Biodiesel fuel

• US 5,578,090 A
• Filed: 06/07/1995
• Issued: 11/26/1996
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Bri (Iron Mountain Incorporated)
• Original Assignee: Bri (Iron Mountain Incorporated)
• Inventors: Bradin, David S.
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US08/477,261
• Time in Patent Office: 538 Days
• Field of Search: 44/308, 44/398, 44/388
• US Class Current: 44/308
• CPC Class Codes: C10L 1/026 for compression ignition
• CPC Class Codes: C10L 1/10 containing additives
• CPC Class Codes: C10L 1/18 containing oxygen
• CPC Class Codes: C11C 3/003 by esterification of fatty acids with alcohols C11C3/02 takes precedence
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A fuel additive composition including fatty acid alkyl esters and glyceryl ethers, and an alternative fuel composition that includes the fuel additive composition. Also provided is a method for preparing the fuel additive composition and the alternative fuel composition. In one embodiment, the fuel additive composition is prepared by esterifying free fatty acids and etherifying glycerol with one or more olefins in the presence of an acid catalyst. In one embodiment, the fuel additive composition can be thermally cracked under conditions of increased temperature and/or pressure in the presence of a Lewis acid catalyst. In another embodiment, the fuel additive composition is hydrocracked. The resulting fuel additive composition can be blended with diesel fuel to produce an alternative fuel composition. In one embodiment, the alternative fuel composition includes between approximately 25 and 95 percent diesel fuel and between approximately 5 and 75 percent of the fuel additive composition.

Claims

1. A fuel additive composition comprising between approximately 10 and 75% fatty acid alkyl esters, 1 and 25% glyceryl ethers, and 0 and 10% triglycerides, wherein the alkyl group on the ethers and the esters is selected from the group consisting of C_1-10 straight, branched or cyclic alkanes.

2. The fuel additive of claim 1 wherein the fatty acid alkyl esters comprise ethyl esters.

3. The fuel additive of claim 1 wherein between approximately 1 and 50% by weight of the fatty acid alkyl esters are derived from animal fat.

4. The fuel additive of claim 1 wherein between approximately 1 and 100 percent by weight of the fatty acid alkyl esters are derived from soybean oil.

5. The fuel additive of claim 1 further comprising between approximately 25 and 95 percent petroleum-based diesel fuel.

6. The fuel additive composition of claim 5 wherein between approximately 25 and 75 percent of the fuel additive composition comprises fatty acid ethyl esters.

7. The fuel additive composition of claim 1 further comprising one or more additional components selected from the group consisting of detergents, octane boosters, cetane number improvers, metal deactivators, corrosion inhibitors, antioxidants, rust inhibitors, dispersants, and biocides.