Method for producing polyamide carpet fibers with improved flame retardancy

• US 5,604,007 A
• Filed: 08/19/1993
• Issued: 02/18/1997
• Est. Priority Date: 03/06/1992
• Status: Expired due to Fees

• Current Assignee: BASF Corporation (BASF SE)
• Original Assignee: BASF Corporation (BASF SE)
• Inventors: Shore, Gary W.
• Primary Examiner(s): PEZZUTO, HELEN LEE
• Application Number:
  US08/109,413
• Time in Patent Office: 1,279 Days
• Field of Search: 428/92, 428/95, 428/96, 525/101, 525/104, 525/431, 524/405
• US Class Current: 428/92
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: D01F 1/07 for making fire- or flame-proof filaments
• CPC Class Codes: D01F 6/60 from polyamides from polyamino acids or polypeptides D01F6/68
• CPC Class Codes: D06N 7/0042 Conductive or insulating layers; Antistatic layers; Flame-proof layers
• CPC Class Codes: Y10T 428/23957 Particular shape or structure of pile
• CPC Class Codes: Y10T 428/23979 Particular backing structure or composition
• CPC Class Codes: Y10T 428/23986 With coating, impregnation, or bond

Abstract

A method for producing halogen-free, antimony-free and phosphorous-free polyamide fibers is described by incorporating an additive into the polyamide which comprises a vulcanizable mixture of silicones and a catalyst in a thermoplastic matrix. The fibers have improved flame retardancy and are used for the manufacture of carpets.

Claims

1. A method for producing a flame-retardant thermoplastic polymer carpet or textile fiber comprising the steps of:

(a) forming a polyamide mixture having (i) at least about 80% by weight of a polyamide, wherein at least 90% of the polyamide is at least one nylon selected from the group consisting of nylon 6, nylon 6/6, copolymers thereof, and combinations thereof, and (ii) a vulcanizable additive containing (1) a thermoplastic matrix polymer, (2) silicones in an amount between about 5% to about 20% based on the total weight of the vulcanizable additive, and (3) a platinum complex catalyst, said additive being present in the polyamide mixture in an amount between about 0.05% to about 20% by weight of the polyamide mixture to obtain less than about 1.0% by weight of said silicones in the polyamide mixture sufficient to render the polyamide more flame retardant than the polyamide is without the additive;

(b) melt blending the polyamide mixture at a temperature of from about 250°

C. to about 300°

C. to form a melt-blend of the polyamide and the additive;

(c) melt spinning the melt-blend from step (b) into fibers having a denier per filament from about 6 to about 35;

(d) drawing the fibers; and

(e) treating the drawn fibers in a crimping device to impart texture and bulk thereto.

2. The method of claim 1, wherein step (a) is practiced so that said additive is present in the polyamide mixture in an amount from 0.25% to about 20% by weight of the polyamide mixture.

3. The method of claim 1, wherein the additive contains silicone in an amount from about 5% to about 20% by weight of the additive.

4. The method of claim 1, wherein step (a) further comprises adding a zinc compound to the polyamide mixture in an amount from about 0.1% to about 5.0% by weight of the polyamide mixture.

5. The method of claim 4 wherein the zinc compound is selected from the group consisting of:

zinc borate;

zinc oxide;

zinc hydroxide; and

mixtures thereof.

6. The method of claim 3, wherein step (a) further comprises adding a zinc compound to the polyamide mixture in an amount from about 0.1% to about 5.0% by weight of the polyamide mixture.

7. The method of claim 6 wherein the zinc compound is selected from the group consisting of;

zinc borate;

zinc oxide;

zinc hydroxide; and

mixtures thereof.

8. A method for producing a flame-retardant thermoplastic polymer carpet or textile fiber comprising the steps of:

(a) forming a polyamide mixture having (i) at least about 80% by weight of a polyamide, wherein at least 90% of the polyamide is at least one nylon selected from the group consisting of nylon 6, nylon 6/6, copolymers thereof, and combinations thereof, and (ii) a vulcanizable additive containing (1) a thermoplastic matrix polymer, (2) silicones in an amount between about 5% to about 20% based on the total weight of the vulcanizable additive, and (3) a platinum complex catalyst, said additive being present in the polyamide mixture in an amount between about 0.05% to about 20% by weight of the polyamide mixture to obtain less than about 0.5% by weight of said silicones in the polyamide mixture sufficient to render the polyamide more flame retardant than the polyamide is without the additive;

(b) melt blending the polyamide mixture at a temperature of from about 250°

C. to about 300°

C. to form a melt-blend of the polyamide and the additive;

(c) melt spinning the melt-blend from step (b) into fibers having a denier per filament from about 6 to about 35;

(d) drawing the fibers; and

(e) treating the drawn fibers in a crimping device to impart texture and bulk thereto.

9. The method of claim 8, wherein step (a) is practiced so that said additive is present in the polyamide mixture in an amount from 0.25% to about 20% by weight of the polyamide mixture.

10. The method of claim 8, wherein the additive contains silicone in an amount from about 5% to about 20% by weight of the additive.

11. The method of claim 8, wherein step (a) further comprises adding a zinc compound to the polyamide mixture in an amount from 0.1% to about 5.0% by weight of the polyamide mixture.

12. The method of claim 11, wherein the zinc compound is selected from the group consisting of zinc borate, zinc oxide, zinc hydroxide, and mixtures thereof.

13. The method of claim 10, wherein step (a) further comprises adding a zinc compound to the polyamide mixture in an amount from 0.1% to about 5.0% by weight of the polyamide mixture.

14. The method of claim 13, wherein the zinc compound is selected from the group consisting of zinc borate, zinc oxide, zinc hydroxide, and mixtures thereof.