On-line control and monitoring system for wet lime/limestone flue gas desulfurization process

• US 5,601,784 A
• Filed: 09/09/1994
• Issued: 02/11/1997
• Est. Priority Date: 09/09/1994
• Status: Expired due to Term

• Current Assignee: Electronics and Telecommunications Research Institute
• Original Assignee: Electric Power Research Institute
• Inventors: Richardson, Carl, Hanley, Timothy, Maybach, Gerard B., Glover, Robert L., Meserole, Frank, Moser, Robert E., Maller, Gordon
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US08/302,438
• Time in Patent Office: 886 Days
• Field of Search: 422/68.1, 422/69.70, 422/82, 422/82.01, 422/82.02, 422/82.03, 422/108, 422/111, 436/43, 436/51, 436/55, 210/96.2, 210/143, 210/739, 423/243.08
• US Class Current: 422/70
• CPC Class Codes: C04B 11/264 Gypsum from the desulfurisation of flue gases
• CPC Class Codes: G01N 33/0042 for SO2, SO3
• CPC Class Codes: Y10T 436/11 Automated chemical analysis
• CPC Class Codes: Y10T 436/116664 with automated titrator
• CPC Class Codes: Y10T 436/12 Condition responsive control

Abstract

An on-line control and monitoring system for automatically and continuously analyzing key process indicators in a wet lime/limestone flue gas desulfurization process is provided. The on-line control and monitoring system obtains a slurry and/or a slurry flitrate which is directed at selected fluid flow rates to one or more analytical devices each selected to analyze a flue gas desulfurization process indicator. Data is provided to a data acquisition system which processes the analysis results from the analytical devices and provides flue gas desulfurization process control information. This on-line monitoring and control system can be used to monitor and control the addition rate of performance enhancement additives such as organic acids, thiosulfate, oxidation air and the like.

Claims

1. An on-line control and monitoring system for monitoring selected process control indicators and parameters in a wet lime/limestone flue gas desulfurization process for removing sulfur dioxide from flue gas, wherein said control and monitoring system operates concurrently with the conduct of the flue gas desulfurization process to provide data relative to selected process control indicators and parameters that can be used to control the conduct of the flue gas desulfurization process while the flue gas desulfurization process is operating, wherein said on-line control and monitoring system comprises:

(a) a housing supporting said on-line control and monitoring system;

(b) a supply of flue gas desulfurization process slurry withdrawn from said flue gas desulfurization process while said flue gas desulfurization process is being conducted and directed through a fluid conducting conduit to a continuous filtration system mounted in said housing;

(c) said continuous filtration system being fluidically connected to at least one automatic analyzer mounted in said housing to filter said process slurry supply to provide a continuous supply of analytical quality slurry filtrate;

(d) said at least one automatic analyzer being capable of automatically quantitatively analyzing said slurry filtrate at selected intervals to produce data relating to a selected flue gas desulfurization process control indicator or parameter; and

(e) a control system operationally connected to said automatic analyzer and to said flue gas desulfurization process capable of receiving and processing the data produced by said analyzer and making any adjustments in the conduct of the flue gas desulfurization process indicated by said data to be necessary to optimize sulfur dioxide removal efficiency.

2. The on-line control and monitoring system described in claim 1, wherein said selected process control indicators and parameters include gypsum relative saturation, sulfite concentration, magnesium concentration, chloride concentration, calcium concentration, sulfate concentration, sulfur dioxide removal and total carbonate.

3. The on-line control and monitoring system described in claim 1, wherein the analyzer is selected from the group consisting of automatic titrators, automatic colorimeters, conductivity monitors, automatic ion chromatographs and ion specific electrodes.

4. The on-line control and monitoring system described in claim 1 wherein said analyzer is operatively connected to said control system to be activated to conduct a selected analysis at a selected interval.

5. The on-line control and monitoring system described in claim 1, wherein said system further includes an analyzer fluidically connected directly to said slurry supply and electronically connected to said control system, and said analyzer is capable of automatically quantitatively analyzing said slurry to produce data relating to process indicators of said slurry and transmitting said data to said control system.

6. The on-line control and monitoring system described in claim 5, wherein said analyzer is a potentiometric autotitrator.

7. The on-line control and monitoring system described in claim 6, wherein said analyzer quantitatively measures solid phase carbonate and said control system adjusts limestone addition to said flue gas desulfurization process.

8. The on-line control and monitoring system described in claim 5, wherein said control system includes a data link operatively connected to each said analyzer and to a data acquisition system capable of recording and reading data generated by said analyzers.

9. The on-line control and monitoring system described in claim 8, wherein said control system further includes a feedback loop operatively connected to said flue gas desulfurization process to control the addition of at least one flue gas desulfurization process additive in response to the data from said analyzer relating to a process control indicator affected by said additive.

10. An on-line control and monitoring system for monitoring selected process control indicators and parameters in a wet lime/limestone flue gas desulfurization process for removing sulfur dioxide from flue gas, wherein said control and monitoring system operates concurrently with the conduct of the flue gas desulfurization process to provide data relative to the selected process control indicators and parameters that can be used to control the conduct of the flue gas desulfurization process while said flue gas desulfurization process is operating, wherein said on-line control and monitoring system comprises:

(a) a housing supporting said on-line control and monitoring system;

(b) a supply of flue gas desulfurization process slurry withdrawn from said flue gas desulfurization process while said flue gas desulfurization process is being conducted and directed through a fluid conducting conduit to a continuous filtration system mounted in said housing;

(c) said continuous filtration system being fluidically connected to at least one automatic analyzer mounted in said housing to filter said process slurry supply to provide a continuous supply of analytical quality slurry filtrate;

(d) said at least one automatic analyzer capable of automatically quantitatively analyzing said slurry filtrate at selected intervals to produce data relating to said selected flue gas desulfurization process control indicator or parameter;

(e) a control system operationally connected to said automatic analyzer and to said flue gas desulfurization process capable of receiving and processing the data produced by said analyzer and making any adjustments in the conduct of the flue gas desulfurization process indicated by said data to be necessary to optimize sulfur dioxide removal efficiency; and

(f) at least one automatic analyzer mounted in said housing fluidically connected directly to said slurry supply and electronically connected to said control system capable of automatically quantitatively analyzing said slurry to produce data relating to process indicators of said slurry and transmitting said data to said control system.