Polymer moulding materials for producing a partial color change by laser energy, particularly for the production of colored markings

• US 5,576,377 A
• Filed: 03/20/1995
• Issued: 11/19/1996
• Est. Priority Date: 03/30/1994
• Status: Expired due to Term

• Current Assignee: Lanxess Deutschland GmbH (Lanxess AG)
• Original Assignee: Bayer AG
• Inventors: Messina, Salvatore, Gerling, Frank, Magerstedt, Herbert, Ostlinning, Edgar, Idel, Karsten-Josef, El Sayed, Aziz
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US08/406,493
• Time in Patent Office: 610 Days
• Field of Search: 524/495, 524/515, 524/570, 106/472, 522/2, 523/300
• US Class Current: 524/495
• CPC Class Codes: B41M 5/262 recording or marking of inorganic surfaces or materials, e.g. glass, metal, or ceramics marking of plastic artifacts with inorganic additives B41M5/267
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 5/0041 Optical brightening agents, organic pigments
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds

Abstract

The present invention relates to colored polymer moulding materials which give rise to colored markings on a dark background with a very high contrast ratio on the absorption of laser energy.

Claims

1. A laser-inscribable polymer molding material comprising a polymer selected from the group consisting of polyamide, polyester, polycarbonate, polyester carbonate, polymethacrylate, BS, polystyrene, polyoxymethylene and polyolefin, and 0.1 to 3% by weight of a colorant combination containing an organic dye or pigment, an inorganic pigment of the same color, and carbon black, wherein the polymer molding material has an initial color and further wherein portions of the polymer molding compound that have absorbed laser energy have the same color as said initial color but a lighter tone than portions of the polymer molding material that have not absorbed said laser energy.

2. The molding material of claim 1 wherein the colorant combination consists of 0.04 to 2.0% by weight of said organic dye or pigment , 0.05 to 2.0% by weight of inorganic pigment, and 0.01 to 1.0% by weight of carbon black.

3. The molding material of claim 1, wherein the molding material additionally contains up to 50% by weight reinforcing materials, up to 20% by weight elastomeric modifier, up t o 20% by weight flame retardant additives, and/or up to 2% by weight processing additives.

4. The molding material of claim 1, wherein the colorant combination consists of a mixture of two or more organic dyes or pigments, an inorganic pigment of the same color and carbon black.

5. The molding material of claim 1, wherein the laser energy has a wavelength of from 193 nm to 10,600 nm.

6. The molding material of claim 1, wherein the laser energy has a wavelength of from 193 nm to 1064 nm.