Infrared phosphor and material having latent images and optical reading system using said phosphor

• US 5,611,958 A
• Filed: 05/04/1994
• Issued: 03/18/1997
• Est. Priority Date: 05/11/1993
• Status: Expired due to Term

• Current Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Original Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Inventors: Kanzaki, Hisao, Takeuchi, Yoji, Oshima, Toshio, Fukao, Ryuzo
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US08/238,068
• Time in Patent Office: 1,049 Days
• Field of Search: 202/301.4 P, 250/271, 423/263, 423/306, 235/491, 428/913, 428/690
• US Class Current: 252/301.40P
• CPC Class Codes: B41M 3/144 using fluorescent, luminescent or iridescent effects
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: C09K 11/7701 Chalogenides
• CPC Class Codes: C09K 11/7709 Phosphates
• CPC Class Codes: C09K 11/7756 containing neodynium
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence
• CPC Class Codes: C09K 11/7777 Phosphates
• CPC Class Codes: G06K 19/06046 Constructional details
• CPC Class Codes: G06K 7/12 using a selected wavelength, e.g. to sense red marks and ignore blue marks
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture

Abstract

The invention provides a phosphor excited by infrared rays to emit infrared rays which has a nonacicular particle shape and a particle size of 4 μm or smaller after being synthesized. The phosphor preferably comprises an oxoacid salt-containing compound including at least one element selected from the group consisting of Nd, Yb and Er. The invention further provides a material having a latent image pattern comprising said phosphor and an optical reading system which use the material having a latent image pattern.

Claims

1. An infrared phosphor having nonacicularly-shaped particles that are less than or equal to 4 μ

m in size, the phosphor being stimulated to phosphoresce by infrared light, the infrared phosphor comprising a phosphate compound represented by the following formula;

space="preserve" listing-type="equation">Ln.sub.x B.sub.1-x PO.sub.4

wherein;

B represents at least one element selected from the group consisting of Y, La, Gd, Bi, Ce, Lu, In, Pr and Tb;

Ln represents at least one element selected from the group consisting of Nd;

Yb and Er; and

x is a numerical value of 0.01 to 0.99.

2. A phosphor as in claim 1, wherein:

the phosphor, when stimulated by infrared light, phosphoresces in the range of 800 to 1600 nm.

3. An infrared phosphor according to claim 1, wherein the wavelength of the exciting light coincides with that of the emitted light at room temperature.

4. A material having a latent image comprising:

a substrate; and

a print layer on the substrate;

the print layer including;

an infrared phosphor having nonacicularly-shaped particles that are less than or equal to 4 μ

m in size, the phosphor being stimulated to phosphoresce by infrared light; and

a binder;

wherein the infrared phosphor comprises a phosphate compound represented by the following formula;

space="preserve" listing-type="equation">Ln.sub.x B.sub.1-x PO.sub.4

and wherein;

B represents at least one element selected from the group consisting of Y, La, Gd, Bi, Ce, Lu, In, Pr and Tb;

Ln represents at least one element selected from the group consisting of Nd, Yb and Er; and

x is a numerical value of 0.01 to 0.99.

5. A material having a latent image according to claim 4, wherein the wavelength of the exciting light coincides with that of the emitted light at room temperature.

6. A material having a latent image according to claim 4, wherein thickness of the infrared exciting print layer is in the range of 0.5 to 50 μ

m.

7. A material having a latent image according to claim 4, wherein light reflectance of the surface of the substrate on which the print layer is provided is 20% or higher.

8. A material as in claim 4, wherein:

the phosphor, when stimulated by infrared light, phosphoresces in the range of 800 to 1600 nm.

9. An optical reading system for detecting phosphorescence of a marking substance on an object, the system comprising:

an infrared light emitter;

a marking substance on the object, the marking substance including an infrared phosphor having nonacicularly-shaped particles that are less than or equal to 4 μ

m in size, the phosphor being stimulated to phosphoresce by the infrared light from the light emitter; and

a light detector, the light detector operating after the light emitter turns off so as to detect the phosphorescence from the phosphor;

wherein the infrared phosphor of the marking substance on the object comprises a phosphated compound represented by the following formula;

space="preserve" listing-type="equation">Ln.sub.x B.sub.1-x PO.sub.4

and wherein;

B represents at least one element selected from the group consisting of Y, La, Gd, Bi;

Ce;

Lu, In, Pr and Tb;

Ln represent at least one element selected from the group consisting of Nd, Yb and Er; and

x is a numerical value of 0.01 to 0.99.

10. An optical reading system as in claim 9, wherein:

the phosphor, when stimulated by infrared light from the light emitter, phosphoresces in the range of 800 to 1600 nm.

11. An optical reading system according to claim 9, wherein the wavelength of the exciting light coincides with that of the emitted light at room temperature.