High strength composite

• US 5,587,230 A
• Filed: 06/02/1995
• Issued: 12/24/1996
• Est. Priority Date: 10/29/1993
• Status: Expired due to Term

• Current Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Original Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Inventors: Lin, Leroy C., Bhatnagar, Ashok, Li, Hsin L., Wilson, Laura G.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US08/459,133
• Time in Patent Office: 571 Days
• Field of Search: 427/372.2, 427/374.1, 427/389.9, 428/902, 428/911, 428/245, 428/253, 428/255
• US Class Current: 442/135
• CPC Class Codes: C08J 5/04 Reinforcing macromolecular compounds with loose or coherent fibrous material
• CPC Class Codes: C08J 5/24 Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
• CPC Class Codes: F41H 5/0485 all the layers being only fibre- or fabric-reinforced layers
• CPC Class Codes: Y10S 428/902 High modulus filament or fiber
• CPC Class Codes: Y10S 428/911 Penetration resistant layer
• CPC Class Codes: Y10T 428/24124 Fibers
• CPC Class Codes: Y10T 428/249945 Carbon or carbonaceous fiber
• CPC Class Codes: Y10T 428/249946 Glass fiber
• CPC Class Codes: Y10T 428/249947 Polymeric fiber
• CPC Class Codes: Y10T 442/2623 Ballistic resistant

Abstract

An article made from at least one network of high strength fibers and a matrix composition that includes a vinyl ester and diallyl phthalate. Preferably, the article is made from at least one prepreg element which includes at least two adjacent layers of the high strength fiber network in the vinyl ester-containing matrix composition. The prepreg element is made by applying a mixture of vinyl ester, diallyl phthalate and a carbon-carbon saturated solvent to the high strength fiber network.

Claims

1. A method for producing a ballistic resistant article that includes at least one network of high strength fibers in a matrix composition, wherein the high strength fibers have a tenacity of at least about 7 g/d, a tensile modulus of at least about 150 g/d and an energy-to-break of at least about 8 J/g, the method comprising applying a mixture consisting essentially of at least one thermoset vinyl ester, an optional catalyst for curing the thermoset vinyl ester, diallyl phthalate and at least one carbon-carbon saturated solvent having a boiling point lower than about 115°

C. to a high strength fiber network followed by consolidating the coated high strength fiber network at a temperature higher than the boiling point of the solvent and lower than about 120°

C. to substantially remove the carbon-carbon saturated solvent.

2. A method according to claim 1, wherein the carbon-carbon saturated solvent is selected from the group consisting of an alcohol that contains 1 to 5 carbon atoms, a ketone that contains 3 to 10 carbon atoms and an acetate that contains 1 to 5 carbon atoms.

3. A method according to claim 1 wherein the carbon-carbon saturated solvent is selected from the group consisting of methyl ethyl ketone, acetone, ethanol, methanol, isopropyl alcohol, cyclohexane and ethyl acetone.

4. A method according to claim 3, wherein the carbon-carbon saturated solvent is methyl ethyl ketone.

5. A method according to claim 1, wherein the curing catalyst is selected from the group consisting of tert-butyl perbenzoate, 2,5-dimethyl-2,5-di-2-ethylhexanoylperoxyhexane and benzoyl peroxide.

8. A method according to claim 1 wherein the solvent has a boiling point of less than about 90°

C.

9. A method according to claim 1 wherein the consolidating step occurs at a temperature of about 90°

to 120°

C.

10. A method according to claim 1 wherein the consolidating step occurs at a temperature of about 90°

to 100°

C.

14. A ballistic resistant article made in accordance with the method of claim 1.

6. A method for producing a ballistic resistant article that includes at least one network of high strength fibers in a matrix composition, wherein the high strength fibers have a tenacity of at least about 7 g/d, a tensile modulus of at least about 150 g/d and an energy-to-break of at least about 8 J/g, the method comprising coating a high strength fiber network with a solution consisting essentially of at least one thermoset vinyl ester, an optional catalyst for curing the thermoset vinyl ester, diallyl phthalate and at least one carbon-carbon saturated solvent having a boiling point lower than about 115°

C. followed by drying the coated high strength fiber network at a temperature higher than the boiling point of the solvent and lower than about 120°

C. to substantially remove the carbon-carbon saturated solvent.

7. A method according to claim 6 wherein the carbon-carbon saturated solvent is methyl ethyl ketone and the drying step is effected by transporting the coated high strength fiber network through an oven having a length of about 8 to 14 m at a temperature of about 90°

to 120°

C.

11. A method according to claim 6 wherein the solvent has a boiling point of less than about 90°

C.

12. A method according to claim 6 wherein the drying step occurs at a temperature of about 90°

to 120°

C.

13. A method according to claim 12 wherein the drying step occurs at a temperature of about 90°

to 100°

C.

15. A ballistic resistant article made in accordance with the method of claim 6.