Fuel additive concentrate with enhanced storage stability

• US 5,591,237 A
• Filed: 12/26/1995
• Issued: 01/07/1997
• Est. Priority Date: 12/26/1995
• Status: Expired due to Fees

• Current Assignee: Ethyl Corporation (Newmarket Corporation)
• Original Assignee: Ethyl Corporation (Newmarket Corporation)
• Inventors: Bell, Donald R.
• Primary Examiner(s): Medley, Margaret
• Application Number:
  US08/578,414
• Time in Patent Office: 378 Days
• Field of Search: 44/326, 44/324, 44/325, 44/331, 44/389, 44/457, 44/458
• US Class Current: 44/325
• CPC Class Codes: C10L 1/10 containing additives
• CPC Class Codes: C10L 1/1225 halogen containing compounds
• CPC Class Codes: C10L 1/1266 nitrogen containing compounds, (e.g. NH3)
• CPC Class Codes: C10L 1/1855 Cyclic ethers, e.g. epoxides, lactides, lactones
• CPC Class Codes: C10L 1/1881 carboxylic group attached to an aliphatic carbon atom
• CPC Class Codes: C10L 1/1883 polycarboxylic acid
• CPC Class Codes: C10L 1/1888 tall oil
• CPC Class Codes: C10L 1/19 Esters ester radical containing compounds; ester ethers; carbonic acid esters C10L1/1802, C10L1/1805, C10L1/1808, C10L1/1811, C10L1/1814, C10L1/1817 take precedence
• CPC Class Codes: C10L 1/224 Amides; Imides carboxylic acid amides, imides C10L1/221, C10L1/2227 take precedence
• CPC Class Codes: C10L 1/231 nitro compounds; nitrates; nitrites C10L1/221 takes precedence
• CPC Class Codes: C10L 1/232 containing nitrogen in a heterocyclic ring C10L1/221 takes precedence
• CPC Class Codes: C10L 1/2383 Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C) C10L1/221 takes precedence
• CPC Class Codes: C10L 10/04 for minimising corrosion or incrustation

Abstract

A fuel additive concentrate package comprising a detergent/dispersant, an organic nitrate combustion improver, and a corrosion inhibitor comprising dimer and/or trimer acid is provided enhanced shelf life stability by treating the concentrate with a shelf life stability amount, for example 1,500 and 10,000 ppm, respectively of acid selected from the group consisting of nitric acid/hydrochloric acid.

Claims

1. In a fuel additive concentrate package comprising a detergent/dispersant, an organic nitrate combustion improver, and a corrosion inhibitor comprising dimer and/or trimer acid, the improvement wherein said concentrate additionally comprises a shelf life stability amount of acid selected from the group consisting of nitric acid and hydrochloric acid, said shelf life stability amount of acid being sufficient to provide enhanced shelf life stability to said concentrate.

2. A concentrate according to claim 1 wherein the detergent/dispersant is a reaction product of (i) an alkyl or alkenyl substituted succinic acid or anhydride and (ii) an alkylenepolyamine or mixture of alkylenepolyamines wherein the alkyl or alkenyl group of the substituted succinic acid or anhydride contains from about 10 to about 1000 carbon atoms and wherein the organic nitrate combustion improver comprises a nitrate ester of a substituted or unsubstituted aliphatic or cycloaliphatic alcohol.

3. A concentrate according to claim 2 wherein said acid is nitric acid.

4. A concentrate according to claim 3 wherein said acid is about 1,500 parts per million based on weight of the concentrate.

5. A concentrate according to claim 2 wherein the organic nitrate combustion improver comprises an alkyl nitrate having from 5 to 10 carbon atoms selected from the group consisting of primary amyl nitrates, primary hexyl nitrates, and octyl nitrates and mixtures thereof.

6. A concentrate according to claim 5 wherein the organic nitrate combustion improver is 2-ethylhexyl nitrate.

7. A concentrate according to claim 5 said acid is nitric acid in an amount of about 1,500 parts per million based on weight of the concentrate.

8. A concentrate according to claim 2 wherein the detergent/dispersant comprises the reaction product of (i) an alkyl or alkenyl substituted succinic acid or anhydride wherein the alkyl or alkenyl group has a number average molecular weight in the range of from about 750 to about 2300 and (ii) an alkylenepolyamine or mixture of alkylenepolyamines approximating tetraethylene pentamine and wherein the organic nitrate combustion improver comprises a nitrate ester of at least one primary alkanol having up to 10 carbon atoms in the molecule.

9. A concentrate according to claim 8 wherein the organic nitrate combustion improver comprises an alkyl nitrate having from 5 to 10 carbon atoms selected from the group consisting of primary amyl nitrates, primary hexyl nitrates, and octyl nitrates and mixtures thereof.

10. A concentrate according to claim 9 wherein said acid is nitric acid.

11. A concentrate according to claim 10 wherein said shelf life stability amount of acid is about 1,500 parts per million based on weight of the concentrate.

12. A method for enhancing the shelf-life stability of a fuel additive concentrate package which comprises a detergent/dispersant, an organic nitrate combustion improver, and a corrosion inhibitor comprising dimer and/or trimer acid, the method comprising admixing a shelf life stability amount of acid selected from the group consisting of nitric acid and hydrochloric acid, with said concentrate, said shelf life stability amount of acid being sufficient to provide enhanced shelf life stability to said concentrate.

13. The method of claim 12 wherein the detergent/dispersant is a reaction product of (i) an alkyl or alkenyl substituted succinic acid or anhydride and (ii) a alkylenepolyamine or mixture of alkylenepolyamines wherein the alkyl or alkenyl group of the substituted succinic acid or anhydride contains from about 10 to about 1000 carbon atoms and wherein the organic nitrate combustion improver comprises a nitrate ester of a substituted or unsubstituted aliphatic or cycloaliphatic alcohol.