Process and apparatus to produce a small scale LNG stream from an existing NGL expander plant demethanizer

• US 5,600,969 A
• Filed: 12/18/1995
• Issued: 02/11/1997
• Est. Priority Date: 12/18/1995
• Status: Expired due to Term

• Current Assignee: Conocophillips Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Low, William R.
• Primary Examiner(s): KILNER, CHRISTOPHER B
• Application Number:
  US08/573,973
• Time in Patent Office: 421 Days
• Field of Search: 62/622, 62/623
• US Class Current: 62/622
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0229 Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
• CPC Class Codes: F25J 1/0265 comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
• CPC Class Codes: F25J 1/0267 using flash gas as heat sink
• CPC Class Codes: F25J 1/0274 Retrofitting or revamping of an existing liquefaction unit
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2245/90 the recycled stream being boil-off gas from storage
• CPC Class Codes: F25J 2260/20 Integration in an installation for liquefying or solidifying a fluid stream
• CPC Class Codes: F25J 2260/60 Integration in an installation using hydrocarbons, e.g. for fuel purposes
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/60 Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
• CPC Class Codes: F25J 2290/80 : Retrofitting, revamping or debottlenecking of existing plant
• CPC Class Codes: F25J 3/0209 : Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 : separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 : separation of CnHm with 2 carbon atoms or more

Abstract

This invention concerns a novel process and apparatus for producing relatively small quantities of liquefied natural gas (LNG) by processing a side stream at a conventional NGL expander gas plant.

Claims

1. A process for producing liquefied natural gas at a natural gas expander plant comprising

(a) withdrawing a methane-rich side stream from the gas overhead stream at the demethanizer;

(b) expanding said side stream by flowing through a turbo expander thereby producing energy and a two-phase stream;

(c) splitting said two-phase stream into a first stream and a second stream;

(d) flowing said first stream and a condensible refrigerant vapor stream to a condenser wherein said first stream functions via indirect heat exchange as a coolant thereby condensing at least a portion of the condensible refrigerant stream and producing a liquid-bearing refrigerant stream and a warmed first stream;

(e) flashing said refrigerant stream of step (d) thereby creating a flashed refrigerant stream;

(f) flowing the second stream and at least a portion of the flashed refrigerant stream into an indirect heat exchange means thereby condensing at least a portion of the second stream and producing an LNG-bearing stream and a refrigerant vapor stream.

2. A process according to claim 1 wherein the refrigerant comprises methane in major proportion.

3. A process according to claim 1 wherein the refrigerant is the condensed product of step (f).

4. A process according to claim 1 additionally comprising the steps of

(g) compressing the refrigerant vapor stream of step (f) thereby producing said condensible refrigerant stream of step (d);

and

(h) cooling said condensible refrigerant stream by first flowing through a cooling means coupled to an environmental sink prior to employing said stream in step (d).

5. A process according to claim 4 wherein the refrigerant comprises methane in major proportion.

6. A process according to claim 4 wherein the refrigerant is the condensed product of step (f).

7. A process according to claim 4 further comprising the step of

(i) contacting via indirect heat exchange means the refrigerant vapor stream of step (f) with the cooled refrigerant stream of step (h) prior to introducing said stream to step (d).

8. A process according to claim 7 wherein the refrigerant comprises methane in major proportion.

9. A process according to claim 7 wherein the refrigerant is the condensed product of step (f).

10. A process according to claim 7 additionally comprising the steps of

(j) separating the LNG-bearing stream of step (f) into a return vapor stream and a pressured LNG stream;

and

(k) compressing said flash vapor stream using energy from step (b).

11. A process according to claim 10 additionally comprising the step of

(l) flashing the liquid-bearing stream of step (d) to a pressure of near-atmospheric pressure to 5 psig;

(m) flowing the flashed product of step (l) to a storage vessel wherefrom is produced a storage vapor stream;

(n) compressing said storage vapor stream to a pressure approximately equivalent to the pressure of the return vapor stream;

(o) combining said compressed stream of (m) with said return vapor stream of step (j); and

(o) feeding this combined stream to step (k) above.

12. A process for producing liquefied natural gas at an natural gas expander plant comprising

(a) withdrawing a methane-rich side stream from the gas overhead stream at the demethanizer;

(b) expanding the side stream by flowing through a turbo expander thereby producing energy and a two-phase stream;

(c) separating said two-phase stream into an expanded vapor stream and an expanded liquid stream;

(d) splitting said expanded vapor stream into a first vapor stream and a second vapor stream;

(e) cooling a refrigerant vapor stream in a closed refrigerant stream by indirect heat exchange with said first vapor stream thereby producing an at least partially condensed refrigerant and a heated first vapor stream;

(f) flashing said partially condensed refrigerant; and

(g) cooling said second vapor stream via indirect heat exchange by contact with at least a portion of the product of step (f) thereby producing a second refrigerant vapor and an at least partially condensed natural gas stream.

13. A process according to claim 12 additionally comprising

(h) combining said first vapor stream and at least a portion of said expanded liquid stream and employing this stream in place of the first vapor stream in step (e).

14. An apparatus for producing liquefied natural gas from a methane-rich side stream at a gas processing plant comprising

(a) a first conduit for the methane-rich side stream;

(b) a turbo expander connected to the first conduit of (a);

(c) a splitting device connected to the turbo expander and from which is produced a first stream and a second stream;

(d) a closed refrigeration system nominally comprised of a compressor, condenser, an expansion means, a chiller, necessary refrigerant conduit for connecting the above components in an operational order, and refrigerant;

(e) a second conduit from said splitting means for delivering the first stream coolant to said condenser;

(f) a third conduit from said splitting means for delivering said second stream to said evaporative chiller;

(g) and a fourth conduit from said chiller from which is produced an LNG-bearing stream.

15. An apparatus according to claim 14 wherein said closed refrigeration system is additionally comprised of a refrigerant cooler coupled to an environmental heat sink inserted in the conduit between the compressor and the condenser.

16. An apparatus according to claim 15 wherein said closed refrigeration system is additionally comprised of an economizer inserted in the conduit between the evaporator and the compressor and the conduit between the refrigerant cooler and the condenser.

17. An apparatus according to claim 16 additionally comprising

(h) a fifth conduit connected to said condenser providing for flow of a warmed first stream from condenser;

(h) a gas/liquid separation means connected to said conduit of (g) from which is produced a return vapor stream and a pressured LNG stream;

(i) a sixth conduit connected to said gas/liquid separation means of (h) for said return vapor stream;

(j) a seventh conduit connected to said fifth and sixth conduits through which the combined streams delivered by the fifth and sixth conduits flow; and

(k) a compressor connected to said seventh conduit employing power generated at least in part by the turbo expander of (b) thereby compressing said stream delivered by the seventh conduit.

18. An apparatus according to claim 17 wherein said turbo expander of (b) and compressor of (k) are directly coupled to one another.

19. A apparatus according to claim 17 additionally comprising

(l) an expansion means;

(m) an 8th conduit connected to the separation means of (h) and the expansion means of (l) through which the pressured LNG stream flows;

(n) an LNG storage vessel;

(o) a ninth conduit situated between the expansion means of (m) and the LNG storage vessel of (n);

(o) a vapor blower;

(p) a tenth conduit situated between the LNG storage vessel of (m) and the vapor blower of (o) through which flows the vapor storage stream; and

(q) an eleventh conduit situated connected to the blower of (o) and to either the fifth conduit, the sixth conduit, or the seventh conduit.

20. An apparatus according to claim 19 wherein said turbo expander of (b) and compressor of (k) are directly coupled to one another.