproyl)oxybenzenesulfonate, (6-decanamidocaproyl)oxybenzenesulfonate, and mixtures thereof.

6. The bleaching composition as claimed in claim 1 wherein R¹ and R² together form the non-charged moiety:

##STR32##

7. The bleaching composition as claimed in claim 6 wherein said bleach booster is an aryliminium zwitterion and R³ is H, T is --(CH₂)_b -- or --CH₂ (C₆ H₄)--, Z is --SO₃^-, a is 1 and b is from 2 to 4.

8. The bleaching composition as claimed in claim 7 wherein said bleach booster is an aryliminium zwitterion having the formula:

##STR33##

9. The bleaching composition as claimed in claim 6 wherein said bleach booster is an aryliminium polyion having a net negative charge, R³ is H, T is --(CH₂)_b -- or --CH₂ (C₆ H₄)--, Z is --SO₃^-, a is 2 and b is from 2 to 4.

10. The bleaching composition as claimed in claim 9 wherein said aryliminium polyion has the formula:

##STR34## or a water-soluble salt thereof.

11. The bleaching composition as claimed in claim 1 further comprising at least one detersive surfactant.

12. The bleaching composition as claimed in claim 11 further comprising from about 0.1% to about 10% by weight of at least one chelating agent.

13. The bleaching composition as claimed in claim 1 further comprising from about 0.001% to about 5% by weight of at least one detersive enzyme.

14. The bleaching composition as claimed in claim 11 having an aqueous 1% solution pH of from about 8 to about 10.

15. A zwitterionic laundry bleach booster compound selected from:

##STR35##

16. A method for laundering a fabric, said method comprising:

a step of contacting a fabric to be laundered with a laundry solution, said laundry solution comprising from about 0.01% to about 60% by weight of a peroxygen source and from about 0.01% to about 10% by weight of a bleach booster selected from the group consisting of zwitterionic imines, anionic imine polyions having a net negative charge of from about -1 to about -3, and mixtures thereof, said bleach booster has the formula;

##STR36## wherein R¹ -R³ are moieties having a total charge of from about 0 to about -1;

R¹ and R² form part of a common ring;

T is selected from the group consisting of;

--(CH₂)_b -- wherein b is from about 1 to about 8, --(CH(R⁵))-- wherein R⁵ is C₁ -C₈ alkyl, --CH₂ (C₆ H₄)--, ##STR37## and --(CH₂)_d (E)(CH₂)_f -- wherein d is from 2 to 8, f is from 1 to 3 and E is --C(O)O--, --C(O)NR⁶ -- or;

##STR38## wherein R⁶ is H or C₁ -C₄ alkyl;

Z is covalently bonded to T; and

Z is selected from the group consisting of --CO₂^-, --SO₃^- and --OSO₃^- ; and

a is either 1 or 2.

17. The method as claimed in claim 16 wherein said laundry solution further includes at least one detersive surfactant.

18. The method as claimed in claim 17 wherein said laundry solution further comprises from about 0.1% to about 10% by weight of at least one chelating agent.

19. The method as claimed in claim 16 wherein said laundry solution further comprises from about 0.001% to about 5% by weight of at least one detersive enzymes.

20. The method as claimed in claim 17 wherein said laundry solution has a pH of from about 8 to about 10.

21. The method as claimed in claim 16 wherein said peroxygen source comprises a hydrogen peroxide source and a bleach activator.

22. The method as claimed in claim 21 wherein said hydrogen peroxide source is selected from the group consisting of perborate compounds, percarbonate compounds, perphosphate compounds and mixtures thereof.

23. The method as claimed in claim 21 wherein said bleach activator is selected from the group consisting of tetraacetylethylenediamine, sodium decanoyloxybenzene sulphonate, sodium nonanoyloxybenzene sulfonate, sodium octanoyloxybenezene sulfonate, (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamidocaproyl)oxybenzenesulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.

24. The method as claimed in claim 16 wherein said bleach booster has the formula:

##STR39##

25. A laundry additive product comprising:

a laundry additive being in dosage form for addition to a laundry solution, said additive comprising a bleach booster selected from the group consisting of zwitterionic imines, anionic imine polyions having a net negative charge of from about -1 to about -3 and mixtures thereof, said bleach booster has the formula;

##STR40## wherein R¹ -R³ are moieties having a total charge of from about 0 to about -1;

R¹ and R² form part of a common ring;

T is selected from the group consisting of;

--(CH₂)_b -- wherein b is from about 1 to about 8, --(CH(R⁵))-- wherein R⁵ is C₁ -C₈ alkyl, --CH₂ (C₆ H₄)--, ##STR41## and --(CH₂)_d (E)(CH₂)_f -- wherein d is from 2 to 8, f is from 1 to 3 and m is --C(O)O--, --C(O)NR⁶ -- or;

##STR42## wherein R⁶ is H or C₁ -C₄ alkyl;

Z is covalently bonded to T; and

Z is selected from the group consisting of --CO₂^-, --SO₃^- and --OSO₃^- ; and

a is either 1 or 2.

26. The laundry product as claimed in claim 25 wherein said additive further comprises from about 0.01% to about 60% by weight of a hydrogen peroxide source selected from the group consisting of perborate compounds, percarbonate compounds, perphosphate compounds and mixtures thereof.

27. The laundry additive product as claimed in claim 25 wherein said additive further comprises a bleach activator selected from the group consisting of tetraacetylethylenediamine, sodium decanoyloxybenzene sulfonate, sodium nonanoyloxybenzene sulfonate, sodium octanoyloxybenezene sulfonate, (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamidocaproyl)oxybenzenesulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.

28. The additive laundry product as claimed in claim 25 wherein said bleach booster has the formula:

##STR43##

29. The laundry additive product as claimed in claim 25, wherein said dosage form comprises a pill, tablet, caplet, gelcap or other single dosage form.

30. The laundry additive product as claimed in claim 25 wherein said laundry additive further includes from about 5% to about 90% by weight of a filler or carrier selected from the following:

sulfates, carbonates, silicates, talc, clay, water, monohydric alcohols, polyols or diols.

31. A laundry additive product comprising:

a laundry additive, said additive comprising from about 0.01% to about 10% by weight of a bleach booster selected from the group consisting of zwitterionic imines, anionic imine polyions having a net negative charge of from about -1 to about -3 and mixtures thereof, and from about 5% to about 90% by weight of a filler or carrier for said booster, said filler or carrier being selected from the following;

sulfates, carbonates, silicates, talc, clay, water, monohydric alcohols, polyols or diols, and

wherein said bleach booster has the formula;

##STR44## wherein R¹ -R³ are moieties having a total charge of from about 0 to about -1;

R¹ and R² form part of a common ring;

T is selected from the group consisting of;

--(CH₂)_b -- wherein b is from about 1 to about 8, --(CH(R⁵))-- wherein R⁵ is C₁ -C₈ alkyl, --CH₂ (C₆ H₄)--, ##STR45## and --(CH₂)_d (E)(CH₂)_f -- wherein d is from 2 to 8, f is from 1 to 3 and E is --C(O)O--, --C(O)NR⁶ -- or;

##STR46## wherein R⁶ is H or C₁ -C₄ alkyl;

Z is covalently bonded to T; and

Z is selected from the group consisting of --CO₂^-, --SO₃^- and and a is either 1 or 2.