Dephenolizing process for production of high-quality polycarbonate grade bisphenol A

• US 5,629,457 A
• Filed: 09/29/1995
• Issued: 05/13/1997
• Est. Priority Date: 02/16/1993
• Status: Expired due to Fees

• Current Assignee: China Petrochemical Corporation, Tianjin University
• Original Assignee: China Petrochemical Corporation, Tianjin University
• Inventors: Yu, Shenbo, Qian, Shenghua, Zhang, Minhua, Li, Chuanzhao, Liu, Zongzhang
• Primary Examiner(s): Shaver, Paul F.
• Application Number:
  US08/501,138
• Time in Patent Office: 592 Days
• Field of Search: 568/724
• US Class Current: 568/724
• CPC Class Codes: C07C 37/70 by physical treatment
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

A process for producing high-quality polycarbonate grade bisphenol A directly by removing phenol from the adduct crystal of bisphenol A with phenol via a gas-solid reaction at low temperature comprises directly feeding the adduct crystal into a vacuum or pneumatic dephenolizing device under vacuum a inert gas stream, controlling the temperature of the adduct crystal below its melting point, decomposing the adduct crystal into gas phase and solid phase, removing the gas phase phenol and condensing phenol for recovery, well leaving the rest being the desirable bisphenol A. The process possesses easy operation, short procedure, low energy consumption, and high purity and good color of bisphenol A obtained. Bisphenol A produced according to the process of the invention may be used as the raw material for producing polycarbonates for optical use.

Claims

1. A process for the production of high-quality polycarbonate grade bisphenol A by removing phenol from an adduct crystal of phenol with bisphenol A comprising the steps of directly feeding the adduct crystal of phenol with bisphenol A into a vacuum or pneumatic dephenolizing device under a vacuum or in an inert gas stream, controlling the temperature of the adduct crystal below its melting point, and decomposing the adduct crystal to a gas phase and a solid phase, wherein phenol which is removed from the dephenolizing device by the vacuum or inert gas stream is condensed for recovery and is reused, and wherein solid phase high-quality polycarbonate grade bisphenol A is obtained directly from the dephenolizing device.

2. The process according to claim 1 wherein the inert gas stream comprises any gas which is unreactive to bisphenol A and phenol as well as the adduct crystal thereof.

3. The process according to claim 1 wherein the inert gas stream comprises at least one of nitrogen and argon.

4. The process according to claim 1 wherein the temperature of the adduct crystal is from 40°

to 130°

C.

5. The process according to claim 1 wherein the operating pressure for vacuum dephenolization is from 266.644 to 6,666.1 Pa (2-50 torr) and the residence time of the adduct crystal is from 1 to 4 hours.

6. The process according to claim 1 wherein the operating condition for inert gas stream dephenolization comprises a residence time from 1 to 3.5 hours and a flow rate of the inert gas stream of from 0.1 to 0.50 m/sec.

7. The process according to claim 1 wherein the process comprises one of a batch operation and a continuous operation.

8. The process according to claim 1 wherein the process comprises a batch operation and the temperature of the adduct crystal is raised from 40°

to 130°

C. during the batch operation.

9. The process according to claim 1 wherein the process comprises a continuous operation and the adduct crystal is divided into at least two sections of different temperatures during the continuous operation.

10. The process according to claim 1 wherein the adduct is dephenolized in a static or fluid state.

11. The process according to claim 1 wherein heaters are installed inside the dephenolizing device.