Continuous process for the production of a zinc containing chemical product

• US 5,576,452 A
• Filed: 08/29/1995
• Issued: 11/19/1996
• Est. Priority Date: 08/29/1995
• Status: Expired due to Fees

• Current Assignee: Ferro Corporation
• Original Assignee: Ferro Corporation
• Inventors: Guerini, Anthony F. Jr., Dever, James L.
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US08/520,581
• Time in Patent Office: 448 Days
• Field of Search: 556/130, 556/76, 556/108, 556/113, 556/146, 556/181, 556/83
• US Class Current: 556/130
• CPC Class Codes: C07F 3/003 without C-Metal linkages

Abstract

The present invention provides a continuous melt process for the preparation of a zinc oxide/pentaerythritol chemical product comprising the steps of providing a continuous processor having a product feed zone, a reaction zone, and a discharge zone.

Claims

1. A process for the preparation of a zinc oxide/pentaerythritol chemical product comprising the steps of:

(i) providing a continuous processor having a raw material feed zone, a reaction zone, and a discharge zone;

(ii) feeding zinc oxide and pentaerythritol into said product feed zone and providing a raw material mixture comprising said zinc oxide and said pentaerythritol, said raw material mixture comprising from about 1.7 to about 2.3 moles of said pentaerythritol for about every 1 mole of said zinc oxide;

(iii) maintaining a melt temperature of from about 185°

C. to about 245°

C. in said reaction zone;

(iv) maintaining a temperature of from about 185°

C. to about 245°

C. in said discharge zone;

(v) transporting said raw material mixture into said reaction zone and maintaining a residence time for the raw material mixture in the reaction zone of from about 10 to about 60 seconds so as to provide a reacted chemical product;

(vi) transporting said chemical product into said discharge zone; and

(vii) removing said chemical product from said discharge zone.

2. A process as set forth in claim 1 including the step of venting volatile by-products produced by the reaction of said zinc oxide with said pentaerythritol.

3. A process as set forth in claim 2 wherein said venting occurs in said discharge zone.

4. A process as set forth in claim 2 wherein said venting occurs in a separate venting zone located between said reaction zone and said discharge zone.

5. A process as set forth in claim 2 wherein said venting occurs in said reaction zone.

6. A process as set forth in claim 1 including a Step (viii) of cooling and granulating said chemical product.

7. A process as set forth in claim 6 wherein said Step (viii) is conducted using a unit selected from the group consisting of a chilled roll flaker and a chilled belt flaker.

8. A process as set forth in claim 1 wherein prior to said Step (ii) said zinc oxide and said pentaerythritol are preblended.

9. A process as set forth in claim 1 wherein said product feed zone includes one or more automatic feeders for supplying mixed zinc oxide and pentaerythritol at the desired ratio to said reaction zone.

10. A process as set forth in claim 1 wherein the zinc oxide and pentaerythritol reside in said reaction zone and said discharge zone a minimum of about 70 seconds.

11. A zinc oxide/pentaerythritol chemical product made in accordance with the process of claim 1.

12. A zinc oxide/pentaerythritol chemical product that provides a stabilizer system that displays a retained volume resistivity in PVC resin after aging for 26 weeks at 70% relative humidity and 70°

C. pursuant to test procedure ASTM D257(1994) of at least 1.0×

10¹⁴ Ohm·

cm made by the process of claim 1.

13. A zinc oxide/pentaerythritol chemical product made by a continuous melt process, said continuous melt process comprises the process of feeding zinc oxide and pentaerythritol into the product feed zone of a continuous processor to provide a raw material mixture consisting essentially of said zinc oxide and said pentaerythritol, said raw material mixture consisting essentially of from about 1.7 to about 2.3 moles of said pentaerythritol for about every 1 mole of said zinc oxide, transporting said raw material mixture into the reaction zone of the continuous processor with the reaction zone providing a melt temperature of from about 185°

C. to about 245°

C. such that said raw material mixture maintains a residence time in said reaction zone of from about 10 to about 60 seconds for said raw material mixture so as to provide a reacted zinc oxide/pentaerythritol chemical product, and transporting said chemical product into the discharge zone of the continuous processor.

14. A zinc oxide/pentaerythritol chemical product as set forth in claim 13 wherein said continuous processor of said continuous melt process comprises a piece of equipment selected from the group consisting of a single screw extruder, a twin screw extruder, a continuous mixer, a melt processor and a co-kneader.