Process for liquefaction of a pressurized hydrocarbon-rich fraction

• US 5,588,307 A
• Filed: 11/09/1995
• Issued: 12/31/1996
• Est. Priority Date: 11/11/1994
• Status: Expired due to Fees

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Schmidt, Hans
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/556,192
• Time in Patent Office: 418 Days
• Field of Search: 62/614, 62/636, 62/912
• US Class Current: 62/614
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/0055 originating from an incorporated cascade
• CPC Class Codes: F25J 1/0212 as a single flow MCR cycle
• CPC Class Codes: F25J 2205/66 Regenerating the adsorption vessel, e.g. kind of reactivation gas
• CPC Class Codes: F25J 2220/60 Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2245/90 the recycled stream being boil-off gas from storage
• CPC Class Codes: F25J 2280/02 Control in general, load changes, different modes ("runs"), measurements
• CPC Class Codes: Y10S 62/912 External refrigeration system

Abstract

A pressurized hydrocarbon-rich fraction is cooled and liquefied by heat exchange with the process flows to be heated. Thereafter, the fraction is expanded in an expansion valve and introduced into a storage tank. The flash gas/boil-off gas removed from the storage tank, which optionally forms one of the process flows to be heated, is compressed in one or more stages. The throughput of the flash gas/boil-off gas compressor is kept constant at full load via the position of the expansion valve or expansion turbine controlled by means of a FIC controller. The pressure following expansion valve or expansion turbine is kept substantially constant.

Claims

1. A process for liquefaction of a pressurized gas stream containing hydrocarbons comprising:

cooling and liquefying a pressurized hydrocarbon-rich gas stream by heat exchange with process streams to be heated,

expanding the resultant liquefied stream by means of at least one expansion means into at least one storage tank, and

removing flash gas/boil-off gas stream from said at least one storage tank and compressing said flash gas/boil-off gas stream in at least one compression stage,

wherein throughput of said flash gas/boil-off gas stream in said at least one compression stage is kept constant by controlling the position of said at least one expansion valve or expansion turbine by an FIC controller,

whereby pressure immediately downstream of said at least one expansion means is maintained substantially constant.

2. A process according to claim 1, wherein said flash gas/boil-off gas stream is heated by heat exchange with said hydrocarbon-rich gas stream prior to compression.

3. A process according to claim 2, wherein, before liquefying said hydrocarbon-rich gas stream, components capable of being frozen out are removed from said hydrocarbon-rich gas stream in an adsorption zone and compressed flash gas/boil-off gas is used to regenerate said adsorption zone.

4. A process according to claim 1, wherein, before liquefying said hydrocarbon-rich gas stream, components capable of being frozen out are removed from said hydrocarbon-rich gas stream in an adsorption zone and compressed flash gas/boil-off gas is used to regenerate said adsorption zone.

5. A process according to claim 3, wherein said adsorption zone comprises at least two molecular sieve bed adsorbers, each operated cyclically through adsorption and desorption/regeneration phases.

6. A process according to claim 3, wherein, during cooling of said hydrocarbon-rich gas stream, said hydrocarbon-rich gas stream is delivered to a separator, a C₃₊ hydrocarbon stream is removed from the bottom of said separator, and the remainder of said hydrocarbon-rich gas stream is removed from the top of said separator and cooled by further heat exchange with process streams to be heated prior to being delivered to said at least one storage tank.

7. A process according to claim 6, wherein said C₃₊ hydrocarbon stream is heated by heat exchange with said hydrocarbon-rich gas stream, combined with said compressed flash gas/boil-off gas to form a gas mixture, and said gas mixture is used to regenerate said adsorption zone.

8. A process according to claim 3, wherein carbon dioxide is removed from said hydrocarbon-rich gas stream within said adsorption zone.

9. A process according to claim 5, wherein water is removed from said hydrocarbon-rich gas stream within said adsorption zone.

10. A process according to claim 3, wherein water is removed from said hydrocarbon-rich gas stream within said adsorption zone.

11. A process according to claim 1, wherein during cooling of said hydrocarbon-rich gas stream, said hydrocarbon-rich gas stream is delivered to a separator, a C₃₊ hydrocarbon stream is removed from the bottom of said separator, and the remainder of said hydorcarbon-rich gas stream is removed from the top of said separator and cooled by further heat exchange with process streams to be heated prior to being delivered to said at least one storage tank.

12. A process according to claim 8, wherein said C₃₊ hydrocarbon stream removed from the bottom of said separator is expanded and then subjected to heat exchange with said pressurized hydrocarbon-rich gas stream.

13. A process according to claim 1, wherein said flash gas/boil-off gas is compressed in multiple stages and cooled in a heat exchanger after each compression stage.

14. A process according to claim 1, wherein said hydrocarbon-rich gas stream is pressurized natural gas.

15. A process according to claim 1, wherein said at least one expansion means is at least one expansion valve.

16. A process according to claim 1, wherein said at least one expansion means is at least one expansion turbine.

17. A process according to claim 14, wherein said at least one expansion means is two expansion turbines.

18. A process according to claim 1, wherein said pressurized hydrocarbon-rich gas stream has a pressure of 20-70 bar and a temperature of 20°

-40°

C. prior to said heat exchange with process streams to be heated.

19. A process according to claim 1, wherein said pressurized hydrocarbon-rich gas stream has a hydrocarbon content of 80-99 mole %.

20. A process according to claim 1, wherein the pressure in said at least one storage tank is 1.01-1.10 bar.

21. A process according to claim 1, wherein said pressurized hydrocarbon-rich gas stream also undergoes heat exchange with a refrigeration circuit during said cooling and liquefying.