Process for separating components from gaseous streams

• US 5,626,650 A
• Filed: 05/05/1995
• Issued: 05/06/1997
• Est. Priority Date: 10/23/1990
• Status: Expired due to Term

• Current Assignee: Catalytic Materials, LLC
• Original Assignee: Catalytic Materials, LLC
• Inventors: Baker, R. Terry K., Rodriguez, Nelly M.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/435,337
• Time in Patent Office: 732 Days
• Field of Search: 95/116, 95/127-129, 95/138, 95/139, 95/145, 95/900, 95/901, 95/903
• US Class Current: 95/116
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/304 Linear dimensions, e.g. particle shape, diameter
• CPC Class Codes: B01D 2253/306 Surface area, e.g. BET-specific surface
• CPC Class Codes: B01D 2257/108 Hydrogen
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C01B 3/0021 Carbon, e.g. active carbon, carbon nanotubes, fullerenes; Treatment thereof
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y10S 95/90 Solid sorbent
• CPC Class Codes: Y10S 977/845 Purification or separation of fullerenes or nanotubes

Abstract

The present invention relates to the separation of one or more components from a multi-component gaseous stream. The component(s) being separated are relatively small molecular diameter gas components. They are separated by sorption techniques wherein the sorbent is a unique class of layered nanostructure materials, such as carbon nanofibers, characterized as having; (i) a surface area from about 0.2 to 3,000 m² /g as determined by N₂ adsorption at -196° C., (ii) a crystallinity from about 5% to about 100%, and (iii) interstices from about 0.335 nm to about 0.67 nm.

Claims

1. A process for selectively separating components from a gaseous stream, which components are those having a molecular diameter equal to or less than about 0.67 nm;

which process comprises;

(a) introducing a gaseous stream containing;

(i) gaseous components having a molecular diameter equal to or less than about 0.67 nm, and (ii) gaseous components having a molecular diameter greater than about 0.67 nm into a bed of layered nanostructures characterized as having;

(i) a surface area from about 0.2 to 3,000 m² /g by N2 adsorption at -196°

C., (ii) a crystallinity from about 5% to about 100%, and (iii) interstices from about 0.335 nm to about 0.67 nm between graphite platelets.

2. The process of claim 1 wherein the nanostructure is a carbon nanostructure.

3. The process of claim 2 wherein the carbon nanostructure is selected from the group consisting of carbon nanotubes, carbon fibrils, carbon nanoshells, and carbon nanofibers.

4. The process of claim 3 wherein the carbon nanostructure is a carbon fibril characterized by a substantially constant diameter between about 3.5 nm and 70 nm, a length greater than about 5 times the diameter, an outer region of multiple essentially continuous layers of ordered carbon atoms having c-axis that are substantially perpendicular to the cylindrical axis of the fibril, and a distinct inner core region.

5. The process of claim 4 wherein the carbon fibrils are substantially cylindrical.

6. The process of claim 5 wherein the carbon fibrils are further characterized as having:

a crystallinity from about 50% to 100%.

7. The process of claim 6 wherein the crystallinity is from about 90% to 100%.

8. The process of claim 7 wherein the surface area is from about 50 to 800 m² /g and the interstices of about 0.335 nm to about 0.40 nm.

9. The process of claim 4 wherein the carbon nanostructure is a carbon nanotube characterized as having:

a crystallinity from about 50% to 100%.

10. The process of claim 3 wherein the gaseous component to be separated is selected from hydrogen, oxygen, nitric oxide, nitrous oxide, carbon dioxide, ammonia, and acetylene.

11. The process of claim 10 wherein the gaseous component is hydrogen.

12. A process for selectively separating components from a gaseous stream, which components are those having a molecular diameter equal to or less than about 0.67 nm;

which process comprises;

(a) introducing a gaseous stream containing;

(i) gaseous components having a molecular diameter equal to or less than about 0.67 nm, and (ii) gaseous components having a molecular diameter greater than about 0.67 nm into a bed of carbon nanofibers characterized as having;

(i) a surface area from about 0.2 to 3,000 m² /g by N2 adsorption at -196°

C., (ii) a crystallinity from about 5% to about 100%, and (iii) interstices from about 0.335 nm to about 0.67 nm between graphite platelets.

13. The process of claim 12 wherein the carbon nanofibers are further characterized as having:

a crystallinity from about 75% to 100%, and interstices of about 0.335 nm to 0.40 nm between graphite platelets.

14. The process of claim 13 wherein the crystallinity is from about 90% to 100%.

15. The process of claim 14 wherein the surface area is from about 50 to 800 m² /g.

16. The process of claim 15 wherein the interstices are substantially 0.335 nm.

17. The process of claim 16 wherein the gaseous component is hydrogen.

18. The process of claim 15 wherein the gaseous component to be separated is selected from hydrogen, oxygen, nitric oxide, nitrous oxide, carbon dioxide, ammonia, and acetylene.

19. The process of claim 12 wherein the gaseous component to be separated is selected from hydrogen, oxygen, nitric oxide, nitrous oxide, carbon dioxide, ammonia, and acetylene.