Polyurethane sealant compositions
First Claim
1. A polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of from about 2.0 to about 4.0 and an isocyanate content of from about 1.0 to 10 percent:
- and from about 0.5 to about 20 percent by weight based on the sealant composition of (2) a reaction product of a secondary aminoalkoxy silane and an aliphatic or aromatic polyisocyanate selected from the group consisting of ethylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,12-dodecane diisocyanate, cyclobutane1,3-diisocyanate, cyclohexane-1,3- and 1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanato methyl cyclohexane, 2,4- and 2,6-hexahydrotolylene diisocyanate, hexahydro-1,3- and 1,4-phenylene diisocyanate, perhydro-2,5'"'"'- and 4,4'"'"'-diphenyl methane diisocyanate, 1,3- and 1,4-phenylene diisocyanate, 2,4-and 2,6-tolylene diisocyanate, diphenyl methane-2,4'"'"'and 4,4'"'"'-diisocyanate, naphthylene-1,5-diisocyanate, triphenyl methane-4,4'"'"',4"-triisocyanate, polyphenyl polymethylene polyisocyanate, isophorone diisocyanate, tetramethylxylene diisocyanate and mixtures thereof, said reaction product having an average of at least one silane group and at least one isocyanate group per molecule and a molecular weight of less than about 2,000, wherein the sealant composition does not contain bitumin.
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Accused Products
Abstract
Described herein is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a molecular weight of at least about 2,000; and (2) the reaction product of a secondary amino- or mercaptoalkoxy silane and a polyisocyanate having an average of at least one silane group and at least one isocyanate group per molecule and a molecular weight of less than about 2,000. The sealant composition of the invention is particularly useful in bonding glass to metal substrates when the glass substrate has not been primed with an application of a separate primer composition prior to the application of the sealant.
148 Citations
26 Claims
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1. A polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of from about 2.0 to about 4.0 and an isocyanate content of from about 1.0 to 10 percent:
- and from about 0.5 to about 20 percent by weight based on the sealant composition of (2) a reaction product of a secondary aminoalkoxy silane and an aliphatic or aromatic polyisocyanate selected from the group consisting of ethylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,12-dodecane diisocyanate, cyclobutane1,3-diisocyanate, cyclohexane-1,3- and 1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanato methyl cyclohexane, 2,4- and 2,6-hexahydrotolylene diisocyanate, hexahydro-1,3- and 1,4-phenylene diisocyanate, perhydro-2,5'"'"'- and 4,4'"'"'-diphenyl methane diisocyanate, 1,3- and 1,4-phenylene diisocyanate, 2,4-and 2,6-tolylene diisocyanate, diphenyl methane-2,4'"'"'and 4,4'"'"'-diisocyanate, naphthylene-1,5-diisocyanate, triphenyl methane-4,4'"'"',4"-triisocyanate, polyphenyl polymethylene polyisocyanate, isophorone diisocyanate, tetramethylxylene diisocyanate and mixtures thereof, said reaction product having an average of at least one silane group and at least one isocyanate group per molecule and a molecular weight of less than about 2,000, wherein the sealant composition does not contain bitumin.
- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
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16. A polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least 2.0 and an isocyanate content of from about 1.0 to 10 percent wherein isocyanate prepolymer is prepared from a polyisocyanate having a functionality of from about 2.0 to about 4.0 and a polyol having a functionality of from about 1.5 to about 4.0 and an equivalent weight of about 200 to about 3,500;
- and from about 0.5 to about 20 percent by weight based on the sealant composition of (2) a reaction product of a secondary aminoalkoxy silane and an aliphatic or aromatic polyisocyanate selected from the group consisting of ethylene diisocyanate, 1,4tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,12-dodecane diisocyanate, cyclobutane1,3-diisocyanate, cyclohexane-,1,3- and 1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanato methyl cyclohexane, 2,4- and 2,6-hexahydrotolylene diisocyanate, hexahydro-1,3- and 1,4-phenylene diisocyanate, perhydro-2,5'"'"'- and 4,4'"'"'-diphenyl methane diisocyanate, 1,3- and 1,4-phonylone diisocyanate, 2,4-and 2,6-tolylene diisocyanate, diphenyl methane-2,4'"'"'-and 4,4'"'"'-diisocyanate, naphthylene-1,5-diisocyanate, triphenyl methane-4,4'"'"',4"-triisocyanate, polyphenyl polymethylerie polyisocyanate, isophorone diisocyanate, tetramethylxylene diisocyanate and mixtures thereof, said reaction product having an average of at least one silane group and at least one isocyanate group per molecule and a molecular weight of less than about 2,000, wherein the sealant composition does not contain bitumin.
- View Dependent Claims (17, 18, 19, 20, 21, 22, 23, 24, 25, 26)
Specification