Composite carbon foam electrode

• US 5,626,977 A
• Filed: 02/21/1995
• Issued: 05/06/1997
• Est. Priority Date: 02/21/1995
• Status: Expired due to Term

• Current Assignee: Lawrence Livermore National Security LLC (Government of the United States of America)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Pekala, Richard W., Mayer, Steven T., Kaschmitter, James L.
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/393,588
• Time in Patent Office: 805 Days
• Field of Search: 429/44, 252/502, 252/503, 502/180, 502/182, 423/445 R
• US Class Current: 429/523
• CPC Class Codes: H01G 11/24 characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
• CPC Class Codes: H01G 11/30 characterised by their material
• CPC Class Codes: H01G 11/34 characterised by carbonisation or activation of carbon
• CPC Class Codes: H01G 11/42 Powders or particles, e.g. composition thereof
• CPC Class Codes: H01G 11/46 Metal oxides
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

Claims

1. An electrode comprising a composite carbon foam derived from the pyrolysis of mixtures of granularized material, polyhydroxybenzene compounds, and formaldehyde or furfural, the composite carbon foam having a surface area between about 100 m² /g to about 1200 m² /g.

2. The electrode of claim 1, wherein the composite carbon foam has a density of between about 0.1 g/cc to about 1.2 g/cc.

3. The electrode of claim 1, wherein the granularized material is mixed with mixtures consisting of resorcinol/furfural, resorcinol/formaldehyde, phenol/resorcinol/formaldehyde, catechol/formaldehyde, and phloroglucinol/formaldehyde.

4. The electrode of claim 1, wherein the granularized material is an electrically conductive material.

5. The electrode of claim 4, wherein the electrically conductive material is composed of fibers selected from the group of metal and carbon.

6. The electrode of claim 5, wherein the fibers of metal and carbon are selected from the group of nickel, stainless steel, carbon, and electroplated carbon.

7. The electrode of claim 1, wherein the granularized material is selected from the group consisting of carbon aerogel microspheres, crushed/powderized carbon aerogel, powderized activated and non-activated carbon, and metal and/or metal oxide powders and spheres.

8. The electrode of claim 1, wherein the granularized material is selected from the group of carbon foam, carbon, metals, carbon fibers, metal fibers, and carbon aerogels.

9. The electrode of claim 1, wherein the granularized material is composed of carbon aerogel powders in binders composed of PTFE, EPDM, PVDF and PMMA.