Metal complexes for use as gas generants

• US 5,592,812 A
• Filed: 02/09/1996
• Issued: 01/14/1997
• Est. Priority Date: 01/19/1994
• Status: Expired due to Term

• Current Assignee: Northrop Grumman Innovation Systems, Inc. (Northrop Grumman Corporation)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Doll, Daniel W., Lund, Gary K., Blau, Reed J., Hinshaw, Jerald C.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/599,634
• Time in Patent Office: 340 Days
• Field of Search: 60/205, 60/219, 149/36, 149/45, 149/46, 149/61, 149/75, 149/76, 149/77, 280/741
• US Class Current: 60/205
• CPC Class Codes: C06B 29/00 Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
• CPC Class Codes: C06B 31/00 Compositions containing an inorganic nitrogen-oxygen salt
• CPC Class Codes: C06B 41/00 Compositions containing a nitrated metallo-organic compound
• CPC Class Codes: C06B 43/00 Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a cationic metal template, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand containing hydrogen and nitrogen. The complexes are formulated such that when the complex combusts nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. Such complexes are adaptable for use in gas generating devices such as automobile air bags.

Claims

1. A method for inflating an inflatable air bag which comprises the steps of:

generating substantially non-toxic gas consisting essentially of nitrogen gas and water vapor by combusting an at least essentially azide-free composition adapted for generating gas for use in inflating an air bag which comprises a metal ammine complex having a metal cation of a transition metal or an alkaline earth metal, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand comprising ammonia; and

inflating said air bag using said gas.

10. A method according to claim 1, 2 or 3, wherein said metal cation is a cation of a metal is selected from the group consisting of magnesium, manganese, nickel, vanadium, copper, chromium, zinc, rhodium, iridium, ruthenium, palladium, and platinum.

11. A method according to claim 1, 2, 3, 4, 5, 7 or 8, wherein said metal cation is of a metal selected from the group consisting of manganese, magnesium, cobalt and zinc.

12. A method according to claim 1, 2, 3, 4, 5, 7 or 8, wherein said metal cation is a cobalt cation.

13. A method according to claim 1, 2 or 3, wherein said metal ammine complex is at least one member selected from the group consisting of metal ammine nitrates, metal ammine nitrites, and metal ammine perchlorates, and said metal cation is of a metal selected from the group consisting of magnesium, manganese, nickel, vanadium, copper, chromium, zinc, rhodium, iridium, ruthenium, palladium, and platinum.

18. A method according to claim 1, 2, or 3, wherein the combustion is capable of producing an excess of fuel, and wherein an effective amount of additional oxidizing agent is provided to effect complete and efficient combustion during said generating step.

19. A method according to claim 1, 2 or 3, wherein the combustion is capable of producing an excess of fuel, and wherein said gas generant composition includes an effective amount of additional oxidizing agent to effect complete and efficient combustion during said generating step, and said oxidizing agent is other than said metal ammine complex and is at least one member selected from the group consisting of nitrates, nitrites, chlorates, perchlorates, peroxides, and metal oxides.

21. A method according to claim 1, 2, or 3, wherein the combustion is capable of producing an excess of oxidizing species during the combustion, and wherein said gas generant composition includes an effective amount of additional fuel to effect complete and efficient combustion during said generating step.

2. A method for inflating an inflatable air bag or balloon which comprises the steps of

generating substantially non-toxic gas comprised of nitrogen gas and water vapor by combusting a gas generant composition which consists essentially of at least one metal ammine complex which contains a metal cation of a transition metal or an alkaline earth metal, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand comprising ammonia;

and

inflating said air bag or balloon using said gas.

3. An at least essentially azide-free method for deploying an inflatable air bag from a supplemental safety restraint system which contains said air bag and a gas generating device, which contains an least essentially azide-free gas generant composition, for generating gas which can be used for inflating said air bag, said method comprising the steps of:

generating substantially non-toxic gas consisting essentially of nitrogen gas and water vapor by combusting an at least essentially azide-free gas generant composition comprising a metal ammine complex which comprises a metal cation of a transition metal or alkaline earth metal, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand comprising ammonia; and

inflating said air bag using said gas.

4. A method according to claim 3, wherein said method further comprises combining said generated gas with an inert gas and inflating said air bag with said combination of gases.

5. A method according to claim 3, wherein said air bag is inflated with said generated gas.

6. A method according to claim 3, 4 or 5, wherein said metal ammine complex is at least one member selected from the group consisting of metal ammine nitrites, metal ammine nitrates and metal ammine perchlorates.

7. A method according to claim 3, wherein said complex is a metal ammine nitrite.

8. A method according to claim 3, wherein said complex is a metal ammine nitrate.

9. A method according to claim 3, wherein said complex is a metal ammine perchlorate.

14. A method according to claim 3, 4 or 5, wherein said metal ammine complex comprises at least one complex represented by a formula selected from the group consisting of [Co(NH₃)₄ (NO₂)₂ ](NO₂), Co(NH₃)₂ (NO₃)₃, Co(NH₃)₄ Co(NO₂)₆, and Co(NH₃)₃ (NO₂)₃.

15. A method according to claim 3, wherein the combustion of the complex is stoichiometric to a metal or metal oxide, nitrogen, and water.

16. A method according to claim 3, wherein said method further comprises initiating the combustion of the metal complex using heat.

17. A method according to claim 3, wherein said oxidizing anion is substantially free of carbon and said gas is substantially free of carbon dioxide and carbon monoxide.

20. A method according to claim 3, wherein said anion is coordinated with said transition metal.

22. An at least essentially azide-free method for deploying an inflatable air bag from a supplemental safety restraint system in a vehicle wherein said system includes a gas generating device, which contains an least essentially azide-free gas generant composition, for generating gas useful for inflating said air bag, said method comprising the steps of:

generating a substantially non-toxic gas consisting essentially of nitrogen gas and water vapor by igniting and combusting said gas generant composition, said gas generant composition consisting essentially of at least one metal ammine complex which comprises a metal cation of a transition metal or alkaline earth metal, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand comprising ammonia; and

inflating said inflatable air bag using said gas.