Apparatus and process for electrochemically decomposing salt solutions to form the relevant base and acid

• US 5,595,641 A
• Filed: 12/08/1993
• Issued: 01/21/1997
• Est. Priority Date: 06/27/1991
• Status: Expired due to Fees

• Current Assignee: Permelec Electrode, Ltd.
• Original Assignee: Denora Permelec S.p.A.
• Inventors: Faita, Giuseppe, Traini, Carlo
• Primary Examiner(s): GORGOS, KATHRYN L
• Application Number:
  US08/157,180
• Time in Patent Office: 1,140 Days
• Field of Search: 204/258, 204/263, 204/257, 204/265, 204/72, 204/103, 204/104, 204/129, 205/464, 205/508, 205/510, 205/555, 205/554
• US Class Current: 205/464
• CPC Class Codes: C25B 1/16 Hydroxides by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 1/22 Inorganic acids
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: C25B 9/65 Means for supplying current; Electrode connections; Electric inter-cell connections

Abstract

Electrolyzer comprising at least one elementary cell divided into electrolyte compartments by cation-exchange membranes, said compartments are provided with a circuit for feeding electrolytic solutions and a circuit for withdrawing electrolysis products, said cell is equipped with a cathode and a hydrogen-depolarized anode assembly forming a hydrogen gas chamber fed with a hydrogen-containing gaseous stream, characterized in that said assembly comprises a cation-exchange membrane, a porous, flexible electrocatalytic sheet, a porous rigid current collector having a multiplicity of contact points with said electrocatalytic sheet, said membrane, sheet and current collector are held in contact together by means of pressure without bonding.

Claims

1. Electrolyzer for the electrolysis of a solution of a salt for the production of a solution containing an acid and a solution of a base, said electrolyzer comprises at least one elementary cell divided into a first, a central and a third compartment by means of a first and a second cation-exchange membrane, the first of said compartments contains the first of said membranes and a cathode for the hydrogen evolution and the production of the base, the central compartment, defined by said cation-exchange membranes, is further divided into two parts by an anion-exchange membrane, the third compartment contains the second of said cation-exchange membranes and an anode, said anode comprises a porous electrocatalytic sheet for hydrogen ionization and a porous rigid current collector, characterized in that said current collector has a multiplicity of contact points and said porous electrocatalytic sheet is flexible and is held in contact with said second membrane and said current collector by means of pressure without bonding.

2. The electrolyzer of claim 1 characterized in that the second of the cation-exchange membrane of said assembly is an acid resistant membrane.

3. The electrolyzer of claim 1 characterized in that said electrocatalytic sheet consists in a carbon or graphitized laminate containing an electrocatalyst for the ionization of hydrogen.

4. The electrolyzer of claim 1 characterized of that said electrocatalytic sheet consists of a film comprising a binder and electroconductive and electrocatalytic particles for the ionization of hydrogen.

5. The electrolyzer of claim 1 characterized of that said electrocatalytic sheet consists in a fine metal wire mesh provided with a coating comprising an electrocatalyst for the ionization of hydrogen.

6. The electrolyzer of claim 1 characterized of that said electrocatalytic sheet consists of a sinterized metal sheet comprising an electrocatalyst for the ionization of hydrogen.

7. The electrolyzer of claim 1 characterized in that said current collector is made of valve metal and is provided with an electroconductive coating.

8. The electrolyzer of claim 1 characterized in that said current collector comprises a porous, coarse, rigid metal screen and a porous, fine, flexible metal screen in contact with each other.

9. The electrolyzer of claim 8 characterized in that said coarse metal screen and said fine metal screen are connected together by means of spot-welding.

10. The electrolyzer of claim 8 characterized in that said coarse metal screen is coarse expanded metal sheet and said fine metal screen is fine expanded metal sheet.

11. The electrolyzer of claim 10 characterized in that the said coarse expanded metal sheet has a minimum thickness of 1 millimeter and has apertures with diagonals with a maximum length of 20 millimeters.

12. The electrolyzer of claim 1 characterized in that said pressure is pressure exerted by the solution in contact with a side of said second cation-exchange membrane opposite with respect to that in contact with said electrocatalytic sheet.

13. The electrolyzer of claim 1 characterized in that said pressure is the pressure exerted by resilient means.

14. A method of electrolysis of a solution of a salt for the production of a solution containing an acid and a solution containing a base, carried out in an electrolyzer which comprises at least one elementary cell divided into a first, a central and a third compartment by means of a first and a second cation-exchange membrane, the first of said compartments contains the first of said membranes and a cathode for the hydrogen evolution and the production of the base, the central compartment defined by said cation-exchange membranes is further divided into two parts by an anion-exchange membrane, the third compartment contains the second of said cation-exchange membranes and an anode, said anode comprises a porous electrocatalytic sheet for hydrogen ionization and a porous rigid current collector, said method comprises:

feeding the solution of the base to an inlet of the first compartment

withdrawing a more concentrated solution of the base and hydrogen from an outlet of said first compartment

feeding the solution of the salt to an inlet of the part of the central compartment defined by said first cation-exchange membrane and the anion-exchange membrane,

withdrawing an exhausted solution of the salt from an outlet of said part of the central compartment,

withdrawing a solution of the acid from an outlet of the part of the central compartment defined by the anion-exchange membrane and said second cation-exchange membrane

feeding a hydrogen-containing gaseous stream to an inlet of said third compartment

venting rest gas from an outlet of said compartment characterized in that the hydrogen gas diffuses throughout the porous current collector and the porous electrocatalytic sheet and it is ionized at the interface between said electrocatalytic sheet and the membrane to form H⁺ ions and said H⁺ ions migrate through the membrane into said solution of the acid, said electrocatalytic sheet, said membrane and said current collector are held in contact by means of pressure without bonding.