Solvent extraction in limited coalescence processes

• US 5,580,692 A
• Filed: 05/01/1995
• Issued: 12/03/1996
• Est. Priority Date: 05/26/1992
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Bermel, Alexandra D., Lofftus, Kevin D.
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US08/431,467
• Time in Patent Office: 582 Days
• Field of Search: 430/137, 523/333, 523/339, 210/702, 210/708, 210/332
• US Class Current: 430/137.14
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/10 characterised by carrier particles

Abstract

Powders suitable as electographic toner and/or carrier particles and other powders which utilize a liquid dispersant are produced by limited coalescence techniques. The dispersant is removed by mixing the suspension of coalesced droplets with a sufficient amount of an extracting liquid to cause the dispersant to diffuse out of the coalesced droplets into the extracting liquid.

Claims

1. A method of making particles having a controlled morphology and narrow particle size distribution, comprising the steps of:

dispersing a quantity of a material in a dispersant to form a dispersion phase;

blending said dispersion phase with a suspending liquid under high shear to produce a suspension of dispersion phase droplets in said suspending liquid, wherein said suspending liquid and said dispersant are immiscible enough to form two phases and said suspension contains a stabilizer which controls said dispersion phase droplets'"'"' coalescence;

allowing said dispersion phase droplets in said suspension to coalesce to a larger size at which substantially no further coalescence can occur; and

mixing said suspension of coalesced droplets with a sufficient amount of an extracting liquid to remove said dispersant from said coalesced droplets, wherein said extracting liquid is sufficiently miscible with said dispersant and present in sufficient volume to dissolve enough of said dispersant to cause said coalesced droplets to solidify and is selected from the group consisting of a liquid which is the same as said suspending liquid, a liquid miscible with said suspending liquid and exhibiting some mutual miscibility with said dispersant, and a solution of the suspending liquid and a cosolvent, said cosolvent being miscible with both said dispersant and said suspending liquid,

whereby said droplets form substantially solidified particles having a controlled morphology and narrow size distribution.

2. The method according to claim 1, further comprising the step of isolating the substantially solidified particles from the suspension after said mixing.

3. The method according to claim 2, wherein said isolating is by filtration.

4. The method according to claim 1, wherein said extracting liquid and said suspending liquid are the same and have at least a 2 wt % mutual miscibility with said dispersant.

5. The method according to claim 1, wherein said extracting liquid is completely miscible with said suspending liquid and has at least a 2 wt % mutual miscibility with said dispersant.

6. The method according to claim 1, wherein said material is a hydrophobic material, said dispersant is substantially water-immiscible, and said suspending liquid is substantially immiscible with said dispersant.

7. The method according to claim 6, wherein said dispersant is ethyl acetate and said suspending liquid and said extracting liquid are water.

8. The method according to claim 1, wherein said material is a hydrophilic material, said dispersant is water or a substance more polar than said suspending liquid, and said suspending liquid is substantially immiscible with said dispersant.

9. The method according to claim 8, wherein said dispersant is water, said suspending liquid is benzyl alcohol, and said extracting liquid is a combination of benzyl alcohol and isopropyl alcohol.

10. The method according to claim 1, wherein said mixing is a single stage.

11. The method according to claim 1, wherein said mixing is by multiple stages.

12. The method according to claim 11, wherein said extracting liquid is the same for each of said multiple stages.

13. The method according to claim 12, wherein said extracting liquid is different in one or more of said multiple stages.

14. The method according to claim 1, wherein said mixing is continuous.

15. The method according to claim 1, further comprising the step of evaporating any of said dispersant which remains after said mixing.

16. The method according to claim 1, wherein said stabilizer is selected from the group consisting of latex-based copolymers and microgels.

17. The method according to claim 1, wherein said suspending liquid contains a promoter and said stabilizer is a silica stabilizer.

18. The method according to claim 1, wherein said material is a polymer suitable for use as a toner and is present in said dispersant in a concentration in the range from about 10 to about 35 wt %, and wherein said small droplets of said dispersion phase contain addenda selected from the group consisting of coloring agents and charge control agents.

19. The method according to claim 1, wherein said particles are suitable for use as electrographic carrier particles.