Method of making electrical contact material

• US 5,607,522 A
• Filed: 05/11/1995
• Issued: 03/04/1997
• Est. Priority Date: 12/19/1991
• Status: Expired due to Term

• Current Assignee: EMS Engineered Materials Solutions LLC (Wickeder Westfalenstahl GmbH /Private Group/)
• Original Assignee: Texas Instruments, Inc.
• Inventors: McDonnell, Donald G.
• Primary Examiner(s): Simmons, David A.
• Assistant Examiner(s): Phipps, Margery S.
• Application Number:
  US08/439,259
• Time in Patent Office: 663 Days
• Field of Search: 148/281, 148/431, 148/528, 29/875, 29/877
• US Class Current: 148/281
• CPC Class Codes: C23C 26/00 Coating not provided for in groups C23C2/00 - C23C24/00
• CPC Class Codes: C23C 8/10 Oxidising

Abstract

An electrical contact material having metal oxide particles dispersed in a silver metal matrix and having an easily brazeable backing layer is made free of internal oxide depletion zones by bonding a conventional internally oxidizable silver alloy to a thin backing layer of a second silver alloy to form a composite metal. The first silver alloy is selected to be internally oxidizable under selected oxidizing conditions. The second alloy is selected so that under the selected oxidizing conditions an oxygen-impenetrable barrier is quickly established on the surfaces of the composite formed by the second alloy. In that way, the first alloy layer is forced to be internally oxidized unidirectionally from the opposite surface of the composite to form the desired metal oxide dispersal extending substantially throughout the first alloy layer free of any internal oxide depletion zone in the first layer. An external scale that prevented internal oxidation from proceeding from the second layer surface is then easily removed from the remaining unoxidized silver alloy providing a means for attachment of the contact material by bonding or brazing.

Claims

1. A method for making electrical contact materials comprising the steps of:

providing a composite metal member having a first electrically conductive metal layer with a first external surface portion as part of said member and a second different easily-brazeable electrically-conductive metal layer metallurgically bonded to the first layer with a second external surface portion as part of said member, the first metal layer selected to be internally oxidizable to form metal oxide particles dispersed in the first metal layer when subjected to selected oxidizing conditions, the second metal layer selected to form a barrier to internal oxidizing at the second surface portion when subjected to said selected oxidizing conditions, said selected oxidizing conditions being the required time and temperature in an oxygen atmosphere to internally oxidize the metal in the first layer into metal oxide particles dispersed in the metal layer;

subjecting the composite member to said selected oxidizing conditions, thereby internally oxidizing substantially the entire first metal layer through the first external surface portion while forming the barrier to internal oxidizing in the second metal layer on the second external surface portion, said internal oxidizing of the first layer occurring substantially only through said first external surface portion and not also the second external surface portion so as to not provide any centrally located depletion zone in the first layer; and

removing the barrier from the second external surface portion of the metal member to provide contact materials with an easily-weldable mounting surface.

2. A method according to claim 1 wherein the first metal layer comprises an alloy of silver and a constituent part thereof internally oxidizable in the first metal layer selected from the group consisting of cadmium, tin, indium, and zinc and mixtures thereof, and wherein the second metal layer comprises an alloy of silver and a constituent part thereof present in sufficient concentration to form said internal-oxidizing barrier selected from the group consisting of cadmium, tin and zinc.

3. A method according to claim 2 wherein an additional layer of silver metal is metallurgically bonded between the first and second metal layers to form the metal member.

4. A method according to claim 2 wherein the internal-oxidizing barrier is removed by wire brushing the second surface portion of the metal member.

5. A method according to claim 2 wherein the internal-oxidizing barrier is removed by exposing the the second surface portion of the metal member to a reducing agent.

6. A method according to claim 2 wherein the first metal layer is selected from the group consisting of an alloy of cadmium and silver and an alloy of tin, indium and silver, and the second metal layer is selected from the group consisting of an alloy of tin and silver, an alloy of zinc and silver, and an alloy of cadmium and silver.

7. A method according to claim 6 wherein the internal-oxidizing barrier is formed within 0.001 to 0.003 inches of the second surface portion of the metal member.