Optical sensor

• US 5,629,774 A
• Filed: 09/29/1995
• Issued: 05/13/1997
• Est. Priority Date: 09/19/1991
• Status: Expired due to Fees

• Current Assignee: British Gas Trading Limited (Centrica PLC)
• Original Assignee: British Gas Trading Limited (Centrica PLC)
• Inventors: Shaw, John S., Peacock, Stanley J., Jaggers, Henry C.
• Primary Examiner(s): Rosenberger, Richard A.
• Application Number:
  US08/537,277
• Time in Patent Office: 592 Days
• Field of Search: 356/445
• US Class Current: 356/445
• CPC Class Codes: G01N 2021/752 Devices comprising reaction zones
• CPC Class Codes: G01N 21/553 and using surface plasmons fluorescence excitation G01N21/648; enhanced Raman G01N21/658

Abstract

An optical sensor assembly includes a light source, a surface plasmon-sensitive structure for reflecting light, a light detector, and a signal indicator. The light detector receives light that is reflected from the surface plasmon-sensitive structure at an angle which is sensitive to surface plasmon absorption.

Claims

1. An optical sensor assembly for sensing the presence of analyte in a fluid, comprising:

a surface plasmon resonance-sensitive structure for reflecting light, said structure responding to exposure to an analyte so as to alter an intensity of the reflecting light;

means for producing light focussed on said surface plasmon resonance sensitive structure;

a light detecting means positioned to receive a portion of the light reflected from the surface plasmon resonance-sensitive structure and for producing an output signal in response to the received portion of the reflected light indicative of the presence of, or representative of the concentration or a concentration range of, the analyte in the fluid;

control means for controlling the portion of the reflected light which reaches the light detecting means; and

indicating means for receiving the output signal and in response thereto indicating the presence, concentration or concentration range of the analyte in the fluid.

2. A sensor assembly as claimed in claim 1, in which the control means comprises one or more members defining an opening.

3. A sensor assembly as claimed in claim 2, in which the opening is an aperture defined by one member.

4. A sensor assembly as claimed in claim 2, in which the opening is in the form of a slit defined by the one or more members.

5. A sensor assembly as claimed in claim 2, in which the control means comprises an optical fibre with the bore therethrough constituting the opening.

6. A sensor assembly as claimed in claim 1, in which the light detecting means is a photodetecting means.

7. A sensor assembly as claimed in claim 6, in which the photodetecting means comprises one single photodetector.

8. A sensor assembly as claimed in claim 1, in which the light source is a diode laser.

9. A sensor assembly as claimed in claim 1, in which the indicating means indicates the presence of the analyte only when the output signal is representative of a concentration of the analyte that is above a predetermined minimum or threshold value.

10. A sensor assembly as claimed in claim 1, in which the indicating means comprises two or more discrete indicators, each one being representative of a different minimum concentration or range of concentrations of the analyte in the fluid.

11. A sensor assembly as claimed in claim 10, in which the indicators are activated in succession as the signal from the light detecting means increases in magnitude in response to increase in the concentration of the analyte in the fluid.

12. A sensor assembly as claimed in claim 1, in which the indicating means comprises one or more visual indicators.

13. A sensor as claimed in claim 12, in which the or each visual indicator is a light emitting diode.

14. A sensor assembly as claimed in claim 1, contained within a casing and which is small enough and light enough to be portable.

15. A sensor assembly as claimed in claim 14, in which the casing can be supported on one hand.

16. A sensor assembly as claimed in claim 1, in which the sensing surface of the surface plasmon resonance-sensitive structure is enclosed by an enclosure having an inlet means, via which fluid can enter the enclosure and contact the sensing surface, and an outlet means via which the fluid can leave the enclosure.

17. A sensor assembly as claimed in claim 16, comprising means for forceably causing the fluid to enter the inlet, pass through the enclosure and exit from the outlet.

18. A sensor assembly as claimed in claim 17, in which the means is a fan or blower located in the inlet or outlet.

19. A sensor assembly as claimed in claim 1, in which the light source, surface plasmon resonance-sensitive structure, control means and light detecting means are all fixed in position.

20. A sensor assembly as claimed in claim 1, in which one or more of the light source, surface plasmon resonance-sensitive structure, control means and light detecting means are movable to or positionable in preset or predetermined positions with any remaining components or component being fixed in position.

21. A sensor assembly as claimed in claim 1, in which the surface plasma resonance-sensitive structure comprises a propagating medium having a reflecting surface which supports or is coupled to a metallic layer which in turn is covered by a film of material which is sensitive to the analyte.

22. A sensor assembly as claimed in claim 1, wherein the surface plasmon resonance-sensitive structure comprises a propagating medium having a reflecting surface which supports or is coupled to a metallic layer and the metallic layer is covered by a film of material which is sensitive to the analyte, and in which the reflecting surface supports the metallic layer directly.

23. A sensor assembly as claimed in claim 1, wherein the surface plasma resonance-sensitive structure comprises a propagating medium having a reflecting surface which supports or is coupled to a metallic layer and the metallic layer is covered by a film of material which is sensitive to the analyte and in which the reflecting surface is coupled to a base member which directly supports the metallic layer.

24. A sensor assembly as claimed in claim 1, comprising a reflecting surface which has the form of a grating of suitable pitch with a metallic film being supported or formed directly on the grating.

25. A sensor assembly as claimed in claim 1, wherein the surface plasmon resonance-sensitive structure comprises a propagating medium having a reflecting surface which supports or is coupled to a metallic layer and the metallic layer is covered by a film of material which is sensitive to the analyte, and in which the film of material which is sensitive to the analyte is an organic material.

26. A sensor assembly as claimed in claim 25, in which the organic material is polypyrrole.

27. A sensor assembly as claimed in claim 1, comprising a second light detecting means for receiving from the surface plasmon resonance-sensitive structure, reflected light which is unaffected by the presence of the analyte and for producing in response to the reflected light received a reference output signal, and means for comparing the output signal with the reference output signal and producing a resultant signal which serves as the input signal to the indicator means.

28. An optical sensor assembly according to claim 1, wherein said control means comprises members defining an opening which is sufficiently small to permit the passage therethrough of only a very small portion of all the light produced by the light source which has been reflected by the surface plasmon resonance-sensitive structure.

29. An optical sensor according to claim 28, wherein said members defining said opening are positioned so that said opening is positioned relative to said surface plasmon resonance-sensitive structure such that the light produced by the light source which is reflected through said opening by the surface plasmon resonance-sensitive structure is more strongly influenced by the surface plasma and resonance-sensitive structure than light produced by the light source which is reflected by the surface plasmon resonance-sensitive structure but which does not pass through said opening.

30. An optical sensor assembly according to claim 28, wherein the light produced by the light source which is reflected by the surface plasmon resonance-sensitive structure and which passes through said opening is more strongly influenced by the surface plasmon resonance-sensitive structure than light produced by the light source which is reflected by the surface plasmon resonance-sensitive structure but which does not pass through said opening.

31. An optical sensor assembly according to claim 1, wherein said control means comprises a fiber optic sensor which receives only a very small portion of the light produced by the light source which is reflected by the surface plasma and resonance-sensitive structure.

32. An optical sensor according to claim 31, wherein said very small portion is more strongly influenced by the surface plasmon resonance-sensitive structure than the light produced by the light source which is reflected by the surface plasmon resonance-sensitive structure but which is not received by said fiber optic sensor.

33. An optical sensor assembly according to claim 1, wherein said control means comprises a fiber optic detector for detecting light reflected by the surface plasmon resonance-sensitive structure at an angle at which light produced by the light source which is more strongly influenced by the surface plasma and resonance-sensitive structure than at light reflected at other angles from the surface plasmon resonance-sensitive structure.

34. A hand held optical sensor for sensing the presence of analyte in a fluid, comprising:

a light source;

a surface plasmon resonance-sensitive device;

means for focusing light from the light source onto the plasmon resonance-sensitive surface of the device which, in use, reflects the focused light from the light source in the form of a diverging reflected light beam and, on exposure to analyte, responds so as to alter the intensity of the light which is reflected;

a light detecting means for receiving light reflected from the device;

control means for allowing only a portion of that part of the diverging reflected light beam that has been influenced by the surface plasmon resonance effect to reach the light detecting means wherein the light detecting means receives only the influenced portion of the diverging reflected light beam and produces in response to the received portion of the diverging reflected light beam an output signal indicative of the presence of, or representative of the concentration or a concentration range of, the analyte in the fluid; and

indicating means for receiving the signal and in response thereto indicating the presence, concentration or concentration range of the analyte in the fluid.