Condition tester for a battery

• US 5,627,472 A
• Filed: 01/26/1995
• Issued: 05/06/1997
• Est. Priority Date: 01/26/1995
• Status: Expired due to Term

• Current Assignee: Gillette Company (The Procter & Gamble Company)
• Original Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated)
• Inventors: Bernier, Joseph, Searle, Gary M., Ofer, David
• Primary Examiner(s): Wieder, Kenneth A.
• Assistant Examiner(s): BROWN, GLENN WARNER
• Application Number:
  US08/378,688
• Time in Patent Office: 831 Days
• Field of Search: 324/426, 324/427, 324/435, 340/636, 320/48, 429/90, 429/91, 429/92, 429/93
• US Class Current: 324/435
• CPC Class Codes: G01N 27/4175 Calibrating or checking the analyser
• CPC Class Codes: G01R 31/385 Arrangements for measuring battery or accumulator variables for monitoring G01R31/382
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/488 Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density
• CPC Class Codes: H01M 50/569 Constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals battery terminal connectors with integrated measuring arrangements G01R31/364
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10S 320/21 State of charge of battery

Abstract

A tester for determining the condition of an electrochemical power source, e.g. a battery or main cell, is disclosed. The tester may comprise an electrolytic (coulometric) cell connected in series to a auxiliary cell. The auxiliary cell is a miniature electrochemical power cell. The electrolytic (coulometric) cell may have no electromotive force of its own and may comprise an anode and cathode of the same material, desirably silver, with an electrolyte contacting at least a portion of both the anode and cathode. The tester may be permanently connected in parallel to a main cell being tested and is thin enough to be integratable into a label for the main cell. As the main cell discharges, the electrolytic cell anode clears proportionally to the discharge of one of the electrodes of the main cell to provide a continuous visually discernible indication of the state of charge of the main cell.

Claims

1. A condition indicator for an electrochemical power source, said condition indicator comprising an electrolytic cell having essentially no electromotive force (e.m.f.) of its own, said electrolytic cell comprising an anode, a cathode, and an electrolyte, said electrolyte electrically contacting at least a portion of both said anode and cathode, and said condition indicator further comprising an auxiliary cell electrically connected in series to the electrolytic cell, wherein the auxiliary cell is an electrochemical power generating cell, and wherein said power source is an electrochemical cell other than the auxiliary cell, the electrochemical power source comprising a positive and a negative terminal whereinsaid electrochemical power source is electrically connected to the auxiliary cell with one of (i) and (ii) being in effect, said (i) being the positive terminal of said electrochemical power source electrically connected to the cathode of the auxiliary cell and said (ii) being the negative terminal of said electrochemical power source electrically connected to the anode of the auxiliary cell.

2. The condition indicator of claim 1 wherein at least a portion of one of said anode and cathode is visible, and wherein during electrolysis in the electrolytic cell reaction begins at a first region of said visible electrode and continues therefrom towards remote regions thereof.

3. The combination of a battery and a battery condition indicator, wherein said battery comprises a casing, a negative terminal, and a positive terminal and said condition indicator comprises an electrolytic cell having essentially no electromotive force (e.m.f.) of its own, said electrolytic cell comprising an anode, a cathode, and an electrolyte, said electrolyte electrically contacting at least a portion of both said anode and cathode, said condition indicator being permanently electrically connected to the battery, wherein said condition indicator further comprises an auxiliary cell electrically connected in series to the electrolytic cell, wherein the auxiliary cell is an electrochemical cell other than the battery, said auxiliary cell comprising an anode, a cathode, and an electrolyte contacting at least a portion of said auxiliary cell anode and cathode, wherein the battery is electrically connected to the auxiliary cell with one of (i) add (ii) being in effect, said (i) being the positive terminal of the battery electrically connected to the cathode of the auxiliary cell and said (ii) being the negative terminal of said battery electrically connected to the anode of the auxiliary cell, wherein at least one of said anode and cathode of the electrolytic cell being visible and wherein during discharge of said battery reaction begins at a first region of said visible electrode and continues therefrom towards remote regions thereof.

4. The combination of claim 3 wherein the auxiliary cell cathode is electrically connected to the positive terminal of the battery and the auxiliary cell anode is electrically connected to the cathode of the electrolytic cell and the anode of the electrolytic cell is electrically connected to the negative terminal of the battery.

5. The combination of claim 3 wherein the auxiliary cell anode is electrically connected to the negative terminal of the battery and the auxiliary cell cathode is electrically connected to the anode of the electrolytic cell and the cathode of the electrolytic cell is electrically connected to the positive terminal of the battery.

6. The combination of claim 3 wherein the condition indicator is integrated into a label for said battery.

7. The combination of claim 3 wherein said battery comprises an elongated current collector in electrical contact with said negative terminal, wherein said battery further comprises a resistive element located along the length of said current collector, and wherein the electrolytic cell is electrically connected across said resistive element so that said resistive element functions as a shunt resistor for said electrolytic cell.

8. The combination of claim 3 wherein said battery further comprises a resistive element located between said positive terminal and said casing , and wherein the electrolytic cell is electrically connected across said resistive element so that said resistive element functions as a shunt resistor for said electrolytic cell.

9. The combination of claim 3 wherein the electrolytic cell anode and cathode comprise the same electrochemically active material.

10. The combination of claim 3 wherein the anode and cathode of the electrolytic cell are laterally spaced apart so that no portion of the electrolytic cell anode overlaps any portion of the electrolytic cell cathode.

11. The combination of claim 3 wherein the anode and cathode of the electrolytic cell both comprise silver.

12. The combination of claim 3 wherein the cell condition indicator has a thickness of less than about 100 mils (2.5 mm).

13. The combination of claim 3 wherein the condition indicator has a thickness between about 2 and 15 mils (0.05 and 0.4 mm).