Process for the production of a two-coat finish, and powder coatings suitable for this process

• US 5,601,878 A
• Filed: 01/26/1995
• Issued: 02/11/1997
• Est. Priority Date: 07/07/1992
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Hilger, Christopher, Woltering, Joachim, Rademacher, Josef, Cibura, Klaus, Kranig, Wolfgang
• Primary Examiner(s): Short, Patricia A.
• Application Number:
  US08/362,528
• Time in Patent Office: 747 Days
• Field of Search: 525/173, 525/176, 525/934, 525/174, 525/166, 525/167, 427/386, 427/410, 427/419.1, 427/407.1
• US Class Current: 427/386
• CPC Class Codes: B05D 2401/32 applied as powders
• CPC Class Codes: B05D 2401/40 where the carrier is not clearly specified
• CPC Class Codes: B05D 2451/00 Type of carrier, type of coating (Multilayers)
• CPC Class Codes: B05D 7/532 the two layers being cured or baked together, i.e. wet on wet
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/34 Oxygen-containing compounds, including ammonium and metal salts
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C09D 133/06 of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
• CPC Class Codes: C09D 133/068 containing glycidyl groups
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• CPC Class Codes: Y10S 525/934 Powdered coating composition

Abstract

The invention relates to a process for the production of two-coat finishes, in which a pigmented basecoat is first applied, the resulting basecoat film is coated with a powder clearcoat, and basecoat and clearcoat are subsequently baked together. In accordance with the invention, the powder clearcoat employed is a powder coating which contains an epoxide group-containing polyacrylate resin as binder and a mixture of (A) a polyanhydride and (B) a carboxyl group-containing polyester resin as crosslinking agent. The polyester resin can be prepared by reacting a diol (b1), a compound (b2) which contains per molecule at least three functional groups selected from hydroxyl, primary amino, secondary amino, carboxyl and acid anhydride groups, and (b3) a dicarboxylic acid in a molar ratio of (b1): (b2): (b3)=0.0 to 3.0: 1.0: 1.5 to 9.0 to give a polyester resin having an acid value of 40 to 300.

Claims

1. Process for the production of two-coat finishes on a substrate surface, comprising the steps of

(1) applying a pigmented basecoat to the substrate surface,

(2) forming a polymer film from the coat applied in step (1),

(3) applying a powder clearcoat which contains an epoxide group-containing polyacrylate resin as binder to the resulting basecoat film, and subsequently

(4) baking the basecoat together with the powder clearcoat, characterized in that the powder clearcoat employed in step (3) as crosslinking agent contains a mixture of

(A) 5 to 95 percent by weight of a compound which contains on statistical average at least two carboxyl groups and at least one acid anhydride group per molecule, or a mixture of such compounds, selected from the group consisting of polyanhydrides of aliphatic polycarboxylic acids, polyanhydrides of cycloaliphatic polycarboxylic acids, and mixtures thereof, and

(B) 95 to 5 percent by weight of a carboxyl group-containing polyester resin obtained by reacting

(b1) a diol or a mixture of diols,

(b2) a compound which contains per molecule at least three functional groups selected from the group consisting of hydroxyl, primary amine, secondary amine, carboxyl and acid anhydride groups, one acid anhydride group being regarded as equivalent to two carboxyl groups, and a mixture of such compounds and

(b3) a compound selected from the group consisting of dicarboxylic acid, a dicarboxylic acid anhydride, and mixtures thereof in a molar ratio of (b1):

(b2);

(b3) =0.0 to 3.0;

1.0;

1.5 to 9.0 to give a polyester resin having an acid value of 40 to 300, the percentages by weight relating to (A)+(B)=100 percent by weight.

2. Process according to claim 1, characterized in that the basecoat applied in step (1) contains a metallic pigment.

3. Process according to claim 1, characterized in that the basecoat applied in step (1) contains an aluminum flake pigment.

4. Powder coatings which contain an epoxide group containing polyacrylate resin as binder, characterized in that they contain as crosslinking agent a mixture of

(A) 5 to 95 percent by weight of a compound which contains on statistical average at least two carboxyl groups and at least one acid anhydride group per molecule, or a mixture of such compounds, selected from the group consisting of polyanhydrides of aliphatic polycarboxylic acids, polyanhydrides of cycloaliphatic polycarboxylic acids, and mixtures thereof

(B) 95 to 5 percent by weight of a carboxyl group-containing polyester resin obtained by reacting

(b1) a diol or a mixture of diols,

(b2) a compound which contains per molecule at least three functional groups selected from the group consisting of hydroxyl, primary amino, secondary amino, carboxyl and acid anhydride groups, one acid anhydride group being regarded as equivalent to two carboxyl groups, and mixtures thereof and

(b3) a compound selected from the group consisting of dicarboxylic acid, a dicarboxylic acid anhydride, and mixtures thereof in a molar ratio of (b1):

(b2);

(b3)=0.0 to 3.0;

1.0;

1.5 to 9.0 to give a polyester resin having an acid value of 40 to 300, the percentages by weight relating to (A)+(B)=100 percent by weight.

5. Powder coatings according to claim 4 comprising powder clearcoats for the production of two-coat finishes.