Thermally insulating jacket under reversible vacuum utilizing hydrogen getter in combination with non-evaporable promoter getter

• US 5,625,742 A
• Filed: 07/06/1994
• Issued: 04/29/1997
• Est. Priority Date: 07/08/1993
• Status: Expired due to Term

• Current Assignee: SAES Getters SpA (SAES Getters S)
• Original Assignee: SAES Getters SpA (SAES Getters S)
• Inventors: Ferrario, Bruno, della Porta, Paolo, Conte, Andrea, Boffito, Claudio
• Primary Examiner(s): Walberg, Teresa J.
• Assistant Examiner(s): Jeffrey, John A.
• Application Number:
  US08/268,536
• Time in Patent Office: 1,028 Days
• Field of Search: 392/345, 392/339, 392/346, 165/96, 165/135, 165/902, 165/18, 126/400, 126/658, 126/653, 429/120, 313/553-555, 220/420-422, 373/112
• US Class Current: 392/345
• CPC Class Codes: F16L 59/075 the air layer or the vacuum being delimited by longitudinal channels distributed around the circumference of a tube
• CPC Class Codes: F17C 3/08 by vacuum spaces, e.g. Dewar flask for household use A47J41/02
• CPC Class Codes: F24S 10/45 the enclosure being cylindrical
• CPC Class Codes: F24S 40/46 Maintaining vacuum, e.g. by using getters
• CPC Class Codes: H01M 10/613 Cooling or keeping cold
• CPC Class Codes: H01M 10/6554 Rods or plates
• CPC Class Codes: H01M 10/658 by thermal insulation or shielding
• CPC Class Codes: H01M 50/24 adapted for protecting batteries from their environment, e.g. from corrosion thermal insulation H01M10/658
• CPC Class Codes: Y02E 10/44 Heat exchange systems
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/32 Hydrogen storage

Abstract

A thermally insulating jacket under reversible vacuum, having an inner wall, an outer wall and an hollow space between these walls. The hollow space is in fluid communication with an outer housing containing a reversible non-evaporable hydrogen getter loaded with hydrogen. The reversible hydrogen getter has a certain hydrogen equilibrium pressure. The hollow space contains a non-evaporable promoter getter having a certain hydrogen equilibrium pressure. These jackets can be employed with heat accumulators, batteries, cryogenic vessels, cryogenic pipes, catalytic silencers and solar panels.

Claims

1. A thermally insulating jacket under reversible vacuum, having an inner wall, an outer wall and an hollow space between said walls in fluid communication with an outer housing containing a reversible non-evaporable hydrogen getter loaded with hydrogen before use, wherein:

a) said reversible hydrogen getter has hydrogen equilibrium pressure px₁ lower than 100 mbar at 500°

C., when the hydrogen concentration in the getter is 0.1% by weight, and is kept at a variable or constant temperature Ti different from the temperature Tc of the hotter wall of the jacket;

b) said hollow space contains a non-evaporable promoter getter having a hydrogen equilibrium pressure Px₂ higher than 100 mbar at 500°

C., when the hydrogen concentration in the getter is 0.1% by weight, which is exposed to a temperature Tc different from Ti.

2. An insulating jacket according to claim 1, wherein the amount of hydrogen in said reversible hydrogen getter before use is corresponding to a working pressure inside the jacket, ranging from 5 Pa, when the temperature is at room level, to 50 Pa, when the temperature is at 500°

C.

3. An insulating jacket according to claim 1, wherein said promoter getter is in contact with said hotter wall.

4. A jacket according to claim 1, wherein said pressure Px₁ is lower than 1000 Pa and wherein said pressure Px₂ is higher than ten times Px₁.

5. A jacket according to claim 4, wherein-- said pressure Px₁ is lower than 1000 Pa and wherein said pressure Px₂ is higher than one hundred times Px₁.

6. A jacket according to claim 1, wherein said reversible hydrogen getter is coated with a protective layer of said promoter getter, which is kept at the same temperature Ti of said reversible hydrogen getter.

7. A jacket according to claim 6, wherein said protective layer is surmounted by a porous septum.

8. A jacket according to claim 7, wherein the ration between the mass of said protective layer and the sum of the mass of said reversible hydrogen getter and of the mass of the promoter getter exposed to said temperature Tc is from 0.001:

1 to 1;

1.

9. A jacket according to claim 8, wherein the ration between the mass of said protective layer and the sum of the mass of said reversible hydrogen getter and of the mass of the promoter getter exposed to said temperature Tc is from 0.01:

1 to 0.5;

1.

10. A jacket according to claim 8, wherein at least 85% by volume of the particles has an average size lower than 100 micrometers and wherein the volume percentage of the particles having an average size lower than 15 micrometers is equal to or lower than 10%.

11. A jacket according to claim 1, having a characteristic working pressure ranging from 0.1 Pa, when the temperature is at room level, to 100 Pa, when the temperature is 500°

C.

12. A jacket according to claim 1, having a characteristic return time, namely the time required by the passage from a pressure of 100 Pa, when said temperature ti is 500°

C., too a pressure of 1 Pa, when said temperature Ti is at room level, lower than 10 minutes either in the absence or in the presence of carbon monoxide.

13. A jacket according to claim 1, having a characteristic deep return time, namely the time required by the passage from a pressure of 100 Pa, when said temperature Ti is 500°

C., to a pressure of 0.1 Pa, when said temperature Ti is at room level, lower than 15 minutes, either in the absence or in the presence of carbon monoxide.

14. A jacket according to claim 10, having a characteristic deep return time, namely the time required by the passage from a pressure of 100 Pa, when said temperature Ti is 500°

C., to a pressure of 0.1 Pa, when said temperature Ti is at room level, lower than 12 minutes, either in the absence or in the presence of carbon monoxide.

15. A jacket according to claim 1, wherein said promoter getter is selected from the alloys ZrM₂, wherein M is a transition element selected from Cr, Mn, Fe, Co, Ni and mixtures thereof.

16. A jacket according to claim 12, wherein said reversible hydrogen getter is a non-evaporable ternary getter alloy having a percent composition by weight which when recorded on a diagram suitable from ternary compositions, is lying inside a polygon having at its vertices the points defined as follows:

A) 78% Zr--20% V--2% Fe

B) 45% Zr--20% V--35% Fe

C) 48% Zr--50% V--2% Fe.

17. A jacket according to claim 1, wherein said promoter getter is selected from:

i) the zirconium-manganese-iron alloys (Zr, Mn, Fe);

ii) the titanium-vanadium alloys having a high manganese content;

iii) the titanium-vanadium alloys having a low manganese content;

iv) the titanium-nickel alloys and/or the lanthanum-nickel alloys of the AB₅ type;

v) mixtures thereof.

18. A jacket according to claim 1, wherein said reversible hydrogen getter is selected from:

i) the alloys containing zirconium and vanadium and in particular the zirconium-vanadium-iron alloys;

ii) the zirconium-aluminum alloys;

iii) zirconium;

iv) titanium;

v) mixtures thereof.

19. A jacket according to claim 1, supplied with a heating device which is outside said housing containing said reversible hydrogen getter.

20. A jacket according to claim 1, supplied with a heating device which is directly immersed in said reversible hydrogen getter.

21. A jacket according to claim 17, wherein said heating device is supplied with heat dispersing blades.

22. A jacket according to claim 1, wherein said heating device is supplied with heat dispersing fins.

23. A jacket according to claim 1, wherein said hollow space contains solid insulating material, in particular polystyrene, phenolformaldehyde resins, polyacetalic resins and combinations thereof.

24. A jacket according to claim 1, wherein said reversible hydrogen getter is in the form of shaped bodies like pellets, granules, tablets, rings, saddles, and coated strips.

25. A jacket according to claim 1, wherein said reversible hydrogen getter is in the form of a powder.

26. A jacket according to claim 1, having a shape selected form:

a cylindrical shape;

a hemicylindrical shape;

a shape of two hemicylinders, wherein the first is under reversible vacuum and the second is under stable vacuum.

27. A jacket according to claim 1, wherein said promoter getter is in the form of shaped bodies like pellets, granules, tablets, rings, saddles, and coated strips.

28. A jacket according to claim 1, wherein said promoter getter is in the form of a powder.

29. A jacket according to claim 1, having a shape of two hemicylinders, wherein the first is under reversible vacuum and the second is under reversible vacuum.