Portable hydrogen generator

• US 5,593,640 A
• Filed: 06/07/1995
• Issued: 01/14/1997
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Ball Corporation
• Original Assignee: Ball Corporation
• Inventors: Schmidt, Jeff, Long, Eugene, Lynch, Frank
• Primary Examiner(s): MCMAHON, TIMOTHY M
• Application Number:
  US08/476,729
• Time in Patent Office: 587 Days
• Field of Search: 422/129, 422/111, 422/239, 423/657, 48/61, 48/4, 48/197 R
• US Class Current: 422/111
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen generator employs substantially adiabatic hydrolysis and thermal decomposition of chemical hydrides to provide a controllable generation of hydrogen from a small, lightweight container. The hydrogen generator includes a thermally isolated container for containing a chemical hydride, a preheater to heat the chemical hydride to a predetermined temperature before the chemical hydride is hydrolyzed, a water supply controlled to maintain substantially adiabatic and controlled generation of hydrogen from said chemical hydride, and a buffer to supply an initial flow of hydrogen during generator start-up, absorb excess hydrogen during generator shut-down, and to smooth the hydrogen flow due to changing loads.

Claims

1. A hydrogen generator, comprising:

a thermally isolated container;

a first chemical hydride placed in said thermally isolated container;

heating means for heating said first chemical hydride to a predetermined temperature;

a water supply for hydrolysis of said first chemical hydride only after said first chemical hydride reaches said predetermined temperature;

buffer means for recovering hydrogen from said container; and

control means for controlling the rate of hydrogen generation by said hydrogen generator.

2. The hydrogen source of claim 1, wherein said thermally isolated container comprises a dewar having an outer shell and an inner vessel defining a vacuum space therebetween, and having thermal insulation positioned in said vacuum space.

3. The hydrogen generator of claim 1, wherein said first chemical hydride comprises a metal hydride.

4. The hydrogen generator of claim 3, wherein said metal hydride comprises at least one metal taken from a group consisting of the metals found in the first three rows of the periodic chart.

5. The hydrogen generator of claim 4, wherein said metal hydride is a ternary composition.

6. The hydrogen generator of claim 5, wherein said ternary composition consists essentially of LiAlH₄.

7. The hydrogen generator of claim 6, wherein said heating means heats said LiAlH₄ to a temperature greater than about 100 degrees C.

8. The hydrogen generator of claim 1, wherein said heating means comprises a second chemical hydride positioned in said container between said first chemical hydride and said water source for generating an exothermic reaction when said second chemical hydride is combined with water.

9. The hydrogen generator of claim 8, wherein said second chemical hydride comprises a metal hydride.

10. The hydrogen generator of claim 9, wherein said metal hydride consists essentially of CaH₂ or other similar hydrides.

11. The hydrogen generator of claim 1, wherein said heating means comprises an electrical heater.

12. The hydrogen generator of claim 1, wherein said water supply comprises:

a water source;

a water pump hydraulically coupled to said water source and electrically coupled to said control means; and

a water conduit coupled between said water pump and said container.

13. The hydrogen generator of claim 12, wherein said water source further comprises an annular filter positioned in said container adjacent an outlet of said water conduit.

14. The hydrogen generator of claim 13, wherein said second chemical hydride further comprises a compressible porous medium positioned between said annular filter and said first chemical hydride to prevent liquid water from hydrating said first chemical hydride while a temperature of said first chemical hydride is below said predetermined temperature.

15. The hydrogen generator of claim 1, wherein said buffer means comprises:

an outlet conduit coupled to said container;

a buffer chamber coupled to said outlet conduit; and

a rechargeable hydride positioned in said buffer chamber.

16. The hydrogen generator of claim 15, wherein said rechargeable hydride supplies hydrogen to said outlet conduit when said first chemical hydride is being heated by said heating means, and absorbs excess hydrogen after said hydrolysis is stopped by said control means from hydrolyzing said first chemical hydride.

17. The hydrogen generator of claim 16, wherein said rechargeable hydride comprises a metal hydride.

18. The hydrogen generator of claim 1, wherein said control means comprises a pressure switch coupled to said container for sensing a hydrogen pressure in said container, and for generating a signal corresponding to said hydrogen pressure, said pressure switch being electrically coupled to said water supply for supplying control signals thereto.

19. A hydrogen generator, comprising:

a thermally isolated container;

a water source having a water conduit for supplying water into said container;

a first chemical hydride placed in said container;

a control for operation of said water source;

a chemical composition positioned in said container between said first chemical hydride and an outlet of said water conduit, said chemical composition including components to react exothermically with water supplied into said container to heat said first chemical hydride,

said control operating said water source to supply water to said container, prior to hydrolysis of said first chemical hydride, to generate within said container a temperature sufficient to prevent said first chemical hydride from forming unstable products when said first chemical hydride is hydrolyzed and thereafter at a rate to maintain an adiabatic generation of hydrogen by said first chemical hydride; and

recovery means for recovering hydrogen from said container.

20. The hydrogen source of claim 19, wherein said thermally isolated container comprises a dewar having an outer shell and an inner vessel defining a vacuum space therebetween, and having a thermal insulating material positioned in said vacuum space.

21. The hydrogen generator of claim 19, wherein said first chemical hydride comprises a metal hydride.

22. The hydrogen generator of claim 21, wherein said metal hydride comprises at least one metal taken from a group consisting of the metals found in the first three rows of the periodic chart.

23. The hydrogen generator of claim 22, wherein said metal hydride comprises a ternary composition.

24. The hydrogen generator of claim 23, wherein said ternary composition consists essentially of LiAlH₄.

25. The hydrogen generator of claim 19, wherein said chemical composition generates sufficient heat to raise the temperature of said LiAlH₄ above about 100 degrees C. prior to the hydrolysis of said LiAlH₄.

26. The hydrogen generator of claim 19, wherein said mixture of components of said chemical composition comprise:

a second chemical hydride; and

a compressible porous medium.

27. The hydrogen generator of claim 26, wherein said second chemical hydride, when hydrolyzed, generates an exothermic reaction and exhibits stable hydrogen generation characteristics while at a temperature below about 590 degrees C.

28. The hydrogen generator of claim 26, wherein said second chemical hydride comprises a metal hydride.

29. The hydrogen generator of claim 28, wherein said chemical hydride consists essentially of CaH₂ or other similar hydride.

30. The hydrogen generator of claim 26, wherein said compressible porous medium comprises vermiculite.

31. The hydrogen generator of claim 19, wherein said recovery means comprises:

a hydrogen conduit coupled to said container;

a buffer chamber coupled to said hydrogen conduit; and

a rechargeable hydride positioned in said buffer chamber.

32. The hydrogen generator of claim 31, wherein said rechargeable hydride comprises a metal hydride.

33. The hydrogen generator of claim 31, wherein said rechargeable hydride supplies hydrogen to said hydrogen conduit when said first chemical hydride is being heated by said chemical composition, and absorbs excess hydrogen generated after said water source is stopped from supplying water to said container.

34. The hydrogen generator of claim 19, wherein said control means comprises a pressure switch coupled to said hydrogen conduit, said pressure switch sensing a pressure of said hydrogen to generate a signal corresponding to said pressure of said hydrogen, and said pressure switch being coupled to said water source to control a flow of water to said container based on said pressure signal.

35. A hydrogen generator, comprising:

a thermally isolated container;

a first chemical hydride placed in said container;

a water supply for hydrolysis of said first chemical hydride, said water supply including a water source for supplying water into said container via a water conduit;

a hydrogen conduit coupled to said container for supplying a flow of hydrogen from said container;

control means for controlling the supply of water to said container to obtain an adiabatic generation of hydrogen from said first chemical hydride; and

buffer means coupled to said hydrogen conduit, said buffer means containing a rechargeable hydride for generating hydrogen upon initial start-up of said hydrogen generator, and for absorbing excess hydrogen generated after said water source is stopped from supplying water into said container containing said first chemical hydride.

36. The hydrogen generator of claim 35, wherein said first chemical hydride comprises at least one metal taken from a group consisting of the metals found in the first three rows of the periodic chart.

37. The hydrogen generator of claim 35, wherein said first chemical hydride consists of LiAlH₄.

38. The hydrogen generator of claim 35, wherein said buffer means comprises a receptacle containing said rechargeable hydride.

39. The hydrogen generator of claim 38, wherein said rechargeable hydride comprises a metal hydride.

40. The hydrogen generator of claim 35, further comprising preheating means to preheat the first chemical hydride to a predetermined acceptable temperature prior to hydrolysis of said first chemical hydride.

41. The hydrogen generator of claim 40 wherein said preheating means comprises a chemical composition positioned in said container between said first chemical hydride and an outlet of said water conduit, said chemical composition including components to react with water supplied to said container to heat said first chemical hydride, and to delay the flow of water to said first chemical hydride until the first chemical hydride has reached a predetermined temperature sufficient to prevent said first chemical hydride from undergoing an unstable exothermic reaction when said first chemical hydride is hydrolyzed.

42. The hydrogen generator of claim 41, wherein said chemical composition comprises a metal hydride.

43. The hydrogen generator of claim 40, wherein said metal hydride consists essentially of CaH₂ or other similar hydrides.

44. The hydrogen generator of claim 35, further comprising an electrical heater coupled to said container for heating said first chemical hydride to a predetermined temperature prior to hydrolysis of said first chemical hydride.

45. A small, lightweight, controllable hydrogen generator, comprising:

a container forming a dewar having an outer shell and an inner vessel defining a vacuum space therebetween, and having thermal insulating material positioned in said vacuum space;

a first chemical hydride placed in said inner vessel;

heating means for heating said first chemical hydride to a predetermined temperature sufficient to prevent said first chemical hydride from undergoing unstable reactions when hydrolyzed;

a water supply for hydrolysis of said first chemical hydride only after a temperature of said first chemical hydride reaches said predetermined temperature, said water supply including a water pump for supplying water into said inner vessel via a water conduit;

a hydrogen conduit coupled to said inner vessel for supplying a flow of hydrogen from said inner vessel;

control means for controlling said water pump and the generation of hydrogen; and

buffer means coupled to said inner vessel, said buffer means containing a rechargeable hydride for generating hydrogen prior to the temperature of said first chemical hydride reaching said predetermined temperature, for absorbing excess hydrogen after said water pump is stopped from supplying water to said container, and for smoothing the hydrogen flow due to changing load demands.

46. The hydrogen generator of claim 45, wherein said first chemical hydride comprises at least one metal taken from a group consisting of the metals found in the first three rows of the periodic chart.

47. The hydrogen generator of claim 46, wherein said first chemical hydride consists of LiAlH₄.

48. The hydrogen generator of claim 47, wherein said heating means comprises a chemical composition positioned in said inner vessel between said first chemical hydride and an outlet of said water conduit, said chemical composition including components to react exothermically with water supplied into said inner vessel to heat said first chemical hydride,

said control operating said water pump to deliver an initial supply of water to said inner vessel prior to the hydrolysis of said first chemical hydride to generate within said inner vessel a temperature sufficient to prevent said first chemical hydride from forming an unstable product when said first chemical hydride is hydrolyzed.

49. The hydrogen generator of claim 48, wherein said chemical composition components comprise a metal hydride and vermiculite.

50. The hydrogen generator of claim 49, wherein said metal hydride consists essentially of CaH₂ or other similar hydrides.

51. The hydrogen generator of claim 45, wherein said heating means includes a chemical compound having a chemical component providing an exothermic reaction with water, wherein said compound includes a mixture of compressible porous medium and chemical hydrides positioned between an outlet of said water conduit and said first chemical hydride to prevent liquid water from forming undesirable products in said first chemical hydride while a temperature of said first chemical hydride is below said predetermined temperature.

52. The hydrogen generator of claim 45, wherein said heating means comprises an electrical heater.

53. The hydrogen generator of claim 45, wherein said buffer means comprises a receptacle coupled to said hydrogen conduit, wherein said receptacle contains said rechargeable hydride.

54. The hydrogen generator of claim 45, wherein said rechargeable hydride comprises a metal hydride.