Gas sampling system and method

• US 5,627,328 A
• Filed: 12/29/1995
• Issued: 05/06/1997
• Est. Priority Date: 12/29/1995
• Status: Expired due to Fees

• Current Assignee: Gas Research Institute (GTI Energy)
• Original Assignee: Gas Research Institute (GTI Energy)
• Inventors: Sheridan, David R., Morrison, Glenn C.
• Primary Examiner(s): RAEVIS, ROBERT R
• Application Number:
  US08/580,574
• Time in Patent Office: 494 Days
• Field of Search: 73/1 G, 73/23.31, 73/863.01, 73/863.21, 73/863.23, 73/863.24, 73/863.31, 73/863.81, 73/863.83, 73/864.34, 73/864.73 , 73/864.81
• US Class Current: 73/863.83
• CPC Class Codes: G01N 1/2258 in a stack or chimney
• CPC Class Codes: G01N 1/24 Suction devices G01N1/22 - G01N1/2294 take precedence
• CPC Class Codes: G01N 33/0006 Calibrating gas analysers
• CPC Class Codes: G01N 33/0011 Sample conditioning in general G01N1/28
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array electrochemical electrode arrays G01N27/27

Abstract

A gas sampling system and method that utilizes a double aspirator design to precisely control the flow rate of a gas sample past a sensor (44, 46, or 48). The double aspirator design includes a primary aspirator (24) to draw a gas sample from the exhaust stack (14) at a first flow rate and a secondary aspirator (26) to draw a portion of the gas sample from the primary aspirator at a second flow rate past the sensors. In addition, a first pressure sensor (74) and second pressure sensor (76) are provided in order to monitor changes in the pressure differential across the sensor so that corresponding changes in the second flow rate can be accounted for by the control unit (18) when processing the measurement data from the sensor.

Claims

1. A gas sampling system for analyzing components of a gas sample extracted from a gas emission stream in an exhaust stack of a process by a probe, comprising:

a first vacuum means for drawing said gas sample from said gas emission stream in said exhaust stack at a first flow rate;

a second vacuum means for drawing a portion of said gas sample from said first vacuum means at a second flow rate;

a sensor array including at least two sensors configured such that a specified quantity of said portion of said gas sample is delivered to each of said sensors at a specified sensor flow rate for each said sensor; and

a critical orifice downstream of each of said sensors in order to desensitize said sensor flow rate of each said sensor from changes in pressure downstream of each respective said critical orifice.

2. The system of claim 1, further comprising a first pressure sensor configured to measure the upstream pressure of said sensor array and a second pressure sensor configured to measure the downstream pressure of said sensor array for measuring changes in a pressure drop across said sensor array so that adjustments can be made to account for changes in said sensor flow rates as a result of said changes in said pressure drop.

3. The system of claim 1, further comprising a calibration module capable of providing both unit and probe calibration, said module including means for selectively providing calibration gas substantially directly to one of either said sensor array or said probe.

4. The system of claim 1, wherein each said critical orifice includes an upstream filter for removing matter that may hinder operation of said critical orifices.

5. The system of claim 1, wherein said first and second vacuum means are educators.

6. The system of claim 1, wherein said first flow rate is approximately 10 liters per minute and said second flow rate is approximately 3 liters per minute.

7. The system of claim 1, wherein said sensors includes catalytic heat-flux sensors.

8. The system of claim 1, wherein said first flow rate is greater than said second flow rate.

9. The system of claim 1, wherein said sensor army includes a NO_x catalytic heat-flux sensor, a CO catalytic heat-flux sensor, and an O₂ zirconia sensor.

10. The system of claim 9, wherein a metered amount of make-up air and ammonia are blended with said gas sample delivered to said NO_x sensor.

11. The system of claim 9, wherein a metered amount of make-up air is blended with said gas sample delivered to said CO sensor.

12. A gas sampling system for analyzing components of a gas sample extracted from a gas emission stream in an exhaust stack of an industrial process by a probe for both continuous emissions and process control monitoring, said system capable of being mounted in an on-stack or off-stack configuration, and comprising:

a sensor module including an array of sensors, each sensor configured to receive a portion of said gas sample at specified flow rates;

a calibration module including a calibration valve for selectively delivering calibration gas to one of either said sensor array and said probe; and

an aspirator module in communication with said sensor module and including a primary aspirator for drawing said gas sample from said exhaust stack at a first flow rate and a secondary aspirator for drawing a portion of said gas sample from said primary aspirator and through said sensor module at a second flow rate.

13. The system of claim 12, wherein said sensor module further includes a critical orifice associated with each said sensor for desensitizing said second flow rate from changes in pressure downstream of said sensor module.

14. The system of claim 12, wherein said first flow rate is approximately 10 liters per minute and said second flow rate is approximately 3 liters per minute.

15. The system of claim 12, wherein said primary and secondary aspirators are educators.

16. A gas sampling system for analyzing components of a gas sample extracted from a gas emission stream in an exhaust stack of an industrial process by a probe for both continuous emissions and process control monitoring said system capable of being mounted in an on-stack or off-stack configuration, comprising:

a sensor module including an array of sensors, each sensor configured to receive a portion of said gas sample at specified flow rates;

a calibration module including a calibration valve for selectively delivering calibration gas to one of either said sensor array and said probe;

an aspirator module in communication with said sensor module and including a primary aspirator for drawing said gas sample from said exhaust stack at a first flow rate and a secondary aspirator for drawing a portion of said gas sample from said primary aspirator and through said sensor module at a second flow rate;

a pressure differential measurement means for detecting changes in a pressure drop across said sensor module; and

a critical orifice associated with each said sensor of said sensor module for desensitizing said second flow rate from changes in pressure downstream of said sensor module.

17. A method for extracting a gas sample from a gas stream in an exhaust stack of a process by a probe, comprising the steps of:

drawing said gas sample from said gas stream in said exhaust stack at a first flow rate;

drawing a portion of said gas sample at a second flow rate;

passing said portion of said gas sample to a sensor army including at least two sensors configured such that a specified quantity of said portion of said gas sample is delivered to each of said sensors at a specified sensor flow rate for each said sensor;

desensitizing said sensors from changes in pressure downstream of each said sensor by incorporating a critical orifice downstream of each respective said sensor; and

measuring a pressure differential across said sensor array so that changes in said sensor flow rates at each of said sensors can be accounted for in analyzing said gas sample.