Plastic optical filter

• US 5,611,965 A
• Filed: 08/28/1995
• Issued: 03/18/1997
• Est. Priority Date: 09/07/1994
• Status: Expired due to Fees

• Current Assignee: Kureha Corporation
• Original Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
• Inventors: Katono, Hiroki, Ogihara, Takeo, Sakagami, Teruo, Shouji, Masuhiro
• Primary Examiner(s): TUCKER, PHILIP C
• Application Number:
  US08/519,731
• Time in Patent Office: 568 Days
• Field of Search: 252/582, 252/587, 359/885
• US Class Current: 252/582
• CPC Class Codes: C08F 230/02 containing phosphorus
• CPC Class Codes: C08L 43/02 Homopolymers or copolymers of monomers containing phosphorus
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 5/223 containing organic substances, e.g. dyes, inks or pigments

Abstract

Disclosed herein is a plastic optical filter which has a combined optical function that it has an effect of effectively blocking or attenuating rays in the wavelength range of a near infrared region and excellent luminosity factor-compensating ability and is provided with an optical low-pass filtering function, and is low in specific gravity and hygroscopicity, free from devitrification with time and easy to conduct its processing or machining and polishing treatment.

This plastic optical filter includes a filter base formed of a plastic material comprising a copolymer obtained by copolymerizing a monomer represented by the following formula I:

PO(OH).sub.n R.sub.3-n                                     I

wherein R means a polymerizable functional group represented by the following formula II:

CH.sub.2 ═CXCOO(C.sub.2 H.sub.4 O).sub.m --            II

in which X denotes a hydrogen atom or a methyl group, and m is an integer of 1-5, and n is 1 or 2, with at least one monomer copolymerizable therewith, and an ionic metal component composed of a copper ion incorporated in the copolymer, and a phase grating formed on a surface of the filter base.

Claims

1. A plastic optical filter comprising a filter base formed of a plastic material comprising a copolymer obtained by copolymerizing

a first monomer represented by the following formula I:

space="preserve" listing-type="equation">PO(OH).sub.n R.sub.3-n I

wherein R means a polymerizable functional group represented by the following formula II;

space="preserve" listing-type="equation">CH.sub.2 ═

CXCOO(C.sub.2 H.sub.4 O).sub.m -- II

in which X denotes a hydrogen atom or a methyl group, and m is an integer of 1-5, and n is 1 or 2,

with at least one second monomer copolymerizable therewith, and an ionic metal component composed of a copper ion incorporated in the copolymer;

said plastic material having been cast polymerized in a mold having an inner surface on which a negative pattern of a phase grating is formed, to form a phase grating on a surface of the filter base and

wherein said second monomer is miscible and soluble uniformly with the first monomer, has good radical polymerizability with the first monomer, and forms an optically transparent copolymer.

2. The plastic optical filter according to claim 1, wherein the ionic metal component composed of a copper ion is contained in a proportion of 0.1-20 parts by mass based on 100 parts by mass of the copolymer.

3. The plastic optical filter of claim 1 wherein the second monomer is selected from the group consisting of monofunctional acrylates and methacrylates, polyfunctional acrylates and methacrylates, and unsaturated carboxylic acids.

4. The plastic optical filter of claim 1 wherein the second monomer is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, 2-hydroxybutyl acrylate, 2-hydroxybutyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, n-heptyl acrylate, n-heptyl methacrylate, n-octyl acrylate, n-octyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, glycidyl acrylate, glycidyl methacrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-hydroxy-3-phenoxypropyl methacrylate, phenoxypolyethylene glycol acrylate, phenoxypolyethylene glycol methacrylate, methoxypolyethylene glycol acrylate, methoxypolyethylene glycol methacrylate, 3-chloro-2-hydroxypropyl acrylate;

3-chloro-2-hydroxypropyl methacrylate;

ethylene glycol diacrylate, ethylene glycol dimethacrylate, diethylene glycol diacrylate, diethylene glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, polypropylene glycol diacrylate, polypropylene glycol dimethacrylate, 1,3-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, 1,6-hexanediol diacrylate, 1,6-hexanediol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, 2-hydroxy-1,3-dimethacryloxypropane, 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, 2-hydroxy-1-acryloxy-3-methacryloxypropane, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate;

pentaerythritol tetramethyacrylate;

acrylic acid, methacrylic acid, 2-methacryloyloxyethyl-succinic acid;

2-methacryloyloxyethyl-phthalic acid;

styrene, α

-methylstyrene, chlorostyrene, dibromostyrene, methoxystyrene, divinylbenzene, vinylbenzoic acid, hydroxymethylstyrene, trivinylbenzene and any combination thereof.

5. The plastic optical filter of claim 1, wherein the copolymer is obtained by copolymerizing a monomer mixture of said first and second monomers and wherein said first monomer is used in an amount of 3-60 parts by mass based on 100 parts by mass of the monomer mixture.

6. The plastic optical filter of claim 5, wherein said ionic metal component is contained in an amount of 0.1-20 parts by mass based on 100 parts by mass of the copolymer, said ionic metal component comprising at least 80 mass % copper ion.

7. The plastic optical filter of claim 3, wherein the copolymer is obtained by copolymerizing a monomer mixture of said first and second monomers and wherein said first monomer is used in an amount of 3-60 parts by mass based on 100 parts by mass of the monomer mixture.

8. The plastic optical filter of claim 7, wherein said ionic metal component is contained in an amount of 0.1-20 parts by mass based on 100 parts by mass of the copolymer, said ionic metal component comprising at least 80 mass % copper ion.

9. The plastic optical filter of claim 4, wherein the copolymer is obtained by copolymerizing a monomer mixture of said first and second monomers and wherein said first monomer is used in an amount of 3-60 parts by mass based on 100 parts by mass of the monomer mixture.

10. The plastic optical filter of claim 9, wherein said ionic metal component is contained in an amount of 0.1-20 parts by mass based on 100 parts by mass of the copolymer, said ionic metal component comprising at least 80 mass % copper ion.