Method and apparatus for monitoring nylon 11 made from polyamide plastic made from aminoundecanoic acid

• US 5,614,683 A
• Filed: 12/13/1995
• Issued: 03/25/1997
• Est. Priority Date: 12/13/1995
• Status: Expired due to Term

• Current Assignee: David E. Kranbuehl
• Original Assignee: David E. Kranbuehl
• Inventors: Kranbuehl, David E.
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): Politzer, Jay L.
• Application Number:
  US08/571,610
• Time in Patent Office: 468 Days
• Field of Search: 73/866, 73/866.4, 73/86, 73/53.05
• US Class Current: 73/866
• CPC Class Codes: G01N 33/442 Resins; Plastics

Abstract

The molecular weight of NYLON 11® (a polyamide made from aminoundecanoic acid) has been found to be a reliable indicator of the mechanical properties and remaining useful life of parts made therefrom. By periodically monitoring the molecular weight, and comparing the measured molecular weight to a standard curve or table, the expected useful life remaining, rate of deterioration, time of part replacement, and mechanical properties of a part can be determined. The molecular weight may advantageously be determined using witness coupons placed in close proximity to the part such that they are exposed to the same processing and environmental conditions as the part. These witness coupons can advantageously be retrieved at the required time period using a spooled piece of pipe or the like. Alternatively, the molecular weight may advantageously be determined from core samples taken from the part being monitored, during use in the field, on a periodic basis. In addition, the molecular weight might also be inferred from a sample held in a laboratory which is exposed to substantially the same environmental conditions as the part. The molecular weight measurements can be made using standard techniques and equipment such as a viscometer, gel permeation equipment, or light scattering equipments.

Claims

1. A method for evaluating percent of life remaining, used up, and rate of aging a part made of a polyamide formed from aminoundecanoic acid comprising the steps of:

determining a start time for use of said part made of said polyamide;

measuring a molecular weight of said polyamide, said measuring step being performed at a measurement time;

identifying a use time for said part made of said polyamide by subtracting said start time from said measurement time;

comparing said molecular weight measured during said measuring step to a standard curve or table which correlates molecular weight to time; and

assessing life information for said part made of said polyamide as a function of said use time, said molecular weight, and said standard curve or table, said life information being selected from the group consisting of life remaining for said part, life used up for said part, and rate at which life of said part is being used up.

2. The method of claim 1 wherein said step of measuring is performed with a viscometer, and wherein said molecular weight measured during said step of measuring is a viscosity averaged molecular weight.

3. The method of claim 1 wherein said step of measuring further comprises the step of obtaining a sample from said part made of said polyamide, said measuring step being performed on said sample.

4. The method of claim 1 wherein said step of measuring comprises the step of retrieving a witness coupon made of said polyamide from a position where said witness coupon is exposed to an environment identical to said part made of said polyamide, said measuring step being performed on said witness coupon.

5. The method of claim 1 wherein said step of measuring comprises the step of aging a sample of said polyamide in an environment which duplicates or simulates a field environment for said part made of said polyamide, said measuring step being performed on said sample of said polyamide.

6. The method of claim 1 wherein said comparing step includes the step of using a graph as said standard curve or table.

7. The method of claim 1 wherein said comparing step includes the step of using a table as said standard curve or table.

8. The method of claim 1 wherein said step of assessing life information provides a value for life remaining for said part made of said polyamide.

9. The method of claim 1 wherein said step of assessing life information provides a value for life used up for said part made of said polyamide.

10. The method of claim 1 wherein said step of assessing life information provides a value for a rate at which life of said part made of said polyamide is being used up.

11. The method of claim 1 wherein said measuring step, said identifying step, said comparing step, and said assessing life information step are each performed repeatedly at prescribed intervals.

12. The method of identifying a time to replace parts made of a polyamide formed from aminoundecanoic acid in a service environment, comprising the steps of:

measuring a molecular weight of said polyamide for said part made of said polyamide;

determining if said molecular weight from said measuring step is greater than a threshold value; and

indicating said part made of said polyamide is in need of replacement if said molecular weight is below said threshold value.

13. The method of claim 12 wherein said step of measuring includes the step of providing a viscosity averaged molecular weight value as said molecular weight, and wherein said determining step includes the step of using 17,000 as said threshold value.

14. The method of claim 12 wherein said step of measuring comprises the step of obtaining a sample from said part made of said polyamide, said measuring step being performed on said sample.

15. The method of claim 12 wherein said step of measuring comprises the step of retrieving a witness coupon made of said polyamide from a position where said witness coupon is exposed to an environment identical to said part made of said polyamide, said measuring step being performed on said witness coupon.

16. The method of claim 12 wherein said step of measuring comprises the step of aging a sample of said polyamide in an environment which simulates a field environment for said part made of said polyamide, said measuring step being performed on said sample of said polyamide.

17. A method of evaluating a part made of a polyamide formed from aminoundecanoic acid, comprising the steps of:

measuring a molecular weight of said polyamide used in said part;

using said molecular weight to assess life information selected from the group consisting of life remaining for said part, life used up for said part, modulus, and elongation and load at yield and break.