SO.sub.x, NO.sub.x and particulate removal system

• US 5,585,081 A
• Filed: 04/03/1990
• Issued: 12/17/1996
• Est. Priority Date: 07/25/1988
• Status: Expired due to Term

• Current Assignee: Babcock & Wilcox Power Generation Group Incorporated (Babcock International Group PLC)
• Original Assignee: Babcock & Wilcox Company (Babcock International Group PLC)
• Inventors: Downs, William, Smith, Peter V., Chu, Paul, Doyle, John B.
• Primary Examiner(s): Le, Long V.
• Application Number:
  US07/504,192
• Time in Patent Office: 2,450 Days
• Field of Search: 422/177, 422/171, 422/197, 422/312, 422/222, 422/223, 422/180, 423/239 A, 423/239, 423/244 A, 423/244 R, 423/244.05, 423/244.07, 423/239.1, 423/235, 55/302
• US Class Current: 423/239.1
• CPC Class Codes: B01D 53/8637 Simultaneously removing sulfur oxides and nitrogen oxides

Abstract

A method for controlling emissions of a fossil fuel fired boiler including a high temperature fabric filter house with an SCR catalyst situated therein for receiving flue gases along with an injected ammoniacal compound and sorbent. The sorbent reacts with the SO_x while the ammoniacal compound reduces the NO_x in the presence of the SCR catalyst inside the high temperature fabric filter house. Both the SO_x and the particulates are removed upstream of the SCR catalyst to diminish the problems of SO₂ or SO₃ poisoning of the catalyst and erosion and fouling of the catalyst with the fly ash. Since the sulfur oxides and particulates are removed prior to the heat recovery system, the fouling and corrosion potential are substantially decreased thus allowing the heat recovery system to be operated at a lower outlet flue gas temperature which yields an incremental improvement in energy recovery.

Claims

1. A method of controlling emissions of a fossil fuel fired boiler which produces flue gases containing SO_X, NO_X and particulate, the flue gases being supplied along a flue gas stream to a stack for discharge, comprising the steps of:

providing a high-temperature pulse jet fabric filter house and heat recovering means between the boiler and the stack in series along the flue gas scream with the fabric filter house being upstream of the heat recovering means and having a plurality of fabric filter bags contained therein with each of the fabric filter bags having a bag retainer situated therein;

positioning a selective catalytic reduction catalyst inside each bag retainer of each of the fabric filter bags in the filter house;

injecting sorbent and an ammoniacal compound into the flue gas stream upstream of the fabric filter house for reacting with SO_X and NO_x, the NO_X being further reduced inside the fabric filter house in the presence of the catalyst to clean the hot flue gas; and

supplying the clean hot flue gas to the heat recovering means for recovery of the heat therefrom.

2. A method according to claim 1, further comprising the step of recycling the reacted sorbent from the filter house for reinjection into the flue gas stream.

3. A method according to claim 1, wherein the sorbent is a member selected from the group consisting of calcium oxide, calcium lignosulfonate, calcium silicate hydrates, calcium hydroxide, calcium carbonate, calcium bicarbonate, sodium carbonate, sodium bicarbonate, trona, sodium sesquicarbonate, soda ash, nahcolite, sodium aluminate, and metal oxides.

4. A method according to claim 1, wherein the ammoniacal compound is a member selected from the group consisting of urea, ammonium sulfate, cyanuric acid, ammonia, and organic amines.

5. A method as recited in claim 1, wherein said positioning step includes coating the catalyst on wedge-shaped metal plates prior to positioning the catalyst in the filter bag retainer.

6. A method as recited in claim 1, wherein the positioning step includes situating in an upper portion of the fabric filter bag the catalyst further having a plurality of passages defining a honeycomb shape.

7. A method as recited in claim 6, wherein the situating step includes providing a blow-back tube extending through the catalyst for periodically cleaning the fabric filter bag.

8. A method as recited in claim 1, wherein the positioning step includes situating a catalyst bed between two concentric cylinders with each of the cylinders being constructed of a porous material.

9. A method as recited in claim 1, wherein the positioning step includes situating a catalyst bed in a cylinder that is surrounded coaxially by a second cylinder with both of the cylinders being constructed of a porous material.

10. A method according to claim 1, wherein said pulse jet fabric filter house is at a temperature range between 700°

-850°

F.