Anti-fogging coating composition, product coated with said composition and method for preparation of said product

• US 5,578,378 A
• Filed: 07/20/1995
• Issued: 11/26/1996
• Est. Priority Date: 11/19/1987
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Vitrage
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Chartier, Pascal, Kruger, Albert A.
• Primary Examiner(s): CHAPMAN, MARK A
• Application Number:
  US08/504,838
• Time in Patent Office: 495 Days
• Field of Search: 428/422, 428/441, 428/522, 427/508, 427/517, 522/33
• US Class Current: 428/441
• CPC Class Codes: C09K 3/18 for application to surfaces to minimize adherence of ice, mist or water thereto rendering particulate materials free flowing, in general, e.g. making them hydrophobic B01J2/30; Thawing or antifreeze materials for application to surfaces used in liquids for heat-transfer, heat-exchange or heat-storage or for the production of heat or cold other than by combustion, e.g. radiator liquids, C09K5/00
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31645 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

An anti-fogging coating comprises from 40 to 80% by weight of at least one acrylic or methacrylic acid monomer, from 20 to 60% by weight of at least one short chain acrylic or methacrylic acid ester monomer and, in relation to the total weight of the preceding monomers, from 1 to 15% of a crosslinking agent and from 0.1 to 5% of a polymerization initiator compound using the action of ultraviolet radiation. Transparent products formed from a glass or poly(methyl methacrylate) support and a layer of the preceding composition, polymerized and crosslinked by the action of ultraviolet radiation, exhibit good anti-fogging and mechanical resistance properties.

Claims

1. A product having anti-fogging and scratch-resistance characteristics, comprising a support and at least one anti-fogging layer, wherein the layer is formed from a composition consisting essentially of components (A), (B), (C) and (D), on the basis of components (A) and (B) totaling 100%, by weight:

(A) from 40 to 60by weight of at least one acrylic or methacrylic acid monomer,

(B) from 60 to 40% by weight of at least one acrylic or methacrylic acid ester monomer of the formula ##STR2## wherein R is H or CH₃ and R'"'"' is a C_1-4 alkyl, (C) from 1 to 15% by weight, based on the total weight of monomers (A) and (B), of a crosslinking agent, and

(D) from 0.1 to 5% by weight, based on the total weight of monomers (A) and (B), of a polymerization initiator using the action of ultraviolet radiation, said layer being crosslinked by exposure to ultraviolet radiation.

2. The product in accordance with claim 1, wherein the support is comprised of glass or poly(methyl methacrylate).

3. The product in accordance with claim 1, wherein the thickness of the layer is 20-100 μ

m.

4. The product of claim 1, wherein the crosslinking agent is a polyfunctional acrylic monomer or oligomer.

5. The product of claim 4, wherein the cross-linking agent is selected from the group consisting of 1,4-butanediol diacrylate, trimethylol propane triacrylate, dipentaerythritol pentaacrylate, tripropyleneglycol diacrylate, diethyleneglycol diacrylate and mixtures thereof.

6. The product of claim 1, wherein the polymerization initiator is selected from the group consisting of benzildimethylketal, (hydroxy-1-cyclohexyl)-phenylketone, benzophenone and 2-dimethyl-1-[4-(methylthio) phenyl]-2-morpholinopropanone 1.

7. The product of claim 1, comprising from 50 to 60% by weight of monomers (A), from 40 to 50% by weight of monomers (B), and, based on the total weight of monomers (A) and (B), from 5 to 10% by weight of crosslinking agent (C) and 0.1 to 0.5% of polymerization initiator (D).

8. A method for manufacturing a product having anti-fogging and good mechanical resistance properties comprising:

1) cleaning a surface or surfaces, of a support to be coated, in order to render them wettable,

2) applying on said cleaned surfaces of the support a composition consisting essentially of components (A), (B), (C) and (D), on the basis of components (A) and totaling 100%, by weight;

(A) from 40 to 60% by weight of at least one acrylic or methacrylic acid monomer,

(B) from 60 to 40% by weight of at least one acrylic or methacrylic acid ester monomer of the formula ##STR3## wherein R is H or CH₃ and R'"'"' is a C_1-4 alkyl, (C) from 1 to 15% by weight, based on the total weight of monomers (A) and (B), of a crosslinking agent, and

(D) from 0.1 to 5% by weight, based on the total weight of monomers (A) and (B), of a polymerization initiator using the action of ultraviolet radiation, thereby obtaining a homogeneous layer,

3) exposing said coated surfaces to ultraviolet radiation in order to polymerize and crosslink the homogeneous layer.

9. The method in accordance with claim 8, wherein, after exposure to the ultraviolet radiation, the coated surfaces are treated with a base in order to obtain a surface ion exchange.

10. The method in accordance with claim 9, wherein the surfaces which are coated and exposed to ultraviolet radiation are treated with ammonia or an aqueous solution of soda.