Dialysis separation of heat stable organic amine salts in an acid gas absorption process

• US 5,622,681 A
• Filed: 08/09/1995
• Issued: 04/22/1997
• Est. Priority Date: 01/21/1992
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Rapstein, Kirby T., Grierson, Jeffrey G.
• Primary Examiner(s): Lewis, Michael
• Assistant Examiner(s): DI MAURO, PETER T
• Application Number:
  US08/513,165
• Time in Patent Office: 622 Days
• Field of Search: 423/228, 423/229, 423/242.6, 423/242.7, 210/638
• US Class Current: 423/228
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 61/243 Dialysis

Abstract

There is disclosed an organic amine scrubbing process for acid gas abatement of gas streams. The process comprises Donnan dialysis of an absorbent solution to separate and convert organic amine heat stable salts back to free amine absorbent using an anion exchange or neutral membrane. The organic amine absorbent may be an alkanolamine, a substituted or unsubstituted 5-7 member heterocyclic amine or any organic amine suitable for acid gas scrubbing. There is also disclosed a dialysis cell comprising a two compartment cell separated by a membrane. The cell includes a charge of an organic amine high in the organic amine heat stable salt concentration in one compartment and a charge of a base solution in the other compartment. Also disclosed is a process for abating acid gases wherein the organic amine absorbent is regenerated by Donnan dialysis, and an apparatus for effecting the regeneration.

Claims

1. A method using Donnan exclusion principles wherein an ion exchange occurs across a membrane occurs for converting heat stable organic amine salts to a thermally regenerable amine absorbent for acid gases, comprising the steps of:

(a) feeding an organic amine absorbent solution containing greater than 0.5 percent by weight of heat stable organic amine salts into a first compartment of a dialysis cell whereby said organic amine salts ionize to form heat stable salt anions and organic amine portions, wherein said organic absorbent solution in said first compartment is separated from an aqueous base dialyzing solution in a second compartment of the dialysis cell by a membrane;

(b) inducing an exchange of heat stable salt anions in said first compartment for hydroxyl anions in said second compartment by maintaining an effective hydroxide concentration differential between said compartments to regenerate free amine in said first compartment without the use of electrical potential to drive the ion exchange; and

(c) withdrawing absorbent solution from said first compartment having a reduced heat stable organic amine salt concentration and an enhanced free amine concentration.

2. The method of claim 1, wherein the amine component of said organic absorbent solution concentration ranges from greater than about 0.5 percent by weight to less than 100 percent by weight.

3. The method of claim 1, wherein the amine component of said organic absorbent solution concentration ranges from about 5 percent by weight to 70 percent by weight.

4. The method of claim 1, wherein the amine component of said organic absorbent solution concentration ranges from about 10 percent by weight to 60 percent by weight.

5. The method of claim 1, wherein said organic amine salt that is tied up in the heat stable salt ranges from about 0.5 to 10 percent by weight of the solution.

6. The method of claim 1, wherein said organic amine salt that is tied up in the heat stable salt ranges from about 2 to 5 percent by weight of the solution.

7. The method of claim 1, wherein said base solution is substantially free of amine and has a concentration that ranges from about 0.05 to about 20 percent by weight.

8. The method of claim 1, wherein said base solution is substantially free of amine and has a concentration that ranges from about 0.1 to about 10 percent by weight.

9. The method of claim 1, wherein said base dialyzing solution is selected from the group consisting of hydroxides, bicarbonates, carbonates, or mixtures thereof.

10. A method using Donnan exclusion principles wherein an ion exchange across a membrane occurs for abating acid gas in a gas stream, comprising the steps of:

(a) contacting a gas stream containing said acid gas with an absorbent solution comprising an aqueous organic amine compound, wherein said acid gas is absorbed by said absorbent producing an acid rich organic amine absorbent solution and wherein a portion of said absorbent forms organic amine heat stable salts and a portion forms a non heat stable acid fraction;

(b) thermally stripping the non heat stable acid fraction from the acid rich absorbent solution to produce an acid lean organic amine absorbent solution containing organic amine heat stable salts;

(c) feeding at least a portion of said acid lean absorbent solution containing greater than 0.5 percent by weight of said absorbent heat stable salts into a first compartment of a dialysis cell, wherein said acid lean absorbent solution in said first compartment is separated from an aqueous base solution in a second compartment by a membrane;

(d) exchanging organic amine heat stable salt anions in said first compartment for hydroxyl anions in said second compartment by maintaining an effective base concentration differential between said compartments to regenerate free organic amine absorbent in said first compartment without the use of electrical potential to drive the ion exchange;

(e) withdrawing the acid lean absorbent solution from said first compartment which has a reduced heat stable salt concentration and an enhanced free amine concentration; and

(f) recycling said absorbent solution having enhanced free amine concentration to said contacting step.

11. The method of claim 10, wherein the amine component of said organic absorbent solution concentration ranges from greater than about 0.5 percent by weight to less than 100 percent by weight.

12. The method of claim 10, wherein the amine component of said organic absorbent solution concentration ranges from about 5 percent by weight to 70 percent by weight.

13. The method of claim 10, wherein the amine component of said organic absorbent solution concentration ranges from about 10 percent by weight to 60 percent by weight.

14. The method of claim 10, wherein said organic amine salt that is tied up in the heat stable salt ranges from about 0.5 to 10 percent by weight of the solution.

15. The method of claim 10 wherein said organic amine salt that is tied up in the heat stable salt ranges from about 2 to 5 percent by weight of the solution.

16. The method of claim 10, wherein said base solution is substantially free of amine and has a concentration that ranges from about 0.05 to about 20 percent by weight.

17. The method of claim 10, wherein said base solution is substantially free of amine and the concentration ranges from about 0.1 to about 10 percent by weight.

18. The method of claim 10, wherein said base solution is selected from the group consisting of hydroxides, bicarbonates, carbonates, or mixtures thereof.

19. The method of claim 10, wherein said amine acid gas absorbent comprises an alkanolamine.

20. The method of claim 10, wherein said amine acid gas absorbent comprises a substituted or unsubstituted 5 to 7 member heterocyclic amine.

21. The method of claim 10, wherein said amine is selected from the group consisting of MEA, MDEA, and 4-(2-hydroxyalkyl)-2-piperazinone.