Conductive polyurethane foam and its manufacture

• US 5,591,482 A
• Filed: 02/17/1994
• Issued: 01/07/1997
• Est. Priority Date: 02/17/1993
• Status: Expired due to Fees

• Current Assignee: Inoac Corporation (Inoue Rubber Public Company Limited)
• Original Assignee: Inoac Corporation (Inoue Rubber Public Company Limited)
• Inventors: He, Fei-feng, Yamamoto, Miwako, Yamamoto, Toshihiro
• Primary Examiner(s): DUDASH, DIANA L
• Application Number:
  US08/197,983
• Time in Patent Office: 1,055 Days
• Field of Search: 427/244, 427/255.6, 427/296, 427/301, 427/316, 427/352, 427/322
• US Class Current: 427/244
• CPC Class Codes: C08G 61/124 with a five-membered ring containing one nitrogen atom in the ring
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/405 with polymerisable compounds
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes

Abstract

A method of manufacturing a conductive polyurethane foam in which the polymerization is made easy, the refinement of pyrrole or the like is not required, the recovery rate of a solvent is enhanced, and the pre-treatment is not required at all; and a conductive polyurethane foam having excellent performances. This method includes a process: of coating an oxidizer solution (methanol solution containing FeCl₃ and FeCl₂) on surfaces of cells of a soft polyurethane foam; a process of perfectly removing the solvent of the oxidizer solution by vacuum drying; a process of polymerizing a compound (pyrrole or the like) with conjugated double bonds on the surfaces of cells of the continuous forming type polyurethane foam after being coated with the oxidizer in a vapor-phase atmosphere for forming a conductive electronic conjugated polymer layer (polypyrrole layer or the like) of the compound on the surfaces of the cells; a process of dipping the polyurethane foam formed with the polymer layer in a solvent for extracting the pyrrole and the oxide; and a process for vacuum-drying it. A conductive polyurethane foam can be continuously manufactured by this process. The conductive polyurethane foam thus manufactured has an electric conductivity ranging from 10^-7 to 10^-2 S/cm.

Claims

1. A method of manufacturing a conductive polyurethane foam comprising the steps of:

coating an oxidizer solution on surfaces of cells of a polyurethane foam having a plurality of open cells which are connected to each other;

perfectly removing a solvent of said oxidizer solution by vacuum drying;

polymerizing a compound with conjugated double bonds on the surfaces of the cells of said polyurethane foam, after said cells have been coated with said oxidizer in a vapor-phase atmosphere to form a conductive conjugated polymer layer of said compound on the oxidizer-coated surfaces of said cells; and

dipping said polyurethane foam formed with said polymer layer in an organic solvent which does not dissolve said polyurethane foam to extract any unpolymerized portion of said compound and said oxidizer, followed by vacuum drying.

2. A method of manufacturing a conductive polyurethane foam according to claim 1, wherein said compound with conjugated double bonds comprises pyrrole N-methylpyrrole, N-ethylpyrrole, N-phenylpyrrole, 3, 5-dimethylpyrrole, 3-methoxypyrrole or 3-methyl N-methylpyrrole.

3. A method of manufacturing a conductive polyurethane foam according to claim 2, wherein said oxidizer solution contains FeCl₂ and FeCl₃.

4. A method of manufacturing a conductive polyurethane foam according to claim 3, wherein a mole ratio of FeCl₂ to FeCl₃ is in the range of 0.05-0.5 in said oxidizer solution.

5. A method of manufacturing a conductive polyurethane foam according to claim 4, wherein an amount of FeCl₃ coated on the surface of said polyurethane foam is in the range of 60-160 parts by weight on the basis of 100 parts by weight on the basis of 100 parts by weight of said polyurethane foam, in said oxidizer solution.

6. A method of manufacturing a polyurethane foam according to claim 3, wherein a mole fraction of FeCl₂ to FeCl₃ is in the range of 0.14-0.3, the polymerizing reaction time is in the range of 4-8 hrs, the polymerizing reaction temperature is in the range of 0-20°

C. and an amount of FeCl₃ coated on the surface of said polyurethane foam is in the range of 60-160 parts by weight on the basis of 100 parts by weight of said polyurethane foam.

7. A method of manufacturing a polyurethane foam according to claim 2, wherein said oxidizer solution contain FeCl₃, and the polymerizing reaction temperature is in the range of 0-10°

C.

13. A method of manufacturing a conductive polyurethane foam according to claim 1, wherein said organic solvent is methanol, ethanol, or isopropyl alcohol.

8. A method of manufacturing a conductive polyurethane foam, which is performed by carrying a continuous foaming polyurethane foam sheet, said method comprising the steps of:

coating an oxidizer solution on surfaces of cells of said polyurethane foam sheets, wherein said sheet has a plurality of open cells which are connected to each other;

perfectly removing a solvent of said oxidizer solution by vacuum drying said polyurethane foam sheet coated with said oxidizer solution;

polymerizing a compound with conjugated double bonds on the surfaces of the cells of said polyurethane foam, after said cells have been coated with said oxidizer, in a vapor-phase atmosphere to form a conductive conjugated polymer layer of said compound on the oxidizer-coated surfaces of said cells;

dipping said polyurethane foe sheet in an organic solvent which does not dissolve said polyurethane foam to extract any unpolymerized portion of said compound and said oxidizer solution; and

removing said organic solvent by vacuum drying said polyurethane foam sheet formed with said polymer.

9. A method of manufacturing a conductive polyurethane foam according to claim 8, wherein said compound with conjugated double bonds comprises pyrrole, N-methylpyrrole, N-ethylpyrrole, N-phenylpyrrole, 3, 5-dimethylpyrrole, 3-methoxypyrrole, 3-methyl-N-methylpyrrole.

10. A method of manufacturing a conductive polyurethane foam according to claim 9, wherein said oxidizer solution contains FeCl₂ and FeCl₃, and a mole fraction of FeCl₂ to FeCl₃ is in the range of 0.05-0.5 in said oxidizer solution.

11. A method of manufacturing a polyurethane foam according to claim 9, wherein mole fraction of FeCl₂ to FeCl₃ is in the range of 0.14-0.3, the polymerizing reaction time is in the range of 4-8 hrs, the polymerizing reaction temperature is in the range of 0-20°

C., and an amount of FeCl₃ coated on the surface of said polyurethane foam is in the range of 60-160 parts by weight on the basis of 100 parts by weight of said polyurethane foam.

12. A method of manufacturing a polyurethane foam according to claim 9, wherein said oxidizer solution contains FeCl₃, and the polymerizing reaction temperature is in the range of 0-10°

C.

14. A method of manufacturing a conductive polyurethane foam according to claim 8, wherein said organic solvent is methanol, ethanol, or isopropyl alcohol.