UV/EB curable butyl copolymers for lithographic and corrosion-resistant coating applications

• US 5,585,225 A
• Filed: 10/27/1994
• Issued: 12/17/1996
• Est. Priority Date: 12/20/1990
• Status: Expired due to Fees

• Current Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: McElrath, Kenneth O., Audett, Jay D.
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): Codd, Bernard P.
• Application Number:
  US08/298,450
• Time in Patent Office: 782 Days
• Field of Search: 430/286, 430/287, 430/286.1, 430/287.1, 430/18, 430/175, 430/190, 430/195, 430/296, 430/300, 430/323, 430/325, 430/329, 430/270.1, 430/281.1, 430/905, 430/913 , 430/915, 430/916, 522/35, 522/48, 522/53, 522/57, 522/160, 522/904, 522/905
• US Class Current: 430/323
• CPC Class Codes: C08F 210/00 Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 212/06 Hydrocarbons
• CPC Class Codes: C08F 8/00 Chemical modification by after-treatment graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C
• CPC Class Codes: C08L 23/22 Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
• CPC Class Codes: G03F 7/0388 with ethylenic or acetylenic bands in the side chains of the photopolymer
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y10S 430/106 Binder containing
• CPC Class Codes: Y10S 430/114 Initiator containing
• CPC Class Codes: Y10S 430/116 Redox or dye sensitizer
• CPC Class Codes: Y10S 430/117 Free radical
• CPC Class Codes: Y10S 522/904 Monomer or polymer contains initiating group
• CPC Class Codes: Y10S 522/905 Benzophenone group

Abstract

A lithographic coating and method of framing a lithographic image are disclosed. The method comprises coating at least a portion of a surface of an article with a radiation-crosslinkable polymer, and exposing the coated surface to a pattern of radiation to crosslink the polymer in a lithographic image. The functionalized polymer is a copolymer of an isoolefin of 4 to 7 carbon atoms and para-alkylstyrene, wherein the para-alkylstyrene is functionalized with a radiation reactive group at the para-alkyl group of the para-alkylstyrene.

Claims

1. A method for making a lithographic image on a surface, comprising the steps of:

(a) coating at least a portion of a surface of an article with a composition comprising a random copolymer of an isoolefin of 4 to 7 carbon atoms and para-alkylstyrene comonomer, said isoolefin comprising 10 to 99.5 weight % of said copolymer and said para-alkylstyrene comprising 0.5 to 90 weight % of said copolymer, wherein about 0.5 to 55 weight % of said copolymer comprises para-alkylstyrene monomers having a photoinitiator substituted on the pendent alkyl group, said copolymer having a substantially homogenous compositional distribution;

(b) selectively exposing said surface to gamma, UV, thereby forming a crosslinked latent electron beam, visible, or microwave radiation to crosslink the copolymer lithographic image,

(c) removing the uncrosslinked copolymer to develop the lithographic image.

2. The method of claim 1, wherein said removing step comprises washing said surface with a solvent.

3. The method of claim 1, further comprising etching said surface to transfer said image into said surface.

4. The method of claim 3, further comprising the step of removing said crosslinked coating from etched surface.

5. The method of claim 4, wherein said removing step comprises a chemical or plasma treatment of said coating.

6. The method of claim 1, wherein said coating comprises depositing a solution of said polymer on said surface and removing said solvent to leave a film of said polymer on said surface.

7. The method of claim 1, wherein said coating comprises depositing a hot melt of said polymer on said surface.

8. The method of claim 1, wherein said article comprises metal, paper, wood, plastic, textile, glass, ceramic, graphite, or composites thereof.