Redox reagent-containing post-etch residue cleaning composition
First Claim
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1. A post-etch residue cleaner composition, comprising:
- (a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5;
(b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150°
C. at atmospheric pressure;
(c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I);
##STR4## wherein p is an integer ranging from 1-3;
R1 and R2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II);
##STR5## wherein R5, R6, and R7 are each independently selected from hydrogen, --OH, --CH2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and
R3 and R4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III);
##STR6## wherein X'"'"', Y'"'"', and Z'"'"' are each independently selected from hydrogen, --OH, --CH2 OH, --CH2 CH2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH2 OH or --CH2 CH2 OH;
(d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and
(e) optionally, from about 0% to about 90% by weight of water;
all percents based on the total weight of the cleaner composition.
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Abstract
A noncorrosive post-etch residue cleaning composition containing:
(a) 1-70% by weight of an organic polar solvent having a dipole moment of more than 3.5;
(b) 1-70% by weight of selected amine compounds having at least one hydroxyl group and a boiling point higher than 150° C. at atmospheric pressure;
(c) 0.1-10% by weight of selected amino acid having at least one hydroxyl group;
(d) 1-20% by weight of selected redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7); and
(e) 0-90% by weight of water.
77 Citations
21 Claims
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1. A post-etch residue cleaner composition, comprising:
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(a) from about 1 to about 70% by weight of an organic polar solvent having a dipole moment of more than 3.5; (b) from about 1 to about 70% by weight of an alkanolamine compound having a boiling point higher than 150°
C. at atmospheric pressure;(c) from about 0.1 to about 10% by weight of an amino acid selected from the group consisting of compounds having the formula (I);
##STR4## wherein p is an integer ranging from 1-3;
R1 and R2 are each independently selected from the group consisting of hydrogen and compounds having the formula (II);
##STR5## wherein R5, R6, and R7 are each independently selected from hydrogen, --OH, --CH2 OH, alkyl, alkoxy, phenyl, and mono-, di- or tri-hydroxy-substituted phenyl groups; and
R3 and R4 are each independently selected from the group consisting of hydroxy and compounds having the formula (III);
##STR6## wherein X'"'"', Y'"'"', and Z'"'"' are each independently selected from hydrogen, --OH, --CH2 OH, --CH2 CH2 OH, alkyl, or alkoxy group, and at least one of them is --OH, --CH2 OH or --CH2 CH2 OH;(d) from about 1 to about 20% by weight of a redox reagent having a redox potential in the range between +1.0 V and -2.0 V vs. SHE (at pH=7) selected from the group consisting of sugar alcohols, piperidine, aniline, o-phenylenediamine, hydrazine, 1,10-phenanthroline and benzidine; and (e) optionally, from about 0% to about 90% by weight of water;
all percents based on the total weight of the cleaner composition. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)
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Specification