Micro optical fiber light source and sensor and method of fabrication thereof

• US 5,627,922 A
• Filed: 03/02/1995
• Issued: 05/06/1997
• Est. Priority Date: 09/04/1992
• Status: Expired due to Fees

• Current Assignee: Raoul Kopelman, Weihong Tan, Zhong-You Shi
• Original Assignee: Board of Regents of the University of Michigan (University of Michigan)
• Inventors: Tan, Weihong, Kopelman, Raoul, Shi, Zhong-You
• Primary Examiner(s): Healy, Brian
• Application Number:
  US08/397,331
• Time in Patent Office: 796 Days
• Field of Search: 385/12, 385/125, 385/33, 385/43, 385/14, 385/31, 385/123, 385/38, 385/127, 385/128, 359/368, 359/385, 250/227.14, 250/227.18, 250/227.11, 427/162, 427/163, 427/457, 427/487
• US Class Current: 385/12
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 35/00 Methods or apparatus for measurement or analysis of nanostructures
• CPC Class Codes: G01Q 60/22 Probes, their manufacture, or their related instrumentation, e.g. holders
• CPC Class Codes: G02B 6/241 Light guide terminations
• CPC Class Codes: G02B 6/2552 reshaping or reforming of light guides for coupling using thermal heating, e.g. tapering, forming of a lens on light guide ends
• CPC Class Codes: G02B 6/3624 Fibre head, e.g. fibre probe termination optical details of light guide terminations G02B6/241; reshaping of light guides G02B6/2552; optical details of coupling light into or out of fibre end G02B6/262

Abstract

This invention relates generally to the development of and a method of fabricating a fiber optic micro-light source and sensor (50). An optical fiber micro-light source (50) is presented whose aperture is extremely small yet able to act as an intense light source. Light sources of this type have wide ranging applications, including use as micro-sensors (22) in NSOM. Micro-sensor light sources have excellent detection limits as well as photo stability, reversibility, and millisecond response times. Furthermore, a method for manufacturing a micro optical fiber light source is provided. It involves the photo-chemical attachment of an optically active material onto the end surface of an optical fiber cable which has been pulled to form an end with an extremely narrow aperture. More specifically, photopolymerization has been applied as a means to photo-chemically attach an optically active material (60). This process allows significant control of the size of the micro light source (50). Furthermore, photo-chemically attaching an optically active material (60) enables the implementation of the micro-light source in a variety of sensor applications.

Claims

1. An optical fiber light source comprising an optical fiber having one end of said fiber substantially uniformly tapered to define a tapered portion of said optical fiber, said tapered portion having an end face to further define an optical fiber tip, said tapered portion also having sides coated with an opaque material to prevent the escape of light from said tapered portion, and an optically active material photo-chemically attached to said optical fiber tip where said optically active material is responsive to excitation by light wherein the optically active material includes a first dye material photopolymerized onto said fiber optic tip and a second optically active dye material photopolymerized onto said first optically active dye material.

2. The apparatus of claim 1 wherein said optically active material comprises at least one illuminescent dye.

8. The apparatus as defined in claim 1 wherein said opaque material is a conductive material and said material partially coats a non-tapered portion of said optical fiber, said material having a thickness so as to be a non-opaque coating on said non-tapered portion, and an electrode having one end implanted in said optically active material for detecting an electro-chemical signal in proximity to said optically active material.

3. An optical fiber light source comprising an optical fiber having one end of said fiber substantially uniformly tapered to define a tapered portion of said optical fiber, said tapered portion having an end face to further define an optical fiber tip, said tapered portion also having sides coated with an opaque material to prevent the escape of light from said tapered portion, and an optically active material photo-chemically attached to said optical fiber tip where said optically active material is responsive to excitation by light, the tapered portion of said optical fiber being is inserted into a pulled micro pipette having a shank portion terminating in an aperture of said micro pipette, said optically active material located substantially near said aperture.

4. The apparatus as defined in claim 3 wherein said micro pipette provides protection for said fiber optic tip and optically activated material.

5. The apparatus as defined in claim 3 wherein a fluid may be drawn into the shank portion of said micro pipette so that chemical analysis may be performed.

6. The apparatus as defined in claim 3 wherein the shank of said micro pipette has inner walls coated with a chemically responsive material, said material being chemically responsive to a fluid drawn into the shank portion of said micro pipette, said material interacting with said fluid, enabling chemical analysis via said optically active material.

7. The apparatus as defined in claim 3 further comprising:

an opaque material applied to the exterior of said micro pipette; and

a luminescent material within the shank portion of said micro pipette and near said aperture of said micro pipette, said optically active material acting as a light source for said luminescent material through said optical fiber.

9. A fiber optic light source sensor wherein said sensor includes:

an optical fiber including a first tapered terminal end and a tip as defined by an end face of the tapered optical fiber, said tip having a diameter less than 10 micrometers;

an optically active material photopolymerized onto the tip of said tapered end, said optically active material including a dye whose optical response varies in accordance with the particular condition to be sensed;

a light source coupled to a second non-tapered end of said optical fiber where said light source generates light of predetermined intensity and wavelength;

a scanner for substantially continuously positioning said optically active material with respect to said sample said optically active material of said optical fiber in close proximity to a sample;

an objective lens disposed in proximity to the optically active material of said optical fiber so that light emitted from said material is collected by said objective lens after interaction with the sample; and

a means for analyzing said light emissions absorbed by said objective lens.

10. The apparatus as defined in claim 9 wherein said optically active material chemically interacts with said sample wherein light from said light source is emitted from said optically active material varies in intensity and wavelength in accordance with said chemical interaction.

11. The apparatus as defined in claim 9 wherein said optically active material operates as a light source for illumination of said sample.

12. The apparatus as defined in claim 9 wherein said scanner comprises a three way translational stage for positioning the optically active material in three orthoganal directions with respect to said sample.

13. A fiber optic light source sensor wherein said sensor includes:

an optical fiber including a first tapered terminal end and a tip as defined by an end face of the tapered optical fiber, said tip having a diameter less than 10 micrometers;

an optically active material photopolymerized onto the tip of said tapered end, said optically active material including a dye whose optical response varies in accordance with the particular condition to be sensed;

a light source coupled to a second non-tapered end of said optical fiber where said light source generates light of predetermined intensity and wavelength;

a three-way translational stage for positioning the optically active material of the optical fiber in close proximity to a sample to effectuate a light emission varying in intensity and wavelength in accordance with said chemical interaction between said sample and said optically active material;

an objective lens disposed in proximity to the optically active material of said optical fiber so that light emitted from said material is collected by said objective lens after interaction with the sample; and

a means for analyzing said light emissions absorbed by said objective lens.

14. An optical fiber light source comprising an optical fiber having one end of said fiber substantially uniformly tapered to define a tapered portion of said optical fiber, said tapered portion having an end face to further define an optical fiber tip, said tapered portion having sides partially coated with an opaque material, leaving an uncoated band of said optical fiber in proximity to said optical fiber tip, and an optically active material photo-chemically attached to said optical fiber tip and said uncoated tapered portion, said optically active material being responsive to excitation by light.

15. The apparatus as defined in claim 14 wherein said optically active material is chemically attached using a photo-chemical process whereby light is coupled into a nontapered end of said optical fiber to enable, fabrication of the optically active material in a predetermined size and shape.

16. The apparatus of claim 15 wherein said photopolymerization process may occur repeatedly in order to photopolymerize substantially different chemically active materials.

17. The apparatus of claim 15 wherein said photopolymerization process may occur repeatedly in order to photopolymerize said optically active material onto said fiber optic tip in progressive steps.

18. An optical fiber light source comprising:

an optical fiber having one end of said fiber substantially uniformly tapered to define a tapered portion of said optical fiber, said tapered portion having an end face to further define an optical fiber tip, said tapered portion also having sides coated with an opaque material to prevent the escape of light from said tapered portion, and an optically active material photo-chemically attached to said optical fiber tip where said optically active material is responsive to excitation by light;

a pulled micro pipette having a shank portion terminating in an aperture of said micro pipette, said optically active material located substantially near said aperture.

19. The apparatus as defined in claim 18 wherein said micro pipette provides protection for said fiber optic tip and optically activated material.

20. The apparatus as defined in claim 18 wherein a fluid may be drawn into the shank portion of said micro pipette so that chemical analysis may be performed.

21. The apparatus as defined in claim 18 wherein the shank of said micro pipette has inner walls coated with a chemically responsive material, said material being chemically responsive to a fluid drawn into the shank portion of said micro pipette, said material interacting with said fluid, enabling chemical analysis via said optically active material.

22. The apparatus as defined in claim 18 further comprising:

an opaque material applied to the exterior of said micro pipette; and

a luminescent material within the shank portion of said micro pipette and near said aperture of said micro pipette, said optically active material acting as a light source for said luminescent material through said optical fiber.

23. An optical fiber light source comprising:

an optical fiber having one end of said fiber substantially uniformly tapered to define a tapered portion of said optical fiber, said tapered portion having an end face to further define an optical fiber tip, said tapered portion also having sides coated with an opaque material to prevent the escape of light from said tapered portion, and an optically active material photo-chemically attached to said optical fiber tip where said optically active material is responsive to excitation by light;

said opaque material is a conductive material and said material partially coats a non-tapered portion of said optical fiber, said material having a thickness so as to be a non-opaque coating on said non-tapered portion, and an electrode having one end implanted in said optically active material for detecting an electro-chemical signal in proximity to said optically active material.