Method of operating a fuel cell

• US 5,601,936 A
• Filed: 05/16/1995
• Issued: 02/11/1997
• Est. Priority Date: 06/16/1994
• Status: Expired due to Fees

• Current Assignee: Transcore Incorporated (Roper Technologies, Inc.)
• Original Assignee: British Gas Trading Limited (Centrica PLC)
• Inventors: Dicks, Andrew L., Dudfield, Christopher D.
• Primary Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/441,733
• Time in Patent Office: 637 Days
• Field of Search: 429/13, 429/16, 429/17, 429/19
• US Class Current: 429/432
• CPC Class Codes: H01M 16/006 of fuel cells with rechargeable batteries
• CPC Class Codes: H01M 8/043 applied during specific periods
• CPC Class Codes: H01M 8/04917 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/2457 with both reactants being gaseous or vaporised
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell is operated at a temperature which is not greater than substantially 250° C., has an electrolyte which can be a solid polymer electrolyte, a liquid phosphoric acid electrolyte, or a liquid alkaline electrolyte, and a cathode and an anode each comprising a platinum catalyst. Hydrogen fuel gas is supplied to the anode and a gaseous oxidant, for example oxygen is supplied to the cathode. The cathode and anode are both connected to first and second circuits in parallel. The first circuit includes a load to be powered by the fuel cell and a first switch. The second circuit includes a battery and a second switch. The switches are operated by a control. When the first swtich is closed the cell powers the load and the second switch is open. When the first switch is open the second switch is closed so the battery applies a reverse D.C. potential the anode and cathode. The first switch is closed and the second switch is open for a time period T1 which is substantially at least ten times greater than time period T2 for which the first switch is open and the second switch is closed. The time period T2 does not exceed substantially 0.25 seconds. The switches can be relays or solid state electronic switch arrangements.

Claims

1. A method of operating a fuel cell of the type comprising an anode and a cathode each comprising catalyst means comprising platinum, the method comprising supplying gaseous fuel comprising hydrogen and/or a gaseous alcohol to said anode and supplying gaseous oxidant comprising oxygen to said cathode, operating the fuel cell at a temperature which does not exceed substantially 250°

C., providing an interruptable first circuit externally of the cell for electric current derived from the cell to flow in the external circuit from the cathode to the anode by reason of the cathode being at a positive potential relative to the anode, providing a second circuit externally of the cell, said second circuit comprising electrical energy supply means for supplying selectively a reverse D.C. potential to said anode and cathode thereby putting the anode at a positive potential with respect to said cathode, interrupting and completing the first circuit alternately and operating the second circuit whereby when the first circuit is interrupted the reverse D.C. potential is applied simultaneously by means of the second circuit and when the first circuit is completed application of said reverse D.C. potential ceases, said first circuit being completed for a first time period and said reverse D.C. potential being applied for a second time period, said first time period being at least substantially ten times greater than said second time period, and the second time period being not greater than substantially 0.25 seconds.

2. A method according to claim 1, wherein said catalyst means is substantially entirely platinum.

3. A method according to claim 1, wherein said operating temperature of the fuel cell does not exceed substantially 100°

.

4. A method according to claim 1, wherein said operating temperature of the fuel cell does not exceed substantially 80°

.

5. A method according to claim 1, wherein said fuel cell comprises is solid polymer electrolyte.

6. A method according to claim 1, wherein said operating temperature does not exceed substantially 200°

.

7. A method according to claim 1, wherein said fuel cell comprises a liquid electrolyte.

8. A method according to claim 7, wherein said fuel cell comprises is phosphoric acid electrolyte.

9. A method according to claim 1, wherein said fuel cell comprises a liquid alkaline electrolyte.

10. A method according to claim 1, wherein said electrical energy supply means comprises electrical cell means.

11. A method according to claim 1, wherein said electrical energy supply means comprises battery means.

12. A method according to claim 10, wherein said electrical energy supply means comprises rechargable electrical cell means.

13. A method according to claim 11, wherein said electrical energy supply means comprises rechargeable electrical battery means.

14. A method according to claim 1, wherein said electrical energy supply means comprises capacitor means.

15. A method according to claim 1, wherein said first circuit comprises an electrical load to be powered by said fuel cell, and second electrical energy supply means is provided to power said load when said first circuit is interrupted.

16. A method according to claim 15, wherein said second electrical energy supply means comprises electrical cell means.

17. A method according to claim 15, wherein said second electrical energy supply means comprises battery means.

18. A method according to claim 15, wherein said second electrical energy supply means comprises rechargeable electrical cell means.

19. A method according to claim 15, wherein said second electrical energy supply means comprises rechargeable battery means.

20. A method according to claim 15, wherein said second electrical energy supply means comprises capacitor means.

21. A method according to claim 1, wherein said first circuit means is interrupted and completed and said second circuit means is operated by operation of control means operating switch means in said first and second circuit means.

22. A method according to claim 21, wherein said switch means is provided by solid state switching means.

23. A method according to claim 1, in which said first time period is substantially 2.50 seconds and said second time period is substantially 0.25 seconds.

24. A method according to claim 1, wherein said first time period is substantially 1.0 seconds and said second time period is substantially 0.1 seconds.

25. A method according to claim 1, wherein said first time period is substantially 0.5 seconds and said second time period is substantially 0.05 seconds.

26. A method according to claim 1, wherein said method is applied to the operation of a stack or battery comprising a plurality of said fuel cells.

27. A method according to claim 1, wherein said reverse D.C. potential is at least substantially equal to 0.8 volts, with respect to the open circuit potential of said fuel cell.

28. A method according to claim 26, wherein said reverse D.C. potential applied to said stack or battery of said fuel cells in series is at least substantially equal to n×

0.8 volts with respect to the open circuit potential of said stack or battery, and n is equal to the number of fuel cells in said stack or battery.