Process and apparatus for the recovery of pure argon

• US 5,592,833 A
• Filed: 02/23/1995
• Issued: 01/14/1997
• Est. Priority Date: 02/24/1994
• Status: Expired due to Fees

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Moll, Anton
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/393,388
• Time in Patent Office: 691 Days
• Field of Search: 62/22, 62/24, 62/41
• US Class Current: 62/648
• CPC Class Codes: F25J 2235/58 the fluid being argon or crude argon
• CPC Class Codes: F25J 2250/02 Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger
• CPC Class Codes: F25J 2250/20 Boiler-condenser with multiple exchanger cores in parallel or with multiple re-boiling or condensing streams
• CPC Class Codes: F25J 3/04412 in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
• CPC Class Codes: F25J 3/04678 cooled by oxygen enriched liquid from high pressure column bottoms
• CPC Class Codes: F25J 3/04727 using an auxiliary pure argon column for nitrogen rejection F25J3/04739 takes precedence
• CPC Class Codes: F25J 3/04884 Arrangement of reboiler-condensers
• CPC Class Codes: F25J 3/04921 within the same column
• CPC Class Codes: Y10S 62/906 Packing
• CPC Class Codes: Y10S 62/924 Argon

Abstract

In recovering pure argon product, air is separated in a rectification system, comprising at least one air separating column (9), a crude argon column (17) and a pure argon column (25). A crude argon fraction (24) is withdrawn from the crude argon column (17) and introduced at an intermediate locality into the pure argon column (25). The head of the pure argon column (25) is cooled by indirect heat exchange (29). From the pure argon column (25) a residual fraction (31) containing essentially nitrogen is withdrawn overhead and from the bottom a pure argon fraction (26) is withdrawn. The mass transfer in the pure argon column (25) is brought about at least in part by a packing (33, 34).

Claims

1. A process for recovering argon comprising:

separating air in at least one air separation column to provide a product oxygen stream and a product nitrogen stream,

withdrawing an argon-containing oxygen stream from said air separation column and introducing said argon-containing oxygen stream into a crude argon column,

withdrawing a crude argon fraction from said crude argon column and introducing said crude argon fraction at an intermediate point into a pure argon column,

cooling the head of said pure argon column by indirect heat exchange, and

withdrawing from an upper region of said pure argon column a residual nitrogen-containing fraction and withdrawing from a lower region of said pure argon column a pure argon fraction,

wherein mass transfer in said pure argon column is brought about, at least in part, by a packing contained therein.

2. A process according to claim 1, wherein mass transfer in said pure argon column, above the intermediate point at which said crude argon fraction is introduced, is performed at least in part by packing contained in said pure argon column.

3. A process according to claim 2, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by trays.

4. A process according to claim 3, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed substantially exclusively by trays.

5. A process according to claim 2, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by packing.

6. A process according to claim 2, wherein mass transfer in said pure argon column, above the intermediate point at which said crude argon fraction is introduced, is performed substantially exclusively by packing.

7. A process according to claim 6, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by trays.

8. A process according to claim 7, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed substantially exclusively by trays.

9. A process according to claim 6, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by packing.

10. A process according to claim 1, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by trays.

11. A process according to claim 10, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed substantially exclusively by trays.

12. A process according to claim 1, wherein mass transfer in said pure argon column, below the intermediate point at which said crude argon fraction is introduced, is performed at least in part by packing.

13. A process according to claim 1, wherein mass transfer in the entirety of said pure argon column is substantially exclusively brought about by packing.

14. A process according to claim 1, wherein said indirect heat exchange for cooling the head of said pure argon column is carried out by means of a cooling medium having an oxygen content of at least 10%.

15. A process according to claim 14, wherein said cooling medium is withdrawn from an intermediate region of said at least one air separation column.

16. A process according to claim 14, wherein said cooling medium is withdrawn from a lower region of said at least one air separation column.

17. A process according to claim 16, wherein said at least one air separation column is a double column comprising a high pressure column and a low pressure column, and said cooling medium is withdrawn from a lower region of said high pressure column.

18. A process according to claim 17, wherein sump liquid collected in the lower region of said high pressure column is employed as said cooling medium.

19. A process according to claim 16, wherein said at least one air separation column is a double column comprising a high pressure column and a low pressure column, and said cooling medium is withdrawn from an intermediate region of said high pressure column.

20. An apparatus comprising:

at least one air separation column having an inlet for introduction of air, a first outlet for removal of an oxygen-containing stream and a second outlet for removal of a nitrogen-containing stream,

conduit means in fluid communication with said air separation column and with a crude argon column,

a pure argon column having a first outlet in a lower region thereof for removal of an argon stream and a second outlet in an upper region thereof for removal of a nitrogen-containing stream,

said crude argon column and an intermediate point of said pure argon column being connected by a crude argon duct, and

wherein said pure argon column contains at least one packing.

21. An apparatus according to claim 20, further comprising a heat exchanger connected to the upper region of said pure argon column by way of a vapor duct and by way of a condensate duct, and a cooling medium duct which is connected to said heat exchanger and to a source of cooling medium having an oxygen content of at least 10%.