Method and apparatus for the detection of toxic gases
First Claim
1. An electrochemical cell for detecting chlorine, fluorine and bromine gas in ambient air comprising:
- a platinum counter electrode;
a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish;
an electrolyte comprising 30% through 50% by weight potassium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes;
a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and
means providing a fixed potential of approximately -150 through -250 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the chlorine, fluorine and bromine gas to be detected.
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Abstract
A compact electrochemical cell utilized for the detection of numerous toxic gases. The cell includes working and counter electrodes, surrounded by a liquid electrolyte, all of which is enclosed behind a gas permeable, hydrophobic membrane. The working electrode may be a single electrode or may be composed of multiple glassy carbon electrodes arranged in a planar electrode array. The counter electrode is either spatially separated from the array or comprises one or more electrodes in the array. The electrolyte composition varies with the type of gas to be detected and can be aqueous, partially aqueous, or substantially non-aqueous. The electrolyte includes an alkali metal halide. A fixed potential applied between the working and counter electrodes is sufficient to initiate electrochemical reactions in the presence of the gas to be detected without interfering reactions of the electrolyte or air.
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Citations
24 Claims
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1. An electrochemical cell for detecting chlorine, fluorine and bromine gas in ambient air comprising:
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a platinum counter electrode; a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising 30% through 50% by weight potassium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately -150 through -250 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the chlorine, fluorine and bromine gas to be detected. - View Dependent Claims (2, 3, 4, 5, 6, 7)
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8. An electrochemical cell for detecting hydrogen sulfide gas in ambient air comprising:
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a platinum counter electrode, a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising approximately 0.4% through 0.8% by weight copper sulfate and approximately 30% through 50% by weight lithium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately -20 through -60 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the hydrogen sulfide gas to be detected. - View Dependent Claims (9, 10, 11)
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12. An electrochemical cell for detecting chlorine dioxide, nitrogen dioxide, ozone and hydrogen peroxide gas in ambient air comprising:
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a platinum counter electrode; a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising approximately 30% through 50% by weight lithium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately -150 through -250 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the chlorine dioxide, nitrogen dioxide, ozone and hydrogen peroxide gas to be detected. - View Dependent Claims (13, 14, 15)
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16. An electrochemical cell for detecting hydrogen chloride, hydrogen fluoride, hydrogen bromide, sulfur dioxide, nitric acid and sulfuric acid gas in ambient air comprising:
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a platinum counter electrode; a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising approximately 0.4% through 1.0% by weight potassium bromate and approximately 30% through 50% by weight potassium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately -150 through -250 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with hydrogen chloride, hydrogen fluoride, hydrogen bromide, sulfur dioxide, nitric acid and sulfuric acid gas to be detected. - View Dependent Claims (17, 18)
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19. An electrochemical cell for detecting ammonia in ambient air comprising:
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a platinum counter electrode; a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising approximately 0.3% through 0.5% by weight copper sulfate, approximately 0.6% through 0.8% by weight tris amine buffer, and approximately 30% through 50% by weight lithium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately +40 through -100 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the ammonia gas to be detected. - View Dependent Claims (20)
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21. An electrochemical cell for detecting hydrogen cyanide gas in ambient air comprising:
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a platinum counter electrode; a plurality of glassy carbon working electrodes having exposed surfaces finished to a high polish; an electrolyte comprising approximately 0.3% through 0.5% by weight copper sulfate, approximately 0.3% through 0.6% by weight tris amine buffer, and approximately 30% through 50% by weight lithium bromide in operative contact with said counter electrode and said exposed surfaces of said working electrodes; a gas permeable hydrophobic membrane enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell; and means providing a fixed potential of approximately -20 through -50 millivolts applied between said counter electrode and said plurality of working electrodes to initiate electrochemical reactions only with the hydrogen cyanide gas to be detected.
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22. A method of detecting ammonia gas in ambient air with an electrochemical cell comprising the steps of:
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providing a platinum counter electrode; providing a plurality of glassy carbon working electrodes having surfaces finished to a high polish; operatively contacting said counter electrode and said plurality of exposed surfaces of said working electrodes with an electrolyte comprising approximately 0.3% through 0.5% by weight copper sulfate, approximately 0.6% through 0.8% by weight tris amine buffer, and approximately 30% through 50% by weight lithium bromide; enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell by a gas permeable hydrophobic membrane; and applying a fixed potential of approximately +40 through -100 millivolts between said counter electrode and said plurality of working electrodes sufficient to initiate electrochemical reactions only with the ammonia gas to be detected.
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23. A method of detecting chlorine, fluorine and bromine gas in ambient air with an electrochemical cell comprising the steps of:
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providing a platinum counter electrode; providing a plurality of glassy carbon working electrodes having surfaces finished to a high polish; operatively contacting said counter electrode and said plurality of exposed surfaces of said working electrodes with an electrolyte comprising 30% through 50% by weight potassium bromide; enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell by a gas permeable hydrophobic membrane; and applying a fixed potential of approximately -150 through -250 millivolts between said counter electrode and said plurality of working electrodes sufficient to initiate electrochemical reactions only with the chlorine, fluorine and bromine gas to be detected.
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24. A method of detecting hydrogen chloride, hydrogen fluoride, hydrogen bromide, sulfur dioxide, nitric acid and sulfuric acid gas in ambient air with an electrochemical cell comprising the steps of:
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providing a platinum counter electrode; providing a plurality of glassy carbon working electrodes having surfaces finished to a high polish; operatively contacting said counter electrode and said plurality of exposed surfaces of said working electrodes with an electrolyte comprising approximately 0.4% through 1.0% by weight potassium bromate and approximately 30% through 50% by weight potassium bromide; enclosing said counter electrode, said plurality of working electrodes, and said electrolyte within said cell by a gas permeable hydrophobic membrane; and applying a fixed potential of approximately -150 through -250 millivolts between said counter electrode and said plurality of working electrodes sufficient to initiate electrochemical reactions only with the hydrogen chloride, hydrogen fluoride, hydrogen bromide, sulfur dioxide, nitric acid and sulfuric acid gas to be detected.
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Specification