Recyclable polymeric label paper

• US 5,616,384 A
• Filed: 12/02/1993
• Issued: 04/01/1997
• Est. Priority Date: 03/05/1990
• Status: Expired due to Fees

• Current Assignee: Polyweave International LLC
• Original Assignee: International Paper Company
• Inventors: Monroe, Stephen H., Angelini, Peter J., Goettmann, James A., Boylan, John R.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): WILLIAMSON, MICHAEL A
• Application Number:
  US08/161,358
• Time in Patent Office: 1,216 Days
• Field of Search: 428/35.7, 428/36.1, 428/36.4, 428/284, 428/286, 428/287, 428/290, 428/343, 428/347, 428/373, 428/374, 428/394, 428/395, 428/36.9, 428/36.91, 428/36.92, 204/509, 215/1 C, 168/135, 168/157.5
• US Class Current: 428/36.1
• CPC Class Codes: D04H 1/4291 Olefin series
• CPC Class Codes: D04H 1/4309 Polyvinyl alcohol
• CPC Class Codes: D04H 1/435 Polyesters
• CPC Class Codes: D04H 1/43828 sheath-core
• CPC Class Codes: D04H 1/43835 Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• CPC Class Codes: D04H 1/54 by welding together the fibres, e.g. by partially melting or dissolving in combination with needling D04H1/485
• CPC Class Codes: D21H 13/14 Polyalkenes, e.g. polystyrene polyethylene
• CPC Class Codes: G09F 3/04 to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion by a separate adhesive layer G09F3/10
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1362 Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
• CPC Class Codes: Y10T 428/1372 Randomly noninterengaged or randomly contacting fibers, filaments, particles, or flakes
• CPC Class Codes: Y10T 428/139 Open-ended, self-supporting conduit, cylinder, or tube-type article
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]

Abstract

An in-mold label material is a nonwoven mat of fibers having one side fused with the outer surface of a polymeric container and the other side coated with a pigment-containing latex suitable for printing thereon. The label paper is manufactured from commercially available fibers combined in water into a homogeneous mixture and then formed into a mat employing a wet-lay process. For use with polyethylene containers, the label may be a web consisting of 88-100% polyethylene fibers and 0-15% polyvinyl alcohol fibers or 70-100% polyethylene fibers, 0-15% polyvinyl alcohol fibers and 0-30% polypropylene fibers. For use with polyester containers, the label may be a web consisting of 50-90% polyester staple fibers, 10-40% bicomponent polyester/co-polyester, core/sheath binder fibers and 0-10% polyvinyl alcohol binder fibers thermally bonded together. The nonwoven web of fibers has a pigmented coating. After the material has been cut into labels, the labels may be applied to the blow-molded containers in-mold without the use of an adhesive material using a conventional in-mold labeling technique or post-mold using adhesive.

Claims

1. In a labeled plastic container comprising a blow-molded container made of polyethylene and having an outer surface and a non-film polymeric label attached to said outer surface of said blow-molded container, the improvement wherein said label consists of a nonwoven web of wet-laid fibers bonded to said outer surface of said blow-molded container, said fibers comprising polyethylene pulp and none of said fibers being made of cellulosic material, said web having a continuous coating of pigmented binder formed on at least one surface thereof which provides a printable surface, said polyethylene pulp being bonded by said pigmented binder without substantial thermal fusion of said polyethylene pulp by curing said binder at temperatures below the melting temperature of said polyethylene.

2. The labeled plastic container as defined in claim 1, wherein the fiber composition of said nonwoven web is 85-100% polyethylene pulp and 0-15% polyvinyl alcohol binder fibers.

3. The labeled plastic container as defined in claim 1, wherein said binder comprises ethylene vinyl chloride.

4. The labeled plastic container as defined in claim 3, wherein the ratio of pigment to binder lies in the range from 0.5/1 to 8/1.

5. The labeled plastic container as defined in claim 1, wherein the fiber composition of said nonwoven web is 70-100% polyethylene pulp, 0-12% polyvinyl alcohol binder fibers and 0-30% polypropylene staple fibers.

6. A nonwoven composite web for use in making a cellulose-free, non-film polymeric labeled plastic container, consisting of a nonwoven web of 100% fibers entangled by a wet-lay process, said container being made of polyester and said web having the following fiber composition:

50-90% chopped polyester staple fibers;

10-40 wt. % binder fibers containing a co-polyester material having a melting temperature less than the melting temperature of said chopped polyester staple fibers; and

0-10% polyvinyl alcohol binder fibers.

7. The nonwoven composite web as defined in claim 6, wherein said binder fibers comprise bicomponent fibers having a sheath made of co-polyester and a core made of polyester, said polyester co-polyester sheath having a melting temperature which is less than the melting temperature of said chopped polyester staple fibers.

8. The nonwoven composite web as defined in claim 6, wherein said web is thermal calendared at a pressure of 50-150 PLI to fuse said chopped polyester staple fibers at the surfaces of said web.

9. The nonwoven composite web as defined in claim 8, wherein said thermal calendared web is saturated on at least one side thereof with a continuous coating of pigmented binder.