Process for producing moldings from foamed polyolefins

• US 5,618,478 A
• Filed: 03/29/1996
• Issued: 04/08/1997
• Est. Priority Date: 03/31/1995
• Status: Expired due to Fees

• Current Assignee: Huels Aktiengesellschaft
• Original Assignee: Huels Aktiengesellschaft
• Inventors: Traeger, Michael, Wirobski, Reinhard
• Primary Examiner(s): Kuhns, Allan R.
• Application Number:
  US08/623,865
• Time in Patent Office: 375 Days
• Field of Search: 264/50, 264/51, 264/45.4, 264/53
• US Class Current: 264/50
• CPC Class Codes: C08J 2323/02 not modified by chemical after treatment
• CPC Class Codes: C08J 9/228 Forming foamed products

Abstract

A process for producing a molding from prefoamed polyolefin particles, involving: shrinking the prefoamed polyolefin particles to a volume of from 30 to 95% of the prefoamed polyolefin particles original volume to provide shrunken particles; treating the shrunken particles at a temperature lying at least 20° C. below the softening temperature of the shrunken particles, in an inert gas atmosphere under a gauge pressure of from 0.2 to 10 bar, for a time sufficient to provide expansion of the shrunken particles upon removal of the pressure; charging the particles into a mold with substantial maintenance of internal pressure of the particles; and foaming the particles, to provide moldings of very low density useful in applications such as packaging and soft upholstering in motor vehicle interiors.

Claims

1. A process for producing a molding from prefoamed polyolefin particles, comprising the steps of:

a) providing shrunken prefoamed polyolefin particles having a volume of from 30 to 95% of the original volume of the prefoamed polyolefin particles;

b) treating the shrunken particles at a temperature lying at least 20°

C. below the softening temperature of the shrunken particles, in an inert gas atmosphere under a gauge pressure of from 0.2 to 10 bar, for a time sufficient to provide expansion of the shrunken particles upon removal of said gauge pressure;

c) charging the particles into a mold with substantial maintenance of internal pressure of the particles; and

d) foaming the particles.

2. The process according to claim 1, wherein the gauge pressure of the inert gas is from 0.5 to 6 bar.

3. The process according to claim 1, wherein the inert gas used is air, nitrogen or CO₂.

4. The process according to claim 1, wherein the shrunken particles are essentially free of volatile organic blowing agent.

5. The process according to claim 1, wherein the prefoamed polyolefin particles comprise a propylene-ethylene random copolymer, a propylene-but-1-ene random copolymer or a random terpolymer of ethylene, propylene and but-1-ene.

6. The process of claim 1, wherein said sufficient time is from 5 min to 2 hours.

7. The process of claim 1, wherein said temperature of said treating step is ≧

30°

C. below the softening temperature of the shrunken particles.

8. The process of claim 1, wherein step b) is carried out in a pressure container other than the mold used in step c).

9. The process of claim 8, wherein the shrunken particles from the pressure container in step b) are conveyed to the mold in step c) by pressure difference acting as a driving force.