Borohydrides to inhibit polymer formation in petrochemical caustic scrubbers

• US 5,582,808 A
• Filed: 05/05/1995
• Issued: 12/10/1996
• Est. Priority Date: 05/05/1995
• Status: Expired due to Term

• Current Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Patek, Gary
• Primary Examiner(s): Lewis, Michael
• Assistant Examiner(s): HARDING, AMY MARIE
• Application Number:
  US08/435,858
• Time in Patent Office: 585 Days
• Field of Search: 423/210, 526/74, 526/196, 585/832, 585/853, 208/48 AA
• US Class Current: 423/210
• CPC Class Codes: C10G 19/02 with aqueous alkaline solutions

Abstract

The present invention provides borohydrides that are useful in reducing aldol condensation and subsequent polymer formation in caustic scrubbers. The borohydrides are believed to react with reactive carbonyls yielding more stable alcohols and a salt of the borohydride which remains water soluble, and thus is unlikely to be carried out with the hydrocarbon phase. The borohydrides of the present invention have the potential to reduce reactive carbonyls at a molar ratio as high as about 4:1::carbonyl:borohydride. A preferred borohydride is sodium borohydride (sodium tetrahydroborate).

Claims

1. A method for reducing aldol condensation and subsequent polymer formation during caustic scrubbing of a hydrocarbon stream comprising the step of treating a caustic scrubbing solution with a hydride in an amount sufficient to inhibit aldol condensation in said caustic solution but insufficient to interfere with said caustic scrubbing, wherein said hydride comprises a borohydride of the following structure:

space="preserve" listing-type="equation">M.sup.+ BH.sub.x (OR.sup.1).sub.4-x

wherein

M is selected from the group consisting of an alkali element, a tetraalkylammonium ion or quaternary amine having the structure R²₄ N⁺ wherein R² is independently selected from an alkyl group having between 1-10 carbon atoms;

B comprises boron;

x is between about 1-4; and

R¹ is independently selected from an alkyl group having between about 1-10 carbon atoms.

2. The method of claim 1 wherein said hydride has the following structure:

space="preserve" listing-type="equation">M.sup.+- AlH.sub.x (OR.sup.1).sub.4-x

wherein

M is selected from the group consisting of an alkali element, a tetraalkylammonium ion or quaternary amine having the structure R₂₄ N⁺ wherein R² is independently selected from an alkyl group having between about 1-10 carbon atoms;

Al comprises aluminum;

x is between about 1-4; and

R¹ is independently selected from an alkyl group having between about 1-10 carbon atoms.

3. The method of claim 1 wherein said borohydride is selected from the group consisting of sodium borohydride, lithium borohydride, potassium borohydride, tetramethylammonium borohydride, tetraethylammonium borohydride, and sodium triisopropoxyborohydride.

4. The method of claim 3 wherein said borohydride solution is maintained at a pH of about 14 before said treatment step.

5. The method of claim 3 wherein reactive carbonyls are present in said caustic solution at a molar concentration, and wherein said sufficient amount of said borohydride is at least about 25% of said molar concentration of said reactive carbonyls.

6. The method of claim 1 wherein said borohydride comprises sodium borohydride.

7. The method of claim 6 wherein reactive carbonyls are present in said caustic solution at a molar concentration, and wherein said sufficient amount of said borohydride is at least about 25% of said molar concentration of said reactive carbonyls.

8. The method of claim 1 wherein said hydrocarbon stream comprises mixed light olefins derived from pyrolytically cracked mixtures of aliphatic hydrocarbons.

9. The method of claim 1 wherein said caustic scrubbing solution comprises an aqueous solution selected from the group consisting of sodium hydroxide and potassium hydroxide.

10. The method of claim 1 wherein said hydride is selected from the group consisting of an aqueous and an alcoholic borohydride solution.

11. The method of claim 10 wherein said borohydride solution is maintained highly alkaline using a compound selected from the group consisting of a quaternary ammonium hydroxide and an alkali metal hydroxide.

12. The method of claim 11 wherein said borohydride solution is maintained at a pH of about 14 before said treatment step.

13. The method of claim 1 wherein said borohydride solution is maintained at a pH of about 14 before said treatment step.

14. The method of claim 1 wherein said borohydride solution is maintained at a pH of about 14 before said treatment step.

15. The method of claim 1 wherein reactive carbonyls are present in said caustic solution at a molar concentration, and wherein said sufficient amount of said borohydride is at least about 25% of said molar concentration of said reactive carbonyls.

16. The method of claim 1 wherein reactive carbonyls are present in said caustic solution at a molar concentration, and wherein said sufficient amount of said borohydride is at least about 25% of said molar concentration of said reactive carbonyls.

17. The method of claim 16 wherein said borohydride comprises sodium borohydride.

18. A method for reducing aldol condensation and subsequent polymer formation during caustic scrubbing of a hydrocarbon stream comprising the step of treating said caustic scrubbing solution with a borohydride in an amount sufficient to reduce aldol condensation in said caustic solution but insufficient to interfere with said caustic scrubbing, wherein said borohydride has the following structure:

space="preserve" listing-type="equation">M.sup.+- BH.sub.x (OR.sup.1).sub.4-x

wherein

M is selected from the group consisting of an alkali element, a tetraalkylammonium ion or quaternary amine having the structure R²₄ N⁺ wherein R² is independently selected from an alkyl group having between about 1-10 carbon atoms;

B comprises boron;

x is between about 1-4; and

R¹ is independently selected from an alkyl group having between about 1-10 carbon atoms; and

,

said reactive carbonyls are present in said caustic solution at a molar concentration, and wherein said sufficient amount of said borohydride is at least about 25% of said molar concentration of said reactive carbonyls.

19. A reaction mixture in a caustic scrubber comprising a molar concentration of reactive carbonyls and at least about 25% of said molar concentration of a borohydride.