High temperature stable continuous filament glass ceramic fiber

• US 5,585,312 A
• Filed: 12/21/1995
• Issued: 12/17/1996
• Est. Priority Date: 08/23/1994
• Status: Expired due to Term

• Current Assignee: Unifrax I LLC (ASP Unifrax Holdings, Inc.)
• Original Assignee: Unifrax Corporation (ASP Unifrax Holdings, Inc.)
• Inventors: Clere, Thomas M., Olson, James, TenEyck, John D., Waisala, Steven
• Primary Examiner(s): GROUP, KARL E
• Application Number:
  US08/575,060
• Time in Patent Office: 362 Days
• Field of Search: 501/38, 501/35, 501/69, 188/251 A
• US Class Current: 501/35
• CPC Class Codes: C03C 13/006 Glass-ceramics fibres
• CPC Class Codes: C03C 13/007 containing zirconium
• CPC Class Codes: D04H 1/4218 Glass fibres

Abstract

Composition and process for the preparation of high temperature stable continuous glass ceramic fibers with an upper temperature use limit of 2300° F. are provided. The compositional formulation, in mole percent, is 62-85% SiO₂, 9.5-20% Al₂ O₃, 5-15.5% MgO, 0.5-5% TiO_x, and 0-5% ZrO₂. The continuous fibers are prepared by an economical direct melt method, and demonstrate high tensile strength, high Young'"'"'s modulus, and low linear thermal shrinkage characteristics.

Claims

1. High temperature stable glass fibers consisting essentially of

i) about 67.5 to about 85 mole percent SiO₂,

ii) about 9.5 to about 20 mole percent Al₂ O₃,

iii) about 5 to about 15.5 mole percent MgO,

iv) about 0.5 to about 5 mole percent TiO_x, wherein 0<

x<

2, and

v) 0 to about 5 mole percent ZrO₂.

2. The high temperature stable glass fibers of claim 1, wherein said TiO_x is present in an amount of about 1 to about 2 mole percent.

21. The high temperature stable glass fibers of claim 1, wherein said fibers exhibit thermal shrinkage of less than about 3% at 2300°

F. for 24 hours.

22. The high temperature stable glass fibers of claim 1, wherein ZrO₂ is present in an amount effective to achieve a mean tensile strength of at least about 175 KSi.

23. The high temperature stable glass fibers of claim 22, wherein ZrO₂ is present in the amount of about 1.8 mole percent.

3. High temperature stable continuous filament glass fibers consisting essentially of

i) about 67.5 to about 85 mole percent SiO2,

ii) about 9.5 to about 20 mole percent Al₂ O₃,

iii) about 5 to about 15.5 mole percent MgO,

iv) about 0.5 to about 5 mole percent TiO_x, wherein 0<

x<

2, and

v) 0 to about 5 mole percent ZrO₂.

4. The high temperature stable continuous filament glass fibers of claim 3, wherein said TiO_x is present in an amount of about 1 to about 2 mole percent.

5. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers exhibit thermal shrinkage of less than about 3% at 2300°

F. for 24 hours.

6. The high temperature stable continuous filament glass fibers of claim 3, wherein said TiO_x present in an amount of 1.25-1.5 mole percent.

7. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers exhibit an upper use temperature limit of about 2300°

F.

8. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers exhibit a tensile strength greater than about 250 Ksi.

9. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers exhibit a Young'"'"'s modulus greater than about 12 Msi.

10. The high temperature stable continuous filament glass fibers of claim 3, wherein said fibers consist essentially of about 68 to about 82 mole percent SiO₂, about 10 to about 18 mole percent Al₂ O₃, about 6 to about 14 mole percent MgO, about 1 to about 2 mole percent TiO_x, and 0 to about 3 mole percent ZrO₂.

11. The high temperature stable continuous filament glass fibers of claim 10, wherein said fibers consist essentially of about 72 to about 80 mole percent SiO₂, about 10 to about 16 mole percent Al₂ O₃, about 7 to about 14 mole percent MgO, about 1.25 to about 1.5 mole percent TiO_x, and about 0 to about 2 mole percent ZrO₂.

12. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers are substantially free from shot.

13. The high temperature stable continuous filament glass fibers of claim 3 wherein said fibers have an average diameter of about 5 to about 50 microns.

14. The high temperature stable continuous filament glass fibers of claim 3, wherein said fibers are incorporated into a thermally insulating article selected from the group consisting of woven textile, rope, braid, board, paper, blanket, and mat.

15. The high temperature stable continuous filament glass fibers of claim 3, wherein said fibers are incorporated as a reinforcement into an organic matrix.

16. The high temperature stable continuous filament glass fibers of claim 15, wherein said fiber reinforced matrix forms a friction disc.

17. The high temperature stable continuous filament glass fibers of claim 3 wherein ZrO₂ is present in an mount effective to achieve a mean tensile strength of at least about 175 KSi.

18. The high temperature stable continuous filament glass fibers of claim 13 wherein said fibers have an average diameter of about 5 to about 15 microns.

19. The high temperature stable continuous filament glass fibers of claim 3, wherein said fibers are incorporated as a reinforcement into a matrix of carbon.

20. The high temperature stable continuous filament glass fibers of claim 17, wherein ZrO₂ is present in the amount of about 1.8 mole percent.