Low pressure methane storage with highly microporous carbons

• US 5,626,637 A
• Filed: 03/14/1995
• Issued: 05/06/1997
• Est. Priority Date: 10/25/1993
• Status: Expired due to Fees

• Current Assignee: Westvaco Corporation (Meadwestvaco Corporation)
• Original Assignee: Westvaco Corporation (Meadwestvaco Corporation)
• Inventors: Baker, Frederick S.
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US08/403,389
• Time in Patent Office: 784 Days
• Field of Search: 502/425, 502/426, 502/427, 502/416, 502/417, 502/437, 502/526, 206/0.7, 48/174, 48/179, 48/127.3, 141/9, 141/2, 141/100, 141/286
• US Class Current: 48/127.3
• CPC Class Codes: C01B 32/30 Active carbon
• CPC Class Codes: C01B 32/318 characterised by the starting materials
• CPC Class Codes: C01B 32/348 Metallic compounds
• CPC Class Codes: F02B 43/00 Engines characterised by operating on gaseous fuels; Plants including such engines engines characterised by the gas-air charge being ignited by compression ignition of an additional fuel F02B7/06; engines convertible from gas to other fuel consumption F02B69/04
• CPC Class Codes: F02F 7/0085 Materials for constructing engines or their parts
• CPC Class Codes: F17C 11/007 for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
• CPC Class Codes: Y02T 10/30 Use of alternative fuels, e.g. biofuels

Abstract

A process is disclosed for storing gaseous hydrocarbon fuel in storage containers under relatively low pressure by including in the cylinders highly microporous carbons prepared by further chemical activation of activated carbon comprising activation an active carbon precursor material with an alkali solution, predrying the blend to below about 25% moisture content, heat treating this blend at from about 652° to about 1100° C., and acid washing and drying the microporous activated carbon product, which is characterized by greater than 50% of its total pore volume comprising pores of from above 8 Å to 20 Å in width and greater than 70% of its total pore volume comprising pores of less than 20 Å in width and greater than 95% of its total pore volume comprising pores of less than 50 Å in width.

Claims

1. An improved process for storing gaseous hydrocarbon fuel in a storage container comprising filling the storage container with activated carbon prior to filling with the gaseous hydrocarbon fuel wherein the improvement comprises activated carbon prepared by a two stage phosphoric acid/potassium hydroxide activation of lignocellulosic material wherein greater than 50% of the total pore volume of the activated carbon is comprised of pores in the range of greater than 8 Å

up to 20 Å

in width and greater than 95% of the total pore volume of the activated carbon is comprised of pores up to 50 Å

in width, the gaseous hydrocarbon fuel is natural gas which is stored at a pressure of about 500 psi, and the filled storage container delivers at least 150 v/v of natural gas.

2. The process of claim 1 wherein greater than 25% of the total pore volume of the activated carbon is comprised of pores of 10 Å

to 16 Å

in width, greater than 70% of the total pore volume of the activated carbon is comprised of pores less than 20 Å

in width, and greater than 98% of the total pore volume of the activated carbon is comprised of pores less than 50 Å

in width.

3. The process of claim 1 wherein the lignocellulosic material is selected from a member of the group consisting of wood chips, sawdust, wood flour, and coconut shell.

4. The process of claim 1 wherein storage container is selected from a member of the group consisting of a conformable or nonconformable tank, a cylinder, and a vessel.