Detergent gels containing ethoxylated alkyl sulfates and secondary sulfonates

• US 5,607,910 A
• Filed: 12/14/1994
• Issued: 03/04/1997
• Est. Priority Date: 06/30/1993
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Curry, John D., Sherry, Alan E.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): OGDEN JR, NECHOLUS
• Application Number:
  US08/355,765
• Time in Patent Office: 811 Days
• Field of Search: 252/182, 252/551, 252/553, 252/548, 252/544, 252/DIG. 16
• US Class Current: 510/235
• CPC Class Codes: C11D 1/14 derived from aliphatic hydrocarbons or mono-alcohols
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/28 Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 1/37 Mixtures of compounds all of which are anionic
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase

Abstract

The present invention relates to a detergent composition comprising a gel wholly or predominantly in hexagonal liquid crystal phase, said gel comprising:

(a) from about 15% to about 50% ethoxylated alkyl sulfate surfactant by weight of the gel, wherein the alkyl group of the ethoxylated alkyl sulfate surfactant has an average from about 8 to about 20 carbon atoms, and wherein the ethoxylated alkyl sulfate surfactant has an average degree of ethoxylation from about 0.5 to about 15;

(b) from about 1% to about 20%, by weight of the gel, secondary sulfonate surfactant selected from the group consisting of alkylbenzene sulfonates, alkyltoluene sulfonates, paraffin sulfonates, olefin sulfonates, alpha-sulfonated fatty acid alkyl esters, and mixtures thereof;

(c) optionally from 0% to about 15% other surfactants by weight of the gel;

(d) from about 40% to about 80% water by weight of the gel;

(e) from about 0.2% to about 3% magnesium ions by weight of the gel; and

(f) less than 1% hydrotropes by weight of the gel;

wherein the weight ratio of surfactant (a) to surfactant (b) is between about 3:2 and about 10:1, and wherein the total amount of surfactants (a)+(b)+(c) is from about 25% to about 60% by weight of the gel.

Claims

1. A detergent composition comprising a gel wholly or predominantly in hexagonal liquid crystal phase, said gel comprising:

(a) from about 15% to about 50% ethoxylated alkyl sulfate surfactant by weight of the gel, wherein the alkyl group of the ethoxylated alkyl sulfate surfactant has an average from about 8 to about 20 carbon atoms, and wherein the ethoxylated alkyl sulfate surfactant has an average degree of ethoxylation from about 0.5 to about 15;

(b) from about 1% to about 20%, by weight of the gel, secondary sulfonate surfactant selected from the group consisting of alkylbenzene sulfonates, alkyltoluene sulfonates, paraffin sulfonates, olefin sulfonates, alpha-sulfonated fatty acid alkyl esters, and mixtures thereof;

(c) optionally from 0% to about 15%, by weight of the gel, surfactants selected from the group consisting of cationic surfactants, zwitterionic surfactants, ampholytic surfactants, amphoteric surfactants, nonionic surfactants that are not ethoxylated alkyl sulfate surfactants, artionic surfactants that are not secondary sulfonate surfactants, and mixtures thereof;

(d) from about 40% to about 80% water by weight of the gel; and

(e) from about 0.2% to about 3% magnesium ions by weight of the gel;

wherein the gel has a weight ratio of surfactant (a) to surfactant (b) between about 3;

2 and about 10;

1, a total amount of surfactants (a)+(b)+(c) of from about 25% to about 60% by weight of the gel, and a viscosity of from about 500,000 cp to about 6,000,000 cp;

the composition being free of hydrotropes, hydrotropes being water-soluble non-micelle-forming or weakly micelle-forming materials, which contain a large polar group and a small hydrophobic group containing not more than 6 aliphatic carbon atoms, selected from the group consisting of aryl or lower alkylaryl sulfonates, lower alkyl or alkylbenzyl ammonium salts, and lower amides.

2. The composition of claim 1 wherein the secondary sulfonate surfactant is selected from the group consisting of alkylbenzene sulfonates, alkyltoluene sulfonates, paraffin sulfonates, olefin sulfonates, and mixtures thereof.

3. The composition of claim 2 wherein the total amount of surfactants (a)+(b)+(c) is from about 25% to about 50% by weight of the gel.

4. The composition of claim 3 which contains from about 20% to about 45% ethoxylated alkyl sulfate surfactant by weight of the gel.

5. The composition of claim 4 wherein the alkyl group of the ethoxylated alkyl sulfate surfactant has an average from about 8 to about 15 carbon atoms, and wherein the ethoxylated alkyl sulfate surfactant has an average degree of ethoxylation from about 1 to about 6.5.

6. The composition of claim 3 wherein the secondary sulfonate surfactant is selected from the group consisting of alkylbenzene sulfonates, paraffin sulfonates, and mixtures thereof.

7. The composition of claim 5 wherein the secondary sulfonate surfactant is an alkylbenzene sulfonate.

8. The composition of claim 2 wherein the weight ratio of surfactant (a) to surfactant (b) is between about 2:

1 and 5;

1.

9. The composition of claim 7 wherein the weight ratio of surfactant (a) to surfactant (b) is between about 2:

1 and 5;

1.

10. The composition of any of claims 1, 3, 5, 6, 8 or 9 wherein the gel contains substantially no hydrotropes.

11. A detergent composition comprising a gel wholly or predominantly in hexagonal liquid crystal phase, said gel comprising:

(a) from about 15% to about 50% ethoxylated alkyl sulfate surfactant by weight of the gel, wherein the alkyl group of ethoxylated alkyl sulfate surfactant has an average from about 8 to about 20 carbon atoms, and wherein the ethoxylated alkyl sulfate surfactant has an average degree of ethoxylation from about 0.5 to about 15;

(b) from about 1% to about 20%, by weight of the gel, secondary sulfonate surfactant selected from the group consisting of alkylbenzene sulfonates, alkyltoluene sulfonates, paraffin sulfonates, olefin sulfonates, alpha-sulfonated fatty acid alkyl esters, and mixtures thereof;

(c) optionally from 0% to about 15%. by weight of the gel, surfactants selected from the group consisting of cationic surfactants, zwitterionic surfactants, ampholytic surfactants, amphoteric surfactants, nonionic surfactants that are not ethoxylated alkyl sulfate surfactants, anionic surfactants that are not secondary sulfonate surfactants, and mixtures thereof;

(d) from about 40% to about 80% water by weight of the gel; and

(e) from about 0.2% to about 3% magnesium ions by weight of the gel;

wherein the gel has a weight ratio of surfactant (a) to surfactant (b) between about 3;

2 and about 10;

1, a total amount of surfactants (a)+(b)+(c) of from about 25% to about 60% by weight of the gel; and

wherein the composition contains no hydrotropes, hydrotropes being water-soluble non-micelle-forming or weakly micelle-forming materials, which contain a large polar group and a small hydrophobic group containing not more than 6 aliphatic carbon atoms, selected from the group consisting of aryl or lower alkylaryl sulfonates, lower alkyl or alkylbenzyl ammonium salts, and lower amides.

12. The composition of claim 11 wherein the total amount of surfactants (a)+(b)+(c) is from about 25% to about 50% by weight of the gel, and the weight ratio of surfactant (a) to (b) is between about 2:

1 and 5;

1.

13. The composition of claim 12 wherein the secondary sulfonate surfactant is an alkylbenzene sulfonate.

14. The composition of claim 13 wherein the composition comprises from about 20% to about 45% ethoxylated alkyl sulfate surfactant by weight of the gel.

15. The composition of claim 14 wherein the alkyl group of the ethoxylated alkyl sulfate surfactant has an average from about 8 to about 15 carbon atoms, and wherein the ethoxylated alkyl sulfate surfactant has an average degree of ethoxylation from about 1 to about 6.5.