Bipolar lithium-ion rechargeable battery

• US 5,595,839 A
• Filed: 06/01/1995
• Issued: 01/21/1997
• Est. Priority Date: 10/13/1994
• Status: Expired due to Term

• Current Assignee: Eaglepicher Technologies LLC (Eaglepicher Corporation)
• Original Assignee: Yardney Technical Products, Inc. (Vectra Corp.)
• Inventors: Hossain, Sohrab
• Primary Examiner(s): Kalafut, Stephen
• Assistant Examiner(s): LILLEY, RICHARD
• Application Number:
  US08/456,391
• Time in Patent Office: 600 Days
• Field of Search: 429/210, 429/218, 429/221
• US Class Current: 429/210
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 10/0563 Liquid materials, e.g. for Li-SOCl2 cells
• CPC Class Codes: H01M 6/48 with bipolar electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A novel and improved rechargeable, lithium-ion battery system is composed of a plurality of individual electrochemical cells having positive and negative electrodes disposed in opposite face-to-face arrangement with a porous separator containing electrolyte therebetween, and wherein the positive and negative electrodes of adjacent cells are disposed in contact respectively with opposite sides of a common current-collecting element forming a unitary bipolar structure. The negative electrode comprises a layer of carbon adhered to one side of the current-collecting element while the positive electrode comprises a layer containing a lithium transition metal oxide or sulfide compound adhered to the other opposite side of the element. The unitary bipolar structures containing the positive and negative electrodes of adjacent cells include outer peripheral, electrically-insulating seal members, preferably in the form of plastic insulating rings, which are joined together in a sealed stacked array.

Claims

1. A bipolar rechargeable lithium-ion battery comprising:

a plurality of individual electrochemical cells having positive and negative electrodes disposed in opposite face-to-face arrangement with a porous separator containing electrolyte therebetween, wherein the positive and negative electrodes of adjacent cells are disposed in electrical connection respectively with opposite sides of a common current-collecting element forming a unitary bipolar structure, said negative electrode comprising a layer of carbon adhered to one of said opposite sides of said current-collecting element and said positive electrode comprising a layer containing a lithium transition metal oxide compound adhered to the other opposite side of said element, and wherein said electrolyte comprises a lithium salt dissolved in a non-aqueous, organic solvent, and means for joining said unitary bipolar structure of adjacent cells together in a sealed stacked array.

2. A bipolar rechargeable lithium-ion battery according to claim 1, wherein said positive electrode comprises a lithiated transition metal oxide selected from the group consisting of LiCoO₂, LiNiO₂, LiMn₂ O₄, Li₂ Mn₂ O₄ or combinations of these materials.

3. A bipolar rechargeable lithium-ion battery according to claim 2, wherein said negative electrode comprises petroleum coke, carbon, graphite or mixtures thereof.

4. A bipolar rechargeable lithium-ion battery according to claim 3, wherein said current-collecting element includes a bi-metallic member composed of copper on one side and aluminum on the other side thereof.

5. A bipolar rechargeable lithium-ion battery according to claim 4, wherein said negative carbon electrode is disposed adjacent to and in electrical connection with the copper side of said current-collecting element and wherein said positive transition metal oxide electrode is disposed adjacent to and in electrical connection with the aluminum side of said element.

6. A bipolar rechargeable lithium-ion battery according to claim 1, wherein said electrolyte is a non-aqueous solution comprising a solute selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiCF₃ SO₃, LiN(CF₃ SO₂)₂ and LiClO₄ and mixtures thereof, dissolved in a solvent selected from the group consisting of propylene carbonate, ethylene carbonate, diethyl carbonate, dimethoxyethane and dimethyl carbonate and mixtures thereof.

7. A bipolar rechargeable lithium-ion battery according to claim 1, wherein said means for joining said unitary bipolar structure of adjacent cells together comprises a non-conducting polymer ring surrounding the outer peripheral edges of said current-collecting element.

19. A bipolar rechargeable lithium-ion battery according to claim 1, wherein said current-collecting element comprising copper on one of said opposite sides and aluminum on the other of said opposite sides.

20. A bipolar rechargeable lithium-ion battery according to claim 7, wherein said ring comprises a tetrafluoroethylene-ethylene copolymer.

8. A unitary bipolar structure for use in a rechargeable, lithium-ion battery comprising a solid, liquid impermeable, current-collecting element having opposite sides comprising respectively copper and aluminum, a negative electrode comprising a layer of carbon adhered to one of said opposite sides of said element and a positive electrode comprising a layer containing a lithium transition metal oxide compound adhered to the other opposite side of said element.

9. A unitary bipolar structure according to claim 8, wherein said positive electrode comprises a lithiated transition metal oxide selected from the group consisting of LiCoO₂, LiNiO₂, LiMn₂ O₄, Li₂ Mn₂ O₄ and combinations of these materials.

10. A unitary bipolar structure according to claim 9, wherein said negative electrode comprises petroleum coke, carbon, graphite or mixtures thereof.

11. A unitary bipolar structure according to claim 10, wherein said negative carbon electrode is disposed adjacent to and in electrical connection with the copper side of said current-collecting element and wherein said positive transition metal oxide electrode is disposed adjacent to and in electrical connection with the aluminum side of said element.

12. A bipolar rechargeable lithium-ion battery comprising:

a plurality of individual electrochemical cells having positive and negative electrodes disposed in opposite face-to-face arrangement with a porous separator containing electrolyte therebetween, and wherein the positive and negative electrodes of adjacent cells are disposed in physical and electrical contact respectively with opposite sides of a common current-collecting element forming a unitary bipolar structure, said current-collecting element comprising a thin, bi-metallic foil member composed of copper on one side and aluminum on the other side thereof, said negative electrode comprising a layer of carbon adhered to said copper side of said bi-metallic member and said positive electrode comprising a layer containing a lithium transition metal oxide selected from the group consisting of LiCoO₂, LiNiO₂, LiMn₂ O₄, Li₂ Mn₂ O₄ and mixtures thereof, adhered to the other aluminum side of said member, said positive and negative electrodes contacting and adhering to substantially the entire surface areas of the respective sides of said bi-metallic member, said electrolyte being a non-aqueous solution comprising a solute selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiCF₃ SO₃, LiN(CF₃ SO₂)₂, LiClO₄ and mixtures thereof, dissolved in a solvent selected from the group consisting of propylene carbonate, ethylene carbonate, diethyl carbonate, dimethoxyethane, dimethyl carbonate and mixtures thereof, and means for joining said unitary bipolar structure of adjacent cells together in a sealed stacked array.

13. A bipolar rechargeable lithium-ion battery according to claim 12, wherein said negative electrode comprises petroleum coke, carbon, graphite or mixtures thereof.

14. A bipolar rechargeable lithium-ion battery according to claim 13, wherein said means for joining said unitary bipolar structure of adjacent cells together comprises a non-conducting polymer ring surrounding the outer peripheral edges of said current-collecting element.

15. A bipolar rechargeable lithium-ion battery comprising:

a plurality of individual electrochemical cells having positive and negative electrodes disposed in opposite face-to-face arrangement with a porous separator containing electrolyte therebetween, wherein the positive and negative electrodes of adjacent cells are disposed in electrical connection respectively with opposite sides of a common current-collecting element forming a unitary bipolar structure, said current-collecting element comprising copper on one of said opposite sides and aluminum on the other of said opposite sides, said negative electrode comprising a layer containing petroleum coke, carbon, graphite or mixtures thereof adhered to one of said opposite sides of said current-collecting element and said positive electrode comprising a layer containing a lithiated transition metal oxide selected from the group consisting of LiCoO₂, LiNiO₂, LiMn₂ O₄, Li₂ Mn₂ O₄ or combinations of these materials adhered to the other opposite side of said element, and means for joining said unitary bipolar structure of adjacent cells together in a sealed stacked array.

17. A bipolar rechargeable lithium-ion battery according to claim 15, wherein said negative electrode is disposed adjacent to and in electrical connection with the copper side of said current-collecting element and wherein said positive electrode is disposed adjacent to and in electrical connection with the aluminum side of said element.

16. A unitary bipolar structure for use in a rechargeable, lithium-ion battery comprising a solid, liquid impermeable, current-collecting element having opposite sides comprising copper and aluminum, a negative electrode comprising a layer containing petroleum coke, carbon, graphite or mixtures thereof adhered to one of said opposite sides of said element and a positive electrode comprising a layer containing a lithiated transition metal oxide selected from the group consisting of LiCoO₂, LiNiO₂, LiMn₂ O₄, Li₂ Mn₂ O₄ and combinations of these materials adhered to the other opposite side of said element.

18. A unitary bipolar structure according to claim 16, wherein said negative electrode is disposed adjacent to and in electrical connection with the copper side of said current-collecting element and wherein said positive electrode is disposed adjacent to and in electrical connection with the aluminum side of said element.